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New Fe(I) -Fe(I) complex featuring a rotated conformation related to the [2 Fe](H) subsite of [Fe-Fe] hydrogenase.

Munery, Sabrina; Capon, Jean-François; De Gioia, Luca; Elleouet, Catherine; Greco, Claudio; Pétillon, François Y; Schollhammer, Philippe; Talarmin, Jean; Zampella, Giuseppe.

Chemistry ; 19(46): 15458-61, 2013 Nov 11.

Article in English | MEDLINE | ID: mdl-24127299

ABSTRACT

Rotated geometry: The first example of a dinuclear iron(I)-iron(I) complex featuring a fully rotated geometry related to the active site of [Fe-Fe] hydrogenase is reported.

Subject(s)

Hydrogenase/chemistry , Iron Compounds/chemistry , Iron-Sulfur Proteins/chemistry , Iron/chemistry , Binding Sites , Crystallography, X-Ray , Models, Molecular , Molecular Conformation

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