Experimental simulations of the photodecomposition of carbonates and sulphates on Mars.

There is indirect spectroscopic evidence for the presence of sulphates and carbonates on the martian surface, and such minerals are also found in SNC meteorites, which are thought to be of martian origin. But although carbonates are expected to be abundant in the martian regolith, attempts to detect them directly have been unsuccessful. Here we report laboratory studies of the decompostion of calcium carbonate and magnesium sulphate under ultraviolet irradiation, which mimic the conditions under which photodecomposition of surface minerals by solar ultraviolet light might occur on Mars. We find that, even for a low abundance of carbonate minerals in the martian regolith, the rate of CO2 release due to photodecomposition is higher than the rate of CO2 loss from the atmosphere by solar-wind-induced sputtering processes, making this process a potential net source of atmospheric CO2 over time. SO2 is also released from the sulphate, albeit more slowly. The rate of carbonate degradation is high enough to explain the apparent absence of these compounds at the martian surface.

Carbonaceous components in the comet Halley dust.

Cometary grains containing large amounts of carbon and/or organic matter (CHON) were discovered by in situ measurements of comet Halley dust composition during VEGA and GIOTTO flyby missions. In this paper, we report the classification of these cometary grains by means of cluster analysis, discuss the resulting compositional groups, and compare them with substances observed or hypothesized in meteorites, interplanetary dust particles, and the interstellar medium. Grains dominated by carbon and/or organic matter (CHON grains) represent approximately 22% of the total population of measured cometary dust particles. They usually contain a minor abundance of rock-forming elements as well. Grains having organic material are relatively more abundant in the vicinity of the nucleus than in the outer regions of the coma, which suggests decomposition of the organics in the coma environment. The majority of comet Halley organic particles are multicomponent mixtures of carbon phases and organic compounds. Possibly, the cometary CHON grains may be related to kerogen material of an interstellar origin in carbonaceous meteorites. Pure carbon grains, hydrocarbons and polymers of cyanopolyynes, and multi-carbon monoxides are present in cometary dust as compositionally simple and distinctive components among a variety of others. There is no clear evidence of significant presence of pure formaldehyde or HCN polymers in Halley dust particles. The diversity of types of cometary organic compounds is consistent with the interstellar dust model of comets and probably reflects differences in composition of precursor dust. Preservation of this heterogeneity among submicron particles suggests the gentle formation of cometary nucleus by aggregation of interstellar dust in the protosolar nebula without complete mixing or chemical homogenization at the submicron level.

Estimates of mass and angular momentum in the oort cloud.

Estimates can be made of unseen mass (in the form of cometary nuclei) at the heliocentric distances between 3 x 10(3) and 2 x 10(4) astronomical units(AU) under the assumptions (i) that the Oort cloud is a rarefied halo surrounding the core (dense, inner cometary cloud) and (ii) that the mass and albedo of comet Halley is typical for comets both in the core and the Oort cloud populations. The mass appears to be approximately 0.03 solar masses, with angular momentum of the order of 10(52) to 10(53) g-cm(2)/s. This mass is of the order of the total mass of the planetary system before the loss of volatiles. This leads to an estimate of a mass M(o) approximately 100 M( plus sign in circle) (where M( plus sign in circle) is the mass of Earth) concentrated in the Oort cloud (r > 2 x 10(4) AU) with an angular momentum that may exceed the present angular momentum of the whole planetary system by one order of magnitude. The present angular momentum of the Oort cloud appears to be of the same order as the total angular momentum of the planetary system before the loss of volatiles.

[Stimulating action of polyphosphates on peptide formation from glycine and phenylalanine amides under abiogenic conditions]. / O stimuliruiushchem deistvii polifasfatov na obrazovanie peptidov iz amidov glitsina i fenilalanina v abiogennykh usloviiakh.

Synthesis of peptides during polymerization of GlyNH2 and PheNH2 has been demonstrated by means of gel-chromatography and thin-layer chromatography. The optima of pH and temperature have been estimated for the reaction. Grem's salt, tripolyphosphate and pyrophosphate were shown to cause the stimulatory effect on the peptide formation, but there was no correlation between the yield of the peptides and the hydrolysis of the polyphosphates. On the basis of the experimental data, it has been concluded that hydrolysis of polyphosphates is not an energy source for the polymerization of GlyNH2 and PheNH2. Therefore, polyphosphates cause catalytic effect on the peptide synthesis from the amides of amino acids in homogeneous medium.

Role of interstellar molecules in prebiological evolution.

Three generations of organic molecules in space are considered: interstellar molecules, molescules synthesised in protosolar cloud and molecules synthesised on the Earth. It is shown that there is no possibilities for amino acid polymers to be synthesised under interstellar cloud conditions. Molecules of the second generation were disintegrated during the Earth accumulation period. The problem of the origin of life is connected with the evolution of molecules of the third generation.

Gas exchange ("soil breathing") in the detection of extraterrestrial life.

The major exobiological problem is the detection of life on other planets. The present paper presents experimental data on gas exchange between different samples of terrestrial soils and the atmosphere. The feasibility of applying the gas chromatographic technique to the detection of extraterrestrial life is discussed.