Submicrometer dimple array based interference color field displays and sensors.

We report a technique for producing bright color fields over extended surfaces, via optical interference, with the capability of producing arbitrary visible colors in areas as small as 100 microm2. Periodic arrays of submicrometer dimples are fabricated on reflective silicon surfaces, and diffraction-induced mutual interference of light reflected from the upper and lower levels of the dimpled surfaces generates color depending on wavelength scaled dimple depth and periodicity. Colors of the entire visible spectrum can be generated by dimple arrays with different dimple depths. The topological permeability of such an open surface readily allows infusion of liquids, with different refractive indices, for color switching and detection. These easy to fabricate, scalable, robust devices, on solid as well as flexible supports, could find a wide range of applications such as cheap high-resolution printable dye/pigment-free displays, reliable index-of-refraction sensors with color readout for liquids, and lab-on-chip liquid flow monitors.

Fatigue resistance of aligned carbon nanotube arrays under cyclic compression.

Structural components subject to cyclic stress can succumb to fatigue, causing them to fail at stress levels much lower than if they were under static mechanical loading. However, despite extensive research into the mechanical properties of carbon nanotube structures for more than a decade, data on the fatigue behaviour of such devices have never been reported. We show that under repeated high compressive strains, long, vertically aligned multiwalled nanotubes exhibit viscoelastic behaviour similar to that observed in soft-tissue membranes. Under compressive cyclic loading, the mechanical response of the nanotube arrays shows preconditioning, characteristic viscoelasticity-induced hysteresis, nonlinear elasticity and stress relaxation, and large deformations. Furthermore, no fatigue failure is observed at high strain amplitudes up to half a million cycles. This combination of soft-tissue-like behaviour and outstanding fatigue resistance suggests that properly engineered nanotube structures could mimic artificial tissues, and that their good electrical conductivity could lead to their use as compliant electrical contacts in a variety of applications.

Nanospring pressure sensors grown by glancing angle deposition.

Arrays of Cr zigzag nanosprings and slanted nanorods, 15-55 nm and 40-80-nm-wide, respectively, were grown on SiO2/Si substrates by glancing angle deposition. The arrays exhibit a reversible change in resistivity upon loading and unloading, by 50% for nanosprings and 5% for nanorods, indicating their potential as pressure sensors. The resistivity drop is due to a compression of nanosprings (by a measured 19% for an applied external force of 10(-10) N per spring), which causes them to physically touch their neighbors, providing a path for electric current to flow between nanosprings. Repeated loading and unloading at large loads (> or =1 MPa) results in irreversible plastic deformation and a degradation of the pressure sensitivity.

Direct growth of aligned carbon nanotubes on bulk metals.

There are several advantages of growing carbon nanotubes (CNTs) directly on bulk metals, for example in the formation of robust CNT-metal contacts during growth. Usually, aligned CNTs are grown either by using thin catalyst layers predeposited on substrates or through vapour-phase catalyst delivery. The latter method, although flexible, is unsuitable for growing CNTs directly on metallic substrates. Here we report on the growth of aligned multiwalled CNTs on a metallic alloy, Inconel 600 (Inconel), using vapour-phase catalyst delivery. The CNTs are well anchored to the substrate and show excellent electrical contact with it. These CNT-metal structures were then used to fabricate double-layer capacitors and field-emitter devices, which demonstrated improved performance over previously designed CNT structures. Inconel coatings can also be used to grow CNTs on other metallic substrates. This finding overcomes the substrate limitation for nanotube growth which should assist the development of future CNT-related technologies.