ABSTRACT
Shear thickening fluids (STFs) refer to non-Newtonian fluids of the dilatant variety, wherein their viscosity experiences a significant surge with an escalation in the shear rate. In this investigative work, the friction behavior between yarns (pull-out) and absorption of static and kinetic energy during the phenomenon of friction between yarns in STFs are performed by monophase (MP-STF) adding nano SiO2 and dual-phase (MP-STF) adding carbon nanotubes. The ρ-Aramid fabrics were reinforced via the "foulard process", and carried out on MP-STF, and DP-STF/ρ-Aramid-impregnated fabrics to evaluate and compare with the enhancement in interfacial friction properties between yarns. The results showed that DP-STF has more significant than MP-STF and MP-STF in ultimate load, kinetic shear stress, static shear stress, and friction energy level effects. The DP-STF exhibits various friction enhancement mechanisms at the yarn interface, leading to higher absorption of static and kinetic energy related to interfacial friction, as indicated by the results obtained. Furthermore, the DP-STF/ρ-Aramid impregnated fabrics exhibited ultimate load (22.23 ± 0.522 N), kinetic shear stress (35.73 ± 0.850 MPa*100), static shear stress (36.28 ± 0.900 MPa*100), and friction energy level (610.33 ± 0.250). Increased ultimate load (581.7% and 180.7%), kinetic shear stress (621.4% and 174.6%), static shear stress (550.5% and 159.1%), and friction energy level (680.2 and 186.7%) compared to WT-STF and MP-STF, respectively. The current discoveries hold immense potential for various applications in the fields of engineering and smart material technologies. These applications span a multiplicity of industries, including sports products, medical advancements, space technology, as well as protective and shielding products.
ABSTRACT
The use of Kevlar in the field of ballistic and stabbing protection has been studied by researchers in polymeric composites for this purpose. This study presents complementary knowledge on energy absorption and dissipation in ρ-aramid fabric impregnated with shear thickening fluids (STFs), especially aiming to obtain better protection against impacts that are deeply associated with STFs, as well as color change, accelerated aging (QUV), and penetