Impact of Particle Size on the Setting Behavior of Tricalcium Silicate: A Comparative Study Using ISO 6876 Indentation Testing and Isothermal Induction Calorimetry.

This study examines the impact of particle size on the setting behavior of tricalcium silicate powders. The setting behavior was evaluated using ISO 6876 indentation testing and isothermal induction calorimetry techniques. The objective was to compare the outcomes obtained from these methods and establish a correlation between particle size and setting characteristics. The cement pastes were manually mixed with a water-to-solid ratio of 0.66 for conducting indentation tests according to ISO 6876, while calorimetry measurements were performed using isothermal (conduction) calorimetry at room temperature. The findings demonstrate a significant influence of smaller particle sizes on accelerating the hydration process of cement pastes, resulting in a reduction of setting time by up to 24%. Moreover, the final setting times obtained through the indentation method closely approximate the inflection points of the acceleration curves acquired by calorimetry, with time deviations of less than 12% regardless of particle size.

Dissolution, bioactivity behavior, and cytotoxicity of 19.58Li2 O·11.10ZrO2 ·69.32SiO2 glass-ceramic.

Glass and bioactive glass-ceramic can be used in several applications. In bone growth where good bone/biomaterial adhesion was required, bioactive coatings for implants can improve bone formation. The glass and glass-ceramics of the LZS (Li2 O-ZrO2 -SiO2 ) system are very interesting because of their mechanical, electrical, and thermal properties. Very recently, their biological response in contact with human osteoblast has been evaluated. However, despite several initiatives, there are still no studies that systematically assess this system's bioactivity, dissolution, and cytotoxicity in vitro. This work aims to investigate the dissolution, bioactivity behavior, and cytotoxicity of LZS glass-ceramic. LZS glass-ceramics were produced from SiO2 , Li2 CO3, and ZrSiO4 by melting followed by quenching. The obtained glass frits were milled and uniaxially pressed and heat-treated at 800 and 900°C and submitted to physical-chemical, structural and mechanical characterization. Their dissolution behavior was studied in Tris-HCl, while bioactivity was performed in simulated solution body fluid (SBF). The cytotoxicity test was performed using glass-ceramic in direct contact with mesenchymal stem/stromal cells (SC) isolated from human exfoliated deciduous teeth. Structural and microstructural analyzes confirmed bioactivity. The results show that it was possible to produce bioactive glass-ceramic from LZS, proven by the formation of new calcium phosphate structures such as hydroxyapatite on the surface of the samples after exposure to SBF. The SC viability test performed indicated that the materials were not cytotoxic at 0.25, 0.5, and 1.0 mg/ml. The glass-ceramic system under study is very promising for a medicinal application that requires bioactivity and/or biocompatibility for bone regeneration.

Coal mining pyritic waste in Fenton-like processes: Raw and purified catalysts in Reactive Blue 21 dye discoloration.

Raw pyritic waste (RPW) from South Brazilian coal deposits and pure pyritic waste (PPW) were used as catalysts for organic dyes discoloration. Samples were characterized for their chemical, morphological, and structural properties. There was a significant content of Fe and S in both samples from the presence of iron sulfide. The average particle size is 10.9 µm for RPW and 7.4 µm for PPW, demonstrating that the beneficiation process could remove the larger quartz particles, interfered in the distribution, and average particle size. Smaller particle sizes promoted a larger surface area for the PPW. The influence of the pyritic waste in dosage, H2O2 concentration, and pH was evaluated, obtaining discoloration values above 95% for 0.5 g/L of pyritic waste, 2 g/L of H2O2, and pH 4.3 for both pyritic wastes. The degradation kinetics of the Reactive Blue 21 using the raw pyritic waste obtained a dye concentration removal above 93% in 90 min, with an iron release of 5.4 mg/L into the solution. Using PPW, the dye concentration removal was over 92% in 40 min, with the iron release of 15.5 mg/L into the solution. Discoloration rate for the PPW sample is 7 times greater than the rate obtained for RPW, indicating a faster decay rate for the purified sample. A decrease in discoloration efficiency is observed for PPW after 6 cycles of use, due to the higher concentration of iron leached into the medium. From the results, it was concluded that the raw pyritic waste has excellent potential for use as a catalyst for Fenton reaction, especially for dye-containing water discoloration, thus demonstrating the excellent applicability potential of pyritc waste in the degradation of organic pollutants in wastewater.

