Transesterification of Jatropha curcas oil to biodiesel using highly porous sulfonated biochar catalyst: Optimization and characterization dataset.

The study involves a collection of data from the published article titled "Active sites engineered biomass-carbon as a catalyst for biodiesel production: Process optimization using RSM and life cycle assessment "Energy Conversion Management" journal. Here, the activated biochar was functionalized using 4-diazoniobenzenesulfonate to obtain sulfonic acid functionalized activated biochar. The catalyst was comprehensively characterized using XRD, FTIR, TGA, NH3-TPD, SEM-EDS, TEM, BET, and XPS analysis. Further, the obtained catalyst was applied for the transesterification of Jatropha curcas oil (JCO) to produce biodiesel. An experimental matrix was conducted using the RSM-CCD approach and the resulting data were analyzed using multiple regressions to fit a quadratic equation, where the maximum biodiesel yield achieved was 97.1 ± 0.4%, under specific reaction conditions: a reaction time of 50.3 min, a molar ratio of 22.9:1, a reaction temperature of 96.2 °C, and a catalyst loading of 7.7 wt.%. The obtained product biodiesel was analyzed using NMR and GC-MS analyzed and is reported in the above-mentioned article.

In vitro anti-prostate adenocarcinoma and lung cancer studies of phenoxyaniline-block-poly(methyl methacrylate) based nanocomposites via controlled radical polymerization.

A phenoxyaniline-based macroinitiator is utilized for the first time in order to produce phenoxyaniline-block-poly(methyl methacrylate) composites through single electron transfer-living radical polymerization (SET-LRP) under mild conditions. A different weight percentage of Cloisite 93A is added into the polymer mixtures in order to increase their biochemical properties. The prepared block copolymer nanocomposites are characterized using ATR-IR, UV-vis-spectroscopy, XRD, Raman, TGA, DSC, a particle size analyzer, contact angle measurements and SEM in order to characterize their structural, thermal, surface and morphological properties. Further, the developed polymeric nanocomposites are successfully applied in two different cancer cell lines (prostate adenocarcinoma and lung cancer), which show excellent anticancer properties. Also, acridine orange/ethidium bromide (AO/EtBr) dual staining is performed, which causes drastic cell death by apoptosis in both A549 and PC-3 cell lines, which indicated that the prepared polymeric nanocomposites effectively inhibit the cell proliferation and induce the apoptosis in both the cancer cells. Here nanoclay is used for cancer treatment because of its complete water solubility, which essentially causes the formation of a cationic complex between the clay and drug through electrostatic interactions. Hence, the exchange of ions between the clay and other ions in the biological environment leads to inhibition of the proliferation of prostate adenocarcinoma and lung cancer cells in the system.

Developments in Titanium-Based Alkali and Alkaline Earth Metal Oxide Catalysts for Sustainable Biodiesel Production: A Review.

Biodiesel represents a biodegradable, environmentally friendly, and renewable alternative to fossil fuels. Despite more than three decades of research, significant obstacles still hinder the widespread production of biodiesel. This current review elucidates both the potential and the existing challenges associated with homogeneous and heterogeneous catalysts in catalyzing biodiesel production, with a particular focus on alkali analogues, alkaline earth metal oxides, and titania-based catalysts. In particular, a comprehensive analysis is presented concerning alkali and alkaline earth-based titania (TiO2 ) catalysts. Among these, the alkaline earth metal oxides, including lithium, calcium, and strontium when combined with titanium-based catalysts, exhibit superior catalytic activity compared to other metal oxides, owing to their heightened basicity. Consequently, this review offers a thorough and up-to-date insight into the potential of titania-based heterogeneous catalysts for advancing biodiesel production.

Observation of inherited plasmonic properties of TiN in titanium oxynitride (TiOxNy) for solar-drive photocatalytic applications.

This study demonstrates the synthesis of titanium oxynitride (TiOxNy) via a controlled step-annealing of commercial titanium nitride (TiN) powders under normal ambience. The structure of the formed TiOxNy system is confirmed via XRD, Rietveld refinements, XPS, Raman, and HRTEM analysis. A distinct plasmonic band corresponding to TiN is observed in the absorption spectrum of TiOxNy, indicating that the surface plasmonic resonance (SPR) property of TiN is being inherited in the resulting TiOxNy system. The prerequisites such as reduced band gap energy, suitable band edge positions, reduced recombination, and enhanced carrier-lifetime manifested by the TiOxNy system are investigated using Mott-Schottky, XPS, time-resolved and steady-state PL spectroscopy techniques. The obtained TiOxNy photocatalyst is found to degrade around 98% of 10 ppm rhodamine B dye in 120 min and produce H2 at a rate of ∼1546 µmolg-1h-1 under solar light irradiation along with consistent recycle abilities. The results of cyclic voltammetry, linear sweep voltammetry, electrochemical impedance and photocurrent studies suggest that this evolved TiOxNy system could be functioning via plasmonic Ohmic interface rather than the typical plasmonic Schottky interface due to their amalgamated band structures in the oxynitride phase.

Aqueous, Non-Polymer-Based Perovskite Quantum Dots for Bioimaging: Conserving Fluorescence and Long-Term Stability via Simple and Robust Synthesis.

Perovskite quantum dots (PQDs) offer high photoluminescence quantum yields; however, due to their limited stability in aqueous media, to date their utilization in biomedical applications has been limited. The present work demonstrates highly fluorescent and stable aqueous PQDs that were synthesized using a facile engineered phase transfer method. Ligands were engineered to have a dual functionality, i.e., they could simultaneously mediate the strong binding of PQDs and the interactions with water molecules. The resultant water-soluble PQDs demonstrated robust structural and optical properties. The extracted aqueous PQDs remained stable in pellet form for 8 months, which was the entire test duration. Notably, 100% of their fluorescence was also retained. As a proof-of-concept experiment, the water-soluble PQDs were successfully tagged to polyclonal antibodies and used to image Escherichia coli cells in aqueous media. No structural or optical disturbance in PQDs was detected throughout the process. This work marks the beginning of the use of nonpolymeric aqueous PQDs and shows their strong potential to be used in biological applications.