1.
Chem Commun (Camb)
; (18): 1722-3, 2001 Sep 21.
Article
in English
| MEDLINE
| ID: mdl-12240283
ABSTRACT
Novel and readily accessible polymer-supported chiral magnesium amide reagents have been prepared and shown to be effective in the asymmetric deprotonation of a series of prochiral cyclohexanones, affording good to excellent levels of both conversion and enantiomeric ratio (up to 93:7); the Merrifield-based chiral amine species has been shown to be readily recyclable.