Effect of Surface Chemistry on the Squeeze-Thin Film and Friction of Boundary Films.

An approach combining adsorption characterization and lubricity effectiveness of amine-based friction modifier molecules has been performed using chemically controlled surfaces, coated either with cobalt or carbon, while keeping the surface roughness constant and sub-nanometric. Through squeeze measurements and numerical modeling, we have identified the mechanical properties of both adsorbed amine films, as a function of the surface on which they were formed. On the one hand, we were able to evidence that the fluid structuring at the vicinity of the adsorbed boundary film differed as a function of the latter mechanical properties, directly resulting from its molecular organization. On the other hand, we showed that the coverage ratio of the monolayer associated with the shear elastic modulus of the boundary film governed the friction level. Changing the surface chemistry while keeping the roughness constant controls the final organization in the boundary layer, the correlated mechanical properties, and the level of friction dissipation.

Effect of Unsaturation on the Adsorption and the Mechanical Behavior of Fatty Acid Layers.

Adsorption, self-organization, and mechanical properties of different fatty acid layers under different confinement states have been investigated as a function of the presence and conformation of one unsaturation in their aliphatic chain. In situ characterization, at the molecular level, was performed with the ATLAS molecular tribometer, in terms of rheology, forces, and thickness of confined fluid. The results demonstrate that the fatty acids adsorb on the surfaces by weak interactions and form viscoelastic films with a thickness of about 15 Å on each surface. The adsorption kinetics, the packing of the self-assembled monolayers, and the coverage rate depend on the molecular architecture of the fatty acids and lead to various mechanical behaviors under confinement.

Cryogenic measurements of mechanical loss of high-reflectivity coating and estimation of thermal noise.

We report on low-frequency measurements of the mechanical loss of a high-quality (transmissivity T<5 ppm at λ(0)=1064 nm, absorption loss <0.5 ppm) multilayer dielectric coating of ion-beam-sputtered fused silica and titanium-doped tantala in the 10-300 K temperature range. A useful parameter for the computation of coating thermal noise on different substrates is derived as a function of temperature and frequency.

Twin mirrors for laser interferometric gravitational-wave detectors.

Gravitational-wave detectors such as Virgo and the laser interferometric gravitational-wave observatory (LIGO) use a long-baseline Michelson interferometer with Fabry-Perot cavities in the arms to search for gravitational waves. The symmetry between the two Fabry-Perot cavities is crucial to reduce the interferometer's sensitivity to the laser amplitude and frequency noise. To this purpose, the transmittance of the mirrors in both cavities should be as close as possible. This paper describes the realization and the characterization of the first twin large low-loss mirrors with transmissions differing by less than 0.01%.

Ion beam sputtering coatings on large substrates: toward an improvement of the mechanical and optical performances.

Large mirrors (ø350 mm) having extremely low optical loss (absorption, scattering, wavefront) were coated for the VIRGO interferometer. The new generation of mirrors needs to have a better wavefront and lower mechanical loss. To improve the component wavefront, the corrective coating technique was used. By doping the tantalum pentoxide layers, we improved, for the first time to our knowledge, the multilayer mechanical loss. The first results are discussed.