Effective Adsorption of Congo Red from Aqueous Solution Using Fe/Al Di-Metal Nanostructured Composite Synthesised from Fe(III) and Al(III) Recovered from Real Acid Mine Drainage.

This study presents the first known exploration of Congo red dye (CR) adsorption by a polycationic Fe/Al Di-metal nanostructured composite (PDFe/Al) synthesised using Fe(III) and Al(III) recovered from authentic acid mine drainage (AMD). The PDFe/Al successfully removed CR from the aqueous solution. The mineralogical, microstructural, and chemical properties of the synthesised PDFe/Al adsorbent (before and after adsorption) were studied using state-of-the-art analytical instruments. The optimum conditions were observed to be 100 mg·L-1 CR, 1 g of the PDFe/Al in 500 mL adsorbate solution, 20 min of shaking, pH = 3-8, and a temperature of 35 °C. At optimised conditions, the PDFe/Al showed ≥99% removal efficacy for CR dye and an exceptionally high Langmuir adsorption capacity of 411 mg·g-1. Furthermore, a diffusion-limited adsorption mechanism was observed, with two distinct surfaces involved in the adsorption of CR from an aqueous solution. It was determined that the adsorption of CR induced internal strain and deformation within the matrices and interlayers of the PDFe/Al which resulted in a marked increase in the adsorbent pore surface area and pore volume. The remarkably high adsorption capacity could be attributed to the high surface area. A regeneration study showed that the adsorbent could be reused more than four times for the adsorption of CR. The findings from this study demonstrated the feasibility of recovering valuable minerals from toxic and hazardous AMD and demonstrated their potential for the treatment of industrial wastewaters.

Facile thermal activation of non-reactive cryptocrystalline magnesite and its application on the treatment of acid mine drainage.

In this study, the authors report a facile thermal activation of non-reactive cryptocrystalline magnesite and explore its application on the treatment of acid mine drainage (AMD). The primary aim was to optimize the calcination-water interface reactive conditions. Parameters evaluated include calcination temperature, calcination time, AMD-calcination temperature interface, and AMD-calcination duration interface. PHREEQC geochemical modelling was also applied to substantiate obtained results. The results indicated that the formation of MgO and CaO increase with an increase in calcination temperature and time. The optimum temperature and calcination time were observed to be 800 °C and 30 min in the furnace. The pH was observed to increase with an increase in calcination temperature and time but reached equilibrium at 800 °C and 30 min respectively. Geochemical modelling validated the formation of gypsum with attenuation in Ca ions and predicted the formation of MgSO4(aq). Metal species were observed to precipitate with an increase in pH. At 700 °C, Fe was completely removed, while Al, and Mn were completely removed from an aqueous system at 800 °C. This novel study invented the new calcination condition for non-reactive cryptocrystalline magnesite and proved its potential application in wastewater treatment. The calcination conditions were very short and therefore will save industries energy due to replacement of uneconomical and less environmental friendly pre-treatment options that lead to environmental degradation.