ABSTRACT
This article presents the effect of the addition of condensed tannins, used as a reticulation agent, on the polymerization of furfuryl alcohol during wood furfurylation, as well as the effect of these condensed tannins on the thermal stability of modified wood. Three kinds of dicarboxylic acids (adipic acid, succinic acid, and tartaric acid), as well as glyoxal, used as model of a wood reticulation agent, were used to catalyze the polymerization of furfuryl alcohol or tannin-furfuryl alcohol solutions. Impregnation of furfuryl alcohol or tannin-furfuryl alcohol solution into the wood, followed by curing at 103 °C for a specific duration, was performed for the wood modification. The thermal stability of the obtained tannin-furfuryl alcohol polymers and their corresponding modified woods was investigated. The leaching resistance and dimensional stability of the modified woods were also evaluated. Results indicated that the partial substitution of furfuryl alcohol by the tannins improved the polymerization reactivity in conditions where furfuryl alcohol alone did not lead to the formation of a solid polymeric material. The thermal stability and leaching resistance of the furfurylated wood in the presence of tannins were improved. Dimensional stability was also improved for furfurylated samples, but the effect of tannin addition was not so obvious, depending on the acidic catalyst used.
ABSTRACT
This study concerns a scoping and literature review of nanocarbon and its composites with details on specific propositions, including nanocarbon history, nanocarbon types, and lignocellulose nanocarbon types, properties, applications, toxicity, regulation, and business model for commercialization. The review brings novelties, comprehensively expounding on laboratory studies and industrial applications of biomass or lignocellulose materials-derived nanocarbon and its composites. Since its first discovery in the form of Buckyball in 1985, nanocarbon has brought interest to scientists and industries for applications. From the previous studies, it is discovered that many types of nanocarbon are sourced from lignocellulose materials. With their excellent properties of nanomaterials, nanocarbon has been harnessed for such as reinforcing and filler agents for nanocomposites or direct use of individual nanocarbon for specific purposes. However, the toxicological properties of nanocarbon have delivered a level of concern in its use and application. In addition, with the radically growing increase in the use of nanocarbon, policies have been enacted in several countries that rule on the use of nanocarbon. The business model for the commercialization of lignocellulose-based nanocarbon was also proposed in this study. This study can showcase the importance of both individual nanocarbon and nanocarbon-based composites for industrial implementations by considering their synthesis, properties, application, country legislations/regulations, and business model. The studies also can be the major references for researchers to partner with industries and governments in investing in lignocellulose-sourced nanocarbon potential research, development, and policies.
Subject(s)
Lignin , NanocompositesABSTRACT
This study aimed to enhance tropical fast-growing tree species' resistance to subterranean termite (Coptotermes curvignathus) attacks through the manufacturing of polystyrene glued-laminated timber (glulam). Three young tropical wood species, namely manii (Maesopsis eminii), mangium (Acacia mangium), and rubber-wood (Hevea brasiliensis), were cut into laminae. After drying, the laminae were impregnated with styrene monomer, then polymerized using potassium peroxydisulfate as a catalyst and heat. The polystyrene-impregnated laminae were constructed using isocyanate glue and a cold press for three-layered glulam. Untreated or control glulam and solid wood specimens were also prepared. The specimens of each wood species and wood products (solid wood, control glulam, and polystyrene glulam) were exposed to the termite in a laboratory test according to Indonesian standards. The results showed that mangium wood had better resistance to the termite attack than manii and rubber-wood, with both of those woods performing the same. Among the wood products, the glulams were equal and had higher resistance to the termite attack than solid wood. To enhance the termite resistance of polystyrene glulam, we suggest that the polymer loading of polystyrene on each lamina should be increased. In our evaluation of the products' order of priority, polystyrene glulam emerged as performing best towards subterranean termites attack.
