ABSTRACT
Stable propagation of multifilament arrays in transparent bulk media with adjustable separation distances between adjacent child filaments has always been desired for advanced manufacturing. Here, we report on the generation of an ionization-induced volume plasma grating (VPG) by the interaction of two batches of noncollinearly propagating arrays of multiple filaments (AMF). The VPG can externally arrange the propagation of the pulses along regular plasma waveguides via spatial reconstruction of electrical fields, which is compared with the self-formation of randomly distributed multiple filamentation originated from noises. The separation distances of filaments in VPG are controllable by readily changing the crossing angle of the excitation beams. In addition, an innovative method to efficiently fabricate multidimensional grating structures in transparent bulk media through laser modification using VPG was demonstrated.
ABSTRACT
Hydrogenated crystalline TiO2 with oxygen vacancy (OV) defect has been broadly investigated in recent years. Different from crystalline TiO2, hydrogenated amorphous TiO2-x for advanced photocatalytic applications is scarcely reported. In this work, we prepared hydrogenated amorphous TiO2-x (HA-TiO2-x) using a unique liquid plasma hydrogenation strategy, and demonstrated its highly visible-light photoactivity. Density functional theory combined with comprehensive analyses was to gain fundamental understanding of the correlation among the OV concentration, electronic band structure, photon capturing, reactive oxygen species (ROS) generation, and photocatalytic activity. One important finding was that the narrower the bandgap HA-TiO2-x possessed, the higher photocatalytic efficiency it exhibited. Given the narrow bandgap and extraordinary visible-light absorption, HA-TiO2-x showed excellent visible-light photodegradation in rhodamine B (98.7%), methylene blue (99.85%), and theophylline (99.87) within two hours, as well as long-term stability. The total organic carbon (TOC) removal rates of rhodamine B, methylene blue, and theophylline were measured to 55%, 61.8%, and 50.7%, respectively, which indicated that HA-TiO2-x exhibited high wastewater purification performance. This study provided a direct and effective hydrogenation method to produce reduced amorphous TiO2-x which has great potential in practical environmental remediation.
ABSTRACT
Two aggregation-induced emission (AIE) macrocycles (DMP[5]-TPE and PCP[5]-TPE) were prepared by embedding Tetraphenylethene (TPE) unit into the skeletons of Dimethoxypillar[5]arene (DMP[5]) and [15]Paracyclophane ([15]PCP) at meso position, respectively. In crystal, the PCP[5]-TPE showed a distorted cavity, and the incubation of hexane inside the DMP[5]-TPE cavity caused a distinct change in the molecular conformation compared to PCP[5]-TPE. There was no complexation between PCP[5]-TPE and 1,4-dicyanobutane (DCB). UV absorption experiments showed the distorted cavity of DMP[5]-TPE hindered association with DCB.
ABSTRACT
Optical frequency combs, consisting of well-controlled equidistant frequency lines, have been widely used in precision spectroscopy and metrology. Terahertz combs have been realized in quantum cascade lasers (QCLs) by employing either an active mode-locking or phase seeding technique, or a dispersion compensator mirror. However, it remains a challenge to achieve the passive comb formation in terahertz semiconductor lasers due to the insufficient nonlinearities of conventional saturable absorbers. Here, a passive terahertz frequency comb is demonstrated by coupling a multilayer graphene sample into a QCL compound cavity. The terahertz modes are self-stabilized with intermode beat note linewidths down to a record of 700 Hz and the comb operation of graphene-coupled QCLs is validated by on-chip dual-comb measurements. Furthermore, the optical pulse emitted from the graphene-coupled QCL is directly measured employing a terahertz pump-probe technique. The enhanced passive frequency comb operation is attributed to the saturable absorption behavior of the graphene-integrated saturable absorber mirror, as well as the dispersion compensation introduced by the graphene sample. The results provide a conceptually different graphene-based approach for passive comb formation in terahertz QCLs, opening up intriguing opportunities for fast and high-precision terahertz spectroscopy and nonlinear photonics.
ABSTRACT
Efficient terahertz and photoelectron emission were observed from nano-porous gold (NPG) films deposited on an intrinsic gallium arsenide (GaAs) semiconductor substrate stimulated by femtosecond laser with pulse width of 60 fs. Time-domain THz emission and reflection spectroscopy confirmed that the free charges accelerated by irradiated femtosecond laser pulses transferred from the NPG films into the GaAs substrates. Accordingly, charges accumulation was reduced in the NPG films, resulting in a stronger emission of THz pulse than that from NPG films deposited on SiO2 substrate. Charges injected into the GaAs substrate enforced an observable decrease of the THz refractive index proportional to the intensity of incident light. In comparison, for NPG deposited on glass substrates, laser induced free charges were accumulated in the NPG films, and femtosecond laser pulses irradiating on the NPG films made no changes of the THz refractive index of the glass substrates.
ABSTRACT
We present direct observation of filamentary plasma grating induced by interference between two noncollinear infrared femtosecond pulses in water by doping with gold nanoparticles. The gold nanoparticles act as scattering media in water and visualize the fine structure of local optical fields of plasma grating. By measuring the variation of local conductivity as laser undergoes filamentation in water, the generated electron density in water is qualitatively studied. Significant enhancement of local electron density is observed at the intersecting region as two laser beams form plasma grating, indicating the breakthrough of clamped intensity of a conventional filament in water.
ABSTRACT
We experimentally demonstrated that nonlinear filament interaction could spectrally modulate terahertz (THz) radiation generated from asymmetric two-color filaments. It was the spatial plasma density modulation in plasma channels that induced the THz spectral modulation. As a result of optical manipulation of electron density in the filamentary plasma gratings, the proportion of high-frequency THz spectra increased, while that of low-frequency THz spectra decreased, indicating that the increase of free electron density in the filamentary plasma grating brought about THz frequency upshifts.
