Performance improvement of the osmotic microbial fuel cell by the pre-treatment of anaerobic sewage sludge using solenoid magnetic field.

This study explored the effect of a solenoid magnetic field (SOMF) as a pre-treatment on anaerobic sewage sludge (ASS) before using it in an osmotic microbial fuel cell (OMFC) as an inoculant. The ASS efficiency in terms of colony-forming unit (CFU) was improved ten times by applying SOMF compared to the control conditions. The obtained highest power density, current density, and water flux in the OMFC were 32.70 ± 5 mW·m-2, 135.13 ± 15 mA·m-2, and 4.24 ± 0.11 L·m-2h-1 respectively, for 72 h at 1 mT magnetic field. The coulombic efficiency (CE) and chemical oxygen demand (COD) removal efficiency were increased to 40-45% and 4-5% respectively, compared to un-treated ASS. Also, the start-up time of the ASS-OMFC system was almost reduced to 1-2 days based on open circuit voltage data. On the other hand, increasing the pre-treatment intensity of SOMF with time, it decreased the performance of OMFC. Also, the low intensity with increased pre-treatment time up to a specific limit enhanced the performance of OMFC.

Hydrothermal carbonization of cow dung with human urine as a solvent for hydrochar: An experimental and kinetic study.

Hydrothermal carbonization (HTC) is the most cost-effective, environmentally friendly, and efficient physicochemical and biochemical process for converting biomass to products with added value. The objective and novelty of this work is to produce and investigate the qualities of hydrochar fuel (as a solid fuel) from cow manure using human urine as a solvent in order to find a suitable replacement for conventional fuel (i.e., coal). HTC based studies were conducted in batch, at three different reaction temperatures (180 °C, 200 °C, and 220 °C) and two different reaction periods (2 and 4 h). For kinetic analysis and reaction mechanism of the combustion behavior of the produced hydrochar, the model free kinetic methods and the z-master plot were used. From the model free kinetics methods, it was observed that the resultant optimum average activation energy and pre-exponential factor for the produced hydrochar at 180 °C and 2 h reaction period (HTC_180_2) were ∼120 kJ/mol and ∼5.59 × 1025 sec-1, respectively. In addition, the little variation between ΔEα and ΔHα (∼10 kJ/mol) suggests that the combustion of produced hydrochar (HTC_180_2) occurred with minimal energy use. Furthermore, the hydrochar exhibited its highest heating value at 200 °C for 4 h (HTC_200_4) which was 1.44 times higher than the raw dung (13.4 MJ/kg) due to the HTC process. The produced hydrochar demonstrated a significant improvement compared to the conventional solvent, i.e. water.

Performance evaluation of deep eutectic solvent as a draw solute and vertical up-flow forward osmosis module for desalination of seawater.

Forward osmosis (FO) has gained prominence in recent years particularly in desalination due to its ability to operate at low or no hydraulic pressure, with relatively limited membrane fouling and high-water recovery. However, pre-treatment of seawater is required to reduce membrane fouling caused by the presence of suspended solid particles. Also, a significant area of research in forward osmosis is still finding a suitable draw solute (DS) with the ideal characteristics. In this study, a novel deep eutectic solvent (DES) draw solute was used and able to extract water after the 500% dilution of DS. This signifies it as the potential candidate for the ideal DS. A comparative study of plate and frame and vertical up-flow forward osmosis (VUF) FO modules has been evaluated to eliminate the drawbacks associated with FO in terms of membrane fouling and draw solute. In addition, the performance of a novel DES as reline (choline chloride-urea) has been tested in both the modules. In VUF module, significantly less fouling was observed than in the plate and frame module. The initial water flux in plate and frame module was 2.30 LMH with seawater (without pre-treatment) as feed. However, it dropped to 1 LMH after 26 h of run. However, initial water flux in VUF was 1.90 LMH, and it was maintained to 1.50 LMH after 89 h of run. Regeneration of draw solute was carried out using a phase separation method and it was observed that phase separation was only observed for 10% dilution of DES.

Performance of pilot-scale constructed wetland osmotic microbial fuel cell under different gravel conditions.

This paper explores the performance of pilot-scale constructed wetland osmotic microbial fuel cell (CW-OMFC) in different gravel conditions. The performance was measured in terms of power generation, water flux, chemical oxygen demand (COD) removal, and coulombic efficiency. The CW-OMFC was divided into four sections based on the porosity of the materials. The surface area of materials at Side A, Side B, Side C, and Side D were 2.717 m2.g-1, 0.228 m2.g-1, 0.095 m2.g-1, and 0.072 m2.g-1, respectively. The CW-OMFC achieved maximum water flux, minimum reverse salt flux, high power density, and COD removal efficiency of 6.66 ± 0.5 L.m-2.h-1, 3.33 ± 1.2 g.m-2.h-1, 59.53 ± 10 mW.m-2 and 84.69%, respectively, by using high porous materials. The nutrients (nitrogen, phosphorus, and potassium) uptake by plants from wastewater were 12.17%, 12.01%, and 21.73%, respectively.

Effects of temperature, pH, feed, and fertilizer draw solution concentrations on the performance of forward osmosis process for textile wastewater treatment.

Water is crucial for enhancing the yield of agricultural land to meet the growing demand. Forward osmosis (FO) is a developing technology that utilizes the natural osmotic gradient of solutions. In this study, fertilizer drawn FO setup was considered by using potassium chloride (KCl) as the draw solution (DS) for treating textile wastewater as the feed solution (FS). This study investigated the effects of FS temperature, pH, and FS and DS concentrations. The performance investigation involved the study in terms of water flux, reverse salt flux, and specific reverse salt flux. DS and FS properties, osmotic potential, and temperature played a vital role in the performance. At 30°C FS temperature, the highest water flux (5.5 LMH) was observed. Reverse salt flux increased due to the increase in solute diffusivity. The highest value of water flux was obtained at a DS of 1.150 M and FS of 1000 mg/L. The permeation of water improved due to the difference in DS and FS concentrations at pH values above 7. The results of this study suggest that KCl as DS has a higher potential for the treatment of textile wastewater at a temperature of 30°C. Additionally, the functional groups attached to the FO membrane were identified through Fourier-transform infrared (FTIR) spectroscopic study. PRACTITIONER POINTS: Treatment of textile wastewater with the use of fertilizer draw solution (KCl) by forward osmosis process as carried out. The performance was assessed in terms of water flux, reverse salt flux, and specific reverse salt flux. The effects of feed and fertilizer draw solution concentrations; pH and temperature were evaluated on the performance of FO process.

Physico-chemical and biological treatment strategies for converting municipal wastewater and its residue to resources.

An increase in urbanization and industrialization has not only contributed to an improvement in the lifestyle of people, but it has also contributed to a surge in the generation of wastewater. To date, conventional physico-chemical and biological treatment methods are widely used for the treatment of wastewater. However, the efficient operation of these systems require substantial operation and maintenance costs, and the application of novel technologies for the treatment and disposal of sludge/residues. This review paper focuses on the application of different treatment options such as chemical, catalyst-based, thermochemical and biological processes for wastewater or sludge treatment and membrane-based technologies (i.e. pressure-driven and non-pressure driven) for the separation of the recovered products from wastewater and its residues. As evident from the literature, a wide variety of treatment and resource recovery options are possible, both from wastewater and its residues; however, the lack of planning and selecting the most appropriate design (treatment train) to scale up from pilot to the field scale has limited its practical application. The economic feasibility of the selected technologies was critically analyzed and the future research prospects of resource recovery from wastewater have been outlined in this review.

A novel concept of Vertical Up-Flow Forward Osmosis reactor: Design, performance and evaluation.

Performance of the forward osmosis (FO) process is limited due to the decline in water flux and increase in reverse salt flux. In this study, a novel Vertical Up-Flow Forward Osmosis (VUF-FO) reactor was designed and evaluated for eight different contacting patterns of feed and draw agent (DA). The best contacting pattern was compared with the basic H-shape reactor. Pulsating inlets were used for the recirculation of the feed and DA which helped in improving the performance by reducing the concentration polarization on membrane. Water flux in FO (active layer facing feed side) and PRO (active layer facing draw side) mode was 12.75 and 16.28 L/m2hr (LMH) respectively for the contacting pattern R3 and R5 after 8 h of the process. While the water flux in the H-shape reactor was 9.12 and 12.54 LMH for FO and PRO mode respectively. Diffusional behavior of water flux and reverse salt flux were also evaluated for both the FO reactors. Water flux in the H-shape reactor was declined to more than 60% from its initial value in both the modes (i.e. FO and PRO) due to the concentration polarization on membrane. Only 10% decline in water flux was observed for the VUF-FO reactor. This showed a better consistency of water flux in the VUF-FO reactor. The reverse salt flux in the VUF-FO reactor was less than 85% compared to the H-shape reactor. Therefore, a novel designed reactor improved the overall performance of FO in terms of water flux and reverse salt flux.

Technologies for the recovery of nutrients, water and energy from human urine: A review.

The global demand for a constant supply of fertilizer is increasing with the booming of the population. Nowadays more focus is given to the recovery and reuse of the nutrients rather than synthesis of the fertilizer from chemicals. Human urine is the best available resource for the primary macronutrients (Nitrogen, Phosphorus and Potassium) for the fertilizer as it contains 10-12 g/L nitrogen, 0.1-0.5 g/L phosphorous and 1.0-2.0 g/L potassium. For the recovery of these nutrients from human urine, various technologies are available which requires source separation and treatment. . In this review, a wide range of the technologies for the treatment of source-separated human urine are covered and discussed in detail. This review has categorized the technologies based on the recovery of nutrients, energy, and water from human urine. Among the various technologies available, Bio-electrochemical technologies are environmental friendly and recovers energy along with the nutrients. Forward Osmosis is the best available technology for the water recovery and for concentrating the nutrients in urine, without or minimal consumption of energy. However, experimental work in this technology is at its prior stage. A single technology is still not sufficient to recover nutrients, water and energy. Therefore, integration of two or more technologies seems essential.

Photo-polymerization as a new approach to fabricate the active layer of forward osmosis membrane.

A novel approach is employed to prepare the active layer of the forward osmosis membrane by the photo-polymerization method. The poly (ethylene glycol) phenyl ether acrylate (PPEA) and methacrylic acid (MAA) are used as monomers. The emphasis is given to analysing the effect of monomer concentration on chemical functional groups of active layer, thermal stability, surface morphology, roughness, interfacial free energy, organic fouling tendency and osmotic flux performance. The functional groups of the active layer are characterized by ATR-FTIR. Furthermore, thermal analysis (TGA/DTG) is performed to calculate grafting density and thermal stability of prepared FO membranes. Surface morphology and roughness are characterized by atomic force microscopy (AFM). Unlike control polyamide active layer membrane that suffered from organic fouling (28.14 ± 3.70% flux decline and 95% flux recovery), the photo-polymerized 75/25 active layer FO membrane demonstrated the low fouling propensity (2.77 ± 0.62% flux decline) and high flux recovery (nearly ~100%). The interfacial free energy and low fouling property of 75/25 FO membrane is also reflected in improved osmotic flux performance with 11.20 ± 0.79 L/g (AL-FS) and 8.41 ± 0.22 L/g (AL-DS) reverse solute flux selectivity (RSFS) (Jw/Js) than control polyamide FO membrane (7.94 ± 0.22 L/g (AL-FS) and 7.64 ± 0.54 L/g (AL-DS)).

Effect of TiO2 nanoparticles on UASB biomass activity and dewatered sludge.

The accumulation of the nanowastes in the wastewater treatment plants has raised several concerns; therefore, it is an utmost priority to study the nanoparticle (NP) toxicity in such systems. In this work, the effect of TiO2 NPs on up-flow anaerobic sludge blanket (UASB) microflora and their photocatalytic effect on dewatered sludge were studied. We observed 99.98% removal of TiO2 NPs by sludge biomass within 24 h, though negligible toxicity was found up to 100 mg/L TiO2 concentration on extracellular polymeric substances (EPS), volatile fatty acid and biogas generation. The low toxicity corresponds to the agglomeration of TiO2 NPs in UASB sludge. Alterations in dewatered sludge biochemical composition and increase in cell damage were observed upon exposure to sunlight as evidenced by FTIR and fluorescent microscopy, respectively. Results suggest the negligible toxicity of TiO2 NPs on UASB biomass activity; however, once exposed to open environment and sunlight, they may exert detrimental effects.

