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1.
Polymers (Basel) ; 14(3)2022 Feb 01.
Article in English | MEDLINE | ID: mdl-35160580

ABSTRACT

In this study, sorptivity, setting time, resistance to sulfuric acid, and compressive strength of mortars that use alkali-activated GGBS and fly ash as binders, were evaluated experimentally. The activation of binders, was achieved at room temperature of 22 ± 2 °C using combinations of sodium silicates (Na2SiO3) and sodium hydroxide (NaOH) solutions in ratios of 1.5, 2.0, and 2.5. The parameters considered in terms of their effects on fresh and hardened properties include: NaOH molarity, activator ratio Na2SiO3/NaOH, mortar sample age, and relative amount of GGBS/fly ash in binder combination. Sorptivity, change in mass, and compressive strength were determined for mortar samples that were submerged in 10% sulfuric acid solution for 7 days, 28 days, and 90 days. The binder for mortar samples tested at each of the specified ages consisted of 100% GGBS (G100), 75%GGBS+25% fly ash (G75F25), or 50% GGBS + 50% fly ash (G50F50). The binder was activated using Na2SiO3 solution, combined with 10 M, 12 M, 14 M, or 16 M NaOH solution. It was found that sorptivity decreases with increase in curing age, for all activator ratios, concentrations, and relative amounts of GGBS/fly ash. Binder consisting of 75%GGBS + 25% fly ash with NaOH concentration of 12 M had the lowest sorptivity. Exposure of alkali-activated GGBS/fly ash mortar samples to sulfate attack did not cause loss in mass nor visible signs of damage/deterioration. All binder combinations experienced increase in compressive strength after curing in 10%sufluric acid solution, with the optimum G75F25 mix achieving a 28-day strength of 80.53 MPa when NaOH molarity is 10 M, which increased to 91.06 MPa after 90 days. Variation in concentration of NaOH didn't cause significant change in the magnitudes of 28-day or 90-day compressive strengths of G50F50. However, despite slow dissolution of fly ash and immersion in 10% sulfuric acid solution, G50F50 developed 28-day compressive strength of 56.23 MPa and 90-day compressive of 86.73 MPa, which qualifies G50F50 as high strength mortar for practical purposes.

2.
Polymers (Basel) ; 13(9)2021 Apr 26.
Article in English | MEDLINE | ID: mdl-33926028

ABSTRACT

Reducing the fingerprint of infrastructure has become and is likely to continue to be at the forefront of stakeholders' interests, including engineers and researchers. It necessary that future buildings produce minimal environmental impact during construction and remain durable for as long as practicably possible. The use of basalt fiber-reinforced polymer (BFRP) bars as a replacement for carbon steel is reviewed in this article by examining the literature from the past two decades with an emphasis on flexural strength, serviceability, and durability. The provisions of selected design and construction guides for flexural members are presented, compared, and discussed. The bond of BFRP bars to the surrounding concrete was reportedly superior to carbon steel when BFRP was helically wrapped and sand coated. Experimental studies confirmed that a bond coefficient kb = 0.8, which is superior to carbon steel, may be assumed for sand-coated BFRP ribbed bars that are helically wrapped, as opposed to the conservative value of 1.4 suggested by ACI440.1R-15. Code-based models overestimate the cracking load for BFRP-reinforced beams, but they underestimate the ultimate load. Exposure to an alkaline environment at temperatures as high as 60 °C caused a limited reduction in bond strength of BFRP. The durability of BFRP bars is influenced by the type of resin and sizing used to produce the bars.

3.
Polymers (Basel) ; 12(3)2020 Mar 19.
Article in English | MEDLINE | ID: mdl-32204432

ABSTRACT

Reinforced concrete flat slabs or flat plates continue to be among the most popular floor systems due to speed of construction and inherent flexibility it offers in relation to locations of partitions. However, flat slab/plate floor systems that are deficient in two-way shear strength are susceptible to brittle failure at a slab-column junction that may propagate and lead to progressive collapse of a larger segment of the structural system. Deficiency in two-way shear strength may be due to design/construction errors, material under-strength, or overload. Fiber reinforced polymer (FRP) composite laminates in the form of sheets and/or strips are used in structurally deficient flat slab systems to enhance the two-way shear capacity, flexural strength, stiffness, and ductility. Glass FRP (GFRP) has been used successfully but carbon FRP (CFRP) sheets/strips/laminates are more commonly used as a practical alternative to other expensive and/or challenging methods such column enlargement. This article reviews the literature on the methodology and effectiveness of utilizing FRP sheets/strips and laminates at the column/slab intersection to enhance punching shear strength of flat slabs.

4.
Materials (Basel) ; 12(8)2019 Apr 12.
Article in English | MEDLINE | ID: mdl-31013765

ABSTRACT

Alkali-activated slag (AAS) is a promising alternative to ordinary Portland cement (OPC) as sole binder for reinforced concrete structures. OPC is reportedly responsible for over 5% of the global CO2 emission. In addition, slag is an industrial by-product that must be land-filled if not re-used. Therefore, it has been studied by many investigators as environmentally friendly replacement of OPC. In addition to recycling, AAS offers favorable properties to concrete such as rapid development of compressive strength and high resistance to sulfate attack. Some of the potential shortcomings of AAS include high shrinkage, short setting time, and high rate of carbonation. Using ground granulated blast furnace slag (GGBS) as an alternative to OPC requires its activation with high alkalinity compounds such as sodium hydroxide (NaOH), sodium sulfate (Na2SO3), sodium carbonate (Na2CO3), or combination of these compounds such as NaOH and Na2SO3. The mechanism of alkali-activation is still not fully understood and further research is required. This paper overviews the properties, advantages, and potential shortcomings of AAS concrete.

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