Seawater neutralization of alkaline bauxite residue and implications for revegetation.

Reaction of bauxite residue with seawater results in neutralization of alkalinity through precipitation of Mg-, Ca-, and Al-hydroxide and carbonate minerals. In batch studies, the initial pH neutralization reaction was rapid (<5 min), with further reaction continuing to reduce pH for several weeks. Reaction with seawater produced a residue pH of 8 to 8.5. Laboratory leaching column studies were undertaken to provide information on seawater neutralization of the coarse-textured fraction of the waste, residue sand (RS), under conditions comparable with those that might be applied in the field. An 0.80-m-deep column of RS was neutralized by the application of the equivalent of 2-m depth of seawater. In addition to lowering the pH and Na content of the residue, seawater neutralization resulted in the addition of substantial amounts of the plant nutrients Ca, Mg, and K to the profile. Similar results were also obtained from a field-scale assessment of neutralization. However, the accumulation of precipitate, consisting of hydrotalcite, aragonite, and pyroaurite, in the drainage system may preclude the use of in situ seawater neutralization as a routine rehabilitation practice. Following seawater neutralization, RS remains too saline to support plant growth and would require fresh water leaching before revegetation.

An assessment of sulphide oxidation in abandoned base-metal tailings, Te Aroha, New Zealand.

Tailings from the Tui base-metal mine were characterized using a variety of techniques including scanning electron microscopy (SEM) and flame atomic absorption spectroscopy (FAAS), to assess their potential for use as a plant growth medium. With the notable exception of Pb (10 568 mg kg(-1)), 'total' metal concentrations in the surface tailings (0-200mm) were relatively low (Cu, 113; Fe, 3660; Zn, 486 mg kg(-1)). The theoretical acid generating potential (TAGP) and 'total' concentrations of Cu, Fe and Zn of the tailings, were found to increase greatly with depth, reflecting an increase in the abundance of chalcopyrite (CuFeS(2)), pyrite (FeS(2)) and sphalerite (ZnS), as detected by X-ray diffraction (XRD) analysis. SEM micrographs indicate that the distribution of sulphide minerals in the tailings was originally uniform with depth. The depletion of Cu, Fe and Zn in the surface tailings is considered to be a result of sulphide oxidation, as evidenced by the craggy and highly irregular morphology of the sulphide particles and the high hydrogen ion activity (pH 2.3-4.0) in this zone. The persistence of high concentrations of acid-generating sulphide minerals between 200 and 600 mm has important implications in determining strategies for revegetating the tailings.