Aluminum anodizing waste and its uses: An overview of potential applications and market opportunities.

The aluminum anodizing process generates a large volume of waste composed mainly of amorphous aluminum hydroxide with chemical compatibility to be used in other industrial processes as an alternative starting raw material. This waste has several application possibilities such as the production of refractories, ceramic pigments, bricks, and many others. However, despite its potential features, its recycling process is far from well consolidated. This work highlights the most important contributions regarding Al-anodizing waste (AAW) features and their potential applications from the last 30 years. We provide the most complete and detailed characterization of AAW including chemical, physical, thermal, and microstructural analysis. The characterization analyzes were performed in a Brazilian waste sample and were compared with AAW worldwide. Additionally, our characterization results also considered differentiate previous processing; this, it many other possibilities are suggested that have not been explored thus far. The recycling feasibility of AAW is discussed according to the following criteria: classification, including legislation and standards; potentiality, including physical and chemical characteristics and purity; quantity, including production data; viability, including availability, costs regarding disposal and recycling process, and available technology for recycling; and applicability, including market opportunities. Moreover, alumina recovery from AAW and the related environmental aspects are discussed.

Combating pathogens with Cs2.5H0.5PW12O40 nanoparticles: a new proton-regulated antimicrobial agent.

The transfer of pathogens from contaminated surfaces to patients is one of the main causes of health care-associated infections (HCAIs). Cases of HCAIs due to multidrug-resistant organisms have been growing worldwide, whereas inorganic nano-antimicrobials are valuable today for the prevention and control of HCAIs. Here, we present a cesium salt of phosphotungstic heteropolyacid (Cs2.5H0.5PW12O40) as a promising nanomaterial for use in antimicrobial product technologies. This water-insoluble Keggin salt exhibits a broad biocide spectrum against Gram-positive and Gram-negative bacteria, yeasts, and filamentous fungi even under dark conditions. The Cs2.5H0.5PW12O40 nanoparticles (NPs) act as a proton-regulated antimicrobial whose activity is mediated on the release of hydronium ions (H3O+), yielding an in situ acidic pH several units below those tolerable by most of the fungal and bacterial nosocomial pathogens.

Mechanical and toxicological evaluation of concrete artifacts containing waste foundry sand.

The creation of metal parts via casting uses molds that are generally made from sand and phenolic resin. The waste generated after the casting process is called waste foundry sand (WFS). Depending on the mold composition and the casting process, WFS can contain substances that prevent its direct emission to the environment. In Brazil, this waste is classified according to the Standard ABNT NBR 10004:2004 as a waste Class II (Non-Inert). The recycling of this waste is limited because its characteristics change significantly after use. Although the use (or reuse) of this byproduct in civil construction is a technically feasible alternative, its effects must be evaluated, especially from mechanical and environmental points of view. Thus, the objective of this study is to investigate the effect of the use of WFS in the manufacture of cement artifacts, such as masonry blocks for walls, structural masonry blocks, and paving blocks. Blocks containing different concentrations of WFS (up to 75% by weight) were produced and evaluated using compressive strength tests (35 MPa at 28 days) and toxicity tests on Daphnia magna, Allium cepa (onion root), and Eisenia foetida (earthworm). The results showed that there was not a considerable reduction in the compressive strength, with values of 35 ± 2 MPa at 28 days. The toxicity study with the material obtained from leaching did not significantly interfere with the development of D. magna and E. foetida, but the growth of the A. cepa species was reduced. The study showed that the use of this waste in the production of concrete blocks is feasible from both mechanical and environmental points of view.