Phosphomolybdic acid supported on magnetic poly calix[4]resorcinarene-EDTA-chitosan network as a recyclable catalyst for the synthesis of 5-aroyl-NH-1,3-oxazolidine-2-ones.

In this work, a novel procedure for immobilization of phosphomolybdic acid (PMA) on Magnetic polycalix[4]resorcinarene grafted to chitosan by EDTA (calix-EDTA-Cs) was reported. The heterogeneous nanocomposite (CoFe2O4@calix-EDTA-Cs@PMA) was applied an acid nanocatalyst for the synthesis of 5-aroyl-NH-1,3-oxazolidine-2-ones through the reaction of α-epoxyketones with sodium cyanate (NaOCN) in polyethylene glycol (PEG) as a green solvent under ultrasonic irradiation conditions. Some features of this work include quick reaction time, high reaction yield, easy separation of the catalyst, thermal stability, and eco-friendly.

Rice husk-SiO2 supported bimetallic Fe-Ni nanoparticles: as a new, powerful magnetic nanocomposite for the aqueous reduction of nitro compounds to amines.

This paper reports a novel green procedure for immobilization of bimetallic Fe/Ni on amorphous silica nanoparticles extracted from rice husk (RH-SiO2). The heterogeneous nanocomposite (Fe/Ni@RH-SiO2) was identified using SEM, EDX, TEM, BET, H2-TPR, TGA, XRD, VSM, ICP-OES, and FT-IR analyses. The Fe/Ni@RH-SiO2 nanocomposite was applied as a powerful catalyst for the reduction of structurally diverse nitro compounds with sodium borohydride (NaBH4) in green conditions. This procedure suggests some benefits such as green chemistry-based properties, short reaction times, non-explosive materials, easy to handle, fast separation and simple work-up method. The catalyst was separated by an external magnet from the reaction mixture and was reused for 9 successive cycles with no detectable changes of its catalytic efficiency.