1.
Dalton Trans
; 39(5): 1198-200, 2010 Feb 07.
Article
in English
| MEDLINE
| ID: mdl-20104344
ABSTRACT
We report a one-step synthesis of the phosphine, PPh(2)(i)C(3)F(7) from commercially available precursors. The stereoelectronic properties of the phosphine were probed by coordination to transition metals. Mo(CO)(5)PPh(2)(i)C(3)F(7) was synthesised and the synthesis and structure of trans-PtCl(2)(PPh(2)(i)C(3)F(7))(2) are described. PPh(2)(i)C(3)F(7) was found to be a bulky electron-withdrawing ligand.
Subject(s)
Coordination Complexes/chemical synthesis , Phosphines/chemistry , Phosphines/chemical synthesis , Coordination Complexes/chemistry , Crystallography, X-Ray , Molecular Conformation , Stereoisomerism , Transition Elements
2.
Chem Commun (Camb)
; (35): 4479-80, 2005 Sep 21.
Article
in English
| MEDLINE
| ID: mdl-16136257
ABSTRACT
Tris(perfluoroalkyl)phosphines, of interest as tunable alternatives to the carbon monoxide ligand, can be synthesised by the nucleophile mediated reaction of perfluoroalkyltrimethylsilanes with triphenylphosphite; the method can be extended to diphosphines.
