Liquid crystal behavior, photoluminescence and gas sensing: A new series of ionic liquid crystal imidazole and benzoimidazole bearing chalcone groups, synthesis and characterization.

Four new series of chalcones containing imidazole bromonium and benzimidazole bromonium salts with spacer alkyl chains (C n , n = 2 and 4) were synthesized and the chemical structure, thermal behavior, photoluminescence and gas sensing were characterized by several technical methods. The studies have indicated similar mesomorphic properties of the synthesized compounds, dependent on the terminal alkyl-chain and lengths of the alkoxy-spacer. Almost compounds with shorter alky chains, 4a-4e, 5a-5c, 6a-6c and 7a-7d, did not show liquid crystal properties, while the results of other compounds confirm the existence of smectic A in cooling and heating cycles. Photoluminescence of compounds 5a-5i and 7a-7i was also studied. The emission in the blue region reveals that the material has blue light emission properties. Sensing behavior of compounds 4i and 5i was investigated for NH3 and NO2 gases. The sensors exhibited high sensitivity toward NH3, while sensitivity toward the oxidizing gas NO2 is lower.

Synthesis of chitosan-ethylene glycol diglycidyl ether/TiO2 nanoparticles for adsorption of reactive orange 16 dye using a response surface methodology approach.

Chitosan-ethylene glycol diglycidyl ether/TiO2 nanoparticles (CS-EGDE/TNP) composite was synthesized to be biosorbent for the removal of reactive orange 16 (RO16) dye from aqueous solution. The CS-EGDE/TNP composite was characterized via BET, XRD, FTIR, and SEM-EDX techniques. Response surface methodology (RSM) with Box-Behnken design (BBD) was applied to optimize the adsorption key parameters such as adsorbent dose (A: 0.02-0.08 g/L), RO16 dye concentration (B: 20-80 mg/L), solution pH (C: 4-10), temperature (D: 30-50 °C), and contact time (E: 30-90 min). The adsorption isotherm followed Freundlich model and pseudo-second order (PSO) kinetic model. The adsorption capacity of CS-EGDE/TNP for RO16 dye was 1407.4 mg/g at 40 °C. The adsorption mechanism of RO16 dye on the surface of CS-EGDE/TNP can be attributed to various interactions such as electrostatic attraction, n-π interaction, Yoshida H-bonding, and H-bonding. Results supported the potential use of CS-EGDE/TNP as effective adsorbent for the treatment of acid reactive dye.

Box-Behnken design to optimize the synthesis of new crosslinked chitosan-glyoxal/TiO2 nanocomposite: Methyl orange adsorption and mechanism studies.

A crosslinked chitosan-glyoxal/TiO2 nanocomposite (CCG/TNC) was synthesized by loading different ratios of TiO2 nanoparticles into polymeric matrix of crosslinked chitosan-glyoxal (CCG) to be a promising biosorbent for methyl orange (MO). Box-Behnken design (BBD) in response surface methodology (RSM) was applied to optimize various process parameters, viz., loading of TiO2 nanoparticles into CCG polymeric matrix (A: 0%-50%), adsorbent dose (B: 0.04-0.14 g/50 mL), solution pH (C: 4-10), and temperature (D: 30-50 °C). The highest MO removal efficiency of 75.9% was observed by simultaneous interactions between AB, AC, and BC. The optimum TiO2 loading, adsorbent dosage, solution pH, and temperature were (50% TiO2: 50% chitosan labeled as CCG/TNC-50), 0.09 g/50 mL, 4.0, and 40 °C. The adsorption of MO from aqueous solution by using CCG/TNC-50 in batch mode was evaluated. The kinetic results were well described by the pseudo-first order kinetic, and the equilibrium data were in agreement with Langmuir isotherm model with maximum adsorption capacity of 416.1 mg/g. The adsorption mechanism included electrostatic attractions, n-π stacking interactions, dipole-dipole hydrogen bonding interactions, and Yoshida H-bonding.

Trichophyton fungal keratitis.

OBJECTIVE: To report 5 cases of fungal keratitis caused by Trichophyton schoenleinii. METHODS: Case reports. RESULTS: Trichophyton schoenleinii is responsible for aggressive fungal keratitis that is associated with keratolysis as a result of collagenase expression by the organism. Clinically, the organism seems to be sensitive to topical natamycin but resistant to topical amphotericin B and miconazole. Two patients achieved clinical cures with medical therapy alone, but with visual outcomes of only 20/125 and hand motions because of corneal scarring. Two patients achieved clinical cures with therapeutic penetrating keratoplasty (PKP), which remained clear and provided final visual outcomes of 20/60 and 20/200. One patient developed fungal scleritis and panophthalmitis despite 2 therapeutic PKPs and required enucleation. CONCLUSION: Trichophyton schoenleinii is a rare cause of fungal keratitis that may be associated with progressive keratolysis and perforation, scleral extension, and endophthalmitis. Therapeutic keratoplasty may be successful in achieving cure in medically unresponsive cases.