ABSTRACT
In Kenya, 57% of the municipal solid waste generated is Food waste (FW) which has high organic content. However, the treatment and bioconversion of FW to biogas have always been challenging due to its rapid biodegradation, resulting from rapid hydrolysis and accumulation of volatile fatty acids and lowering pH in the bioreactor. In this study, the anaerobic digestibility of FW as a mono substrate was compared to co-digestion of FW with water hyacinth (WH) for improved biogas production and organic matter removal efficiency in a laboratory batch reactor. Different mix proportions of FW and WH were co-digested under mesophilic conditions (37 °C) at a dilution of 6% (w/v) Total Solids (TS) content. The TS of the substrates (Food waste and Water Hyacinth) were pre-processed to have a concentration of TS at 6% (60 g/L) to operate a wet AD which requires the substrate to be less than 15% TS. The proportions of WH: FW (v/v) were 100:0, 85:15, 70:30, 55:45, 30:70, 15:85, and 0:100. In the batch rectors the anaerobic co-digestion was conducted with Substrate to Inoculum (S/I) ratio of 1:1. FW is generally considered to have high volatile solids which hydrolyze rapidly lowering pH arising from excess production of Hydrogen which in presence of CO2 and acetogenic bacteria leads to more production of acetate, formate and other long chain fatty acids which inhibits methanogenesis as a result of rapid acidification. The rapid acidification of the bioreactors that are used to treat FW results in the inhibition of the methanogenesis process. The co-digestion of the substrates could have improved the process parameters by reducing acidity caused by the high C/N ratio, reducing the inhibitory range, and increasing the buffer capacity which enhanced the bio-methane potential and the microbial activity. The batch experiments were set in triplicate for both cases of FW, WH, mixtures, and Inoculum. The results showed that the average gas yields after 81 days for the various mix proportions were 256.27and 357.69 ml/g-VS for mono-digestion of WH and FW respectively. For the mixtures of WH: FW the average reported biogas production were 305.01, 280.27, 548.91,616.01 and 270.87 ml/g-VS for mixtures of 15:85, 30:70, 55:45,70:30 and 85:15 respectively. The modified Gompertz model showed that the digesters with WH and FW alone had lag times of 2.599 and 1.052 days respectively. The mix substrates of WH: FW 85:15, 70:30, 55:45, 30:70 and 15:85 shown lag times of 2.456, 3.777, 2.574, 1.956 and 1.75 days respectively. A mix (WH: FW) of 70:30 had the highest maximum specific biogas production Rmax and the maximum biogas production potential of 18.19 mlCH4/gVS per day and 607.7mlCH4/gVS respectively. The R2 and RSME values ranged from 0.9867 to 0.9963 and 2.663 to 9.359 respectively in all the digesters. The study shows that the co-digestion of WH and FW in the mix ratio of 70:30 improved the volume of biogas produced and organic matter removal efficiency reached 79%.
ABSTRACT
Over reliance on charcoal has accelerated deforestation in sub-Saharan Africa. Seeking alternative sustainable and environmentally friendly sources of biomass energy to meet the escalating energy demand is therefore vital. However, limited evidence exists on the concentrations of toxic emissions of different biomass fuels. Herein, dried human faeces and sawdust were pyrolyzed at 350 °C to produce biochar and mixed in equal ratio to produce briquettes through densification, with molasses (10 wt.%) used as a binder. A comparative study on the heating properties and emission level of carbon monoxide (CO), nitric oxide (NO), and hydrogen sulphide (H2S) during combustion of charcoal, and co-combustion (50:50 wt. %) of charcoal with briquettes was conducted. The thermal profile of the flue gases indicated rapid combustion of volatile gases followed by slow oxidation of the char. Co-combustion significantly (P < 0.05) enhanced the amount of heat energy released with flue gases temperatures reaching a peak of 475 °C. The briquettes had a gross calorific value of 19.8 MJ/kg which was lower than 25.7 MJ/kg for charcoal. Combustion of charcoal did not emit NO, however the concentration of CO was above the critical short term limits of 35 ppm. The concentration of CO and H2S was above the short term exposure limits of 35 ppm, and 0.005 ppm, respectively, during co-combustion, whereas NO concentration was below dangerous exposure levels of 100 ppm. These results suggest that co-combustion of charcoal with the briquettes is a promising approach to generate safe and sufficient heat energy for cooking and reduce deforestation.
ABSTRACT
Enrichment of water bodies with nutrients from wastewater is one of the causes of eutrophication to aquatic ecosystems. This study investigated the use of biochar derived from rice husk, coconut husk, and coffee husk in adsorbing nitrates (NO3-N) and nitrites (NO2-N) from slaughterhouse wastewater. It also explored the desorption efficiencies of the adsorbed nutrients to ascertain the applicability of the enriched biochars as slow-release fertilizers. To characterize the physicochemical properties of the biochars, scanning electron microscopy (SEM) was used. Fourier transforms infrared spectroscopy (FTIR), elemental analysis (CHNO) Langmuir and Freundlich, and the isotherm models were employed to fit the experimental equilibrium adsorption data. It was observed that the Langmuir isotherm model has the best fit of NO3- N and NO2- N on all the biochars. And this was based on the coefficient of correlation values. Also, the coconut husk biochar has the highest adsorption capacities of NO3-N and NO2-N at 12.97 mg/g, and 0.244 mg/g, respectively, attributing to its high porosity as revealed by the SEM images. The adsorption capacities for the rice husk char were 12.315 and 0.233 mg/g, while that for coffee husk char were12.08 mg/g and 0.218 mg/g for NO3-N and NO2-N, respectively. The relatively higher amount of NO3-N adsorbed to that of NO2-N could be attributed to its higher initial concentration in the solution than nitrite concentration. The desorption efficiencies of nitrates were 22.4, 24.39, and 16.79 %, for rice husk char, coconut husk char and coffee husk char, respectively. For the rice husk char, coconut husk char and coffee husk char, the nitrites desorption efficiencies were 80.73, 91.39, and 83.62 %, respectively. These values are good indicators that the studied biochar can be enriched with NO3- N and NO2- N and used as slow-release fertilizers.
ABSTRACT
Human urine is a rich source of nitrogen which can be captured to supplement the existing sources of nitrogen fertilizers thus contributing to enhanced crop production. However, urine is the major contributor of macronutrients in municipal wastewater flows resulting into eutrophication of the receiving water bodies. Herein, pineapple peel biochar (PPB), and lateritic soil (LS) adsorbents were prepared for the safe removal of ammonium nitrogen (NH4+-N) from human urine solutions. Physicochemical properties of PPB, and LS were characterized by scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA) to investigate the relationship of their properties with NH4+-N adsorption. Langmuir, Freundlich, and Dubinin-Radushkevich (D-R) isotherm models were employed to correlate the experimental equilibrium adsorption data. The effect of contact time and initial concentration of NH4+-N adsorption was also evaluated. The D-R isotherm model best described the behaviour of NH4+-N adsorption on both PPB and LS based on the coefficient of correlation values. This model showed that the adsorption of NH4+-N on both samples was a physical process with PPB and LS having mean surface adsorption energies of 1.826 × 10-2, and 1.622 × 10-2 kJ/mol, respectively. The PPB exhibited a slightly higher adsorption capacity for NH4+-N (13.40 mg/g) than LS (10.73 mg/g) with the difference attributed to its higher surface area and porosity. These values are good indicators for assessing the effectiveness of the materials for adsorption of NH4+-N from human urine.