Effect of multiwalled carbon nanotubes on UASB microbial consortium.

The continuous rise in production and applications of carbon nanotubes (CNTs) has grown a concern about their fate and toxicity in the environment. After use, these nanomaterials pass through sewage and accumulate in wastewater treatment plants. Since, such plants rely on biological degradation of wastes; their activity may decrease due to the presence of CNTs. This study investigated the effect of multiwalled carbon nanotubes (MWCNTs) on upflow anaerobic sludge blanket (UASB) microbial activity. The toxic effect on microbial viability, extracellular polymeric substances (EPS), volatile fatty acids (VFA), and biogas generation was determined. The reduction in a colony-forming unit (CFU) was 29 and 58 % in 1 and 100 mg/L test samples, respectively, as compared to control. The volatile fatty acids and biogas production was also found reduced. The scanning electron microscopy (SEM) and fluorescent microscopy images confirmed that the MWCNT mediated microbial cell damage. This damage caused the increase in EPS carbohydrate, protein, and DNA concentration. Fourier transform infrared (FTIR) spectroscopy results supported the alterations in sludge EPS due to MWCNT. Our observations offer a new insight to understand the nanotoxic effect of MWCNTs on UASB microflora in a complex environment system.

Fabricated nanoparticles: current status and potential phytotoxic threats.

Nanotechnology offers unique attributes to various industrial and consumer sectors, and has become a topic of high interest to scientific communities across the world. Our society has greatly benefitted from nanotechnology already, in that many products with novel properties and wide applicability have been developed and commercialized. However, the increased production and use of nanomaterials have raised concerns about the environmental fate and toxicological implications of nanoparticles and nanomaterials. Research has revealed that various nanomaterials may be hazardous to living organisms. Among biota, plants are widely exposed to released nanomaterials and are sensitive to their effects. The accumulation of nannmaterials in the environment is a potential threat, not only because of potential damage to plants hut also because nanoparticles may enter the food chain. Although the literature that addresses the safety of nanoproducts is growing, little is known about the mechanisms by which these materials produce toxicity on natural species, including humans. In this paper, we have reviewed the literature relevant to what phytotoxic impact fabricated nanoparticles (e.g., carbon nanotubes, metallic and metal oxide nanoparticles, and certain other nanomaterials) have on plants. Nanoparticles produce several effects on plant physiology and morphology. Nanoparticles are known to affect root structure, seed germination, and cellular metabolism. Nanoparticles inhibit growth, induce oxidative stress, morphogenetic abnormalities and produce clastogenic disturbances in several plant species. The size, shape and surface coating of NPs play an important role in determining their level of toxicity. Of course, the dose, route of administration, type of dispersion media, and environmental exposure also contribute to how toxic nanoparticles are to plants. Currently, nanotoxicity studies are only in their initial phases of development and more research will be required to identify the actual threat nanoproducts pose to the plant system. To date, data show that there is a large variation in the phytotoxicity caused by different NPs. Moreover, the studies conducted thus far have mostly relied on microscopy to detect effects. Studies that incorporate measures and analyses undertaken with more modern tools are needed. Among new data that are most urgently needed on NPs is how fabricated NPs behave once released into the environment, and how exposure to them may affect plant resistance, metabolic pathways, and plant genetic responses. In this review, we have attempted to collect, present and summarize recent findings from the literature on nanoparticle toxicity in plants. To strengthen the analysis, we propose a scheme for accessing NP toxicity. We also recommend how the potential challenges presented by increased production and release of NPs should be addressed. It is our belief and recommendation that every nanomaterial-based product be subjected to appropriate toxicity and associated assessment before being commercialized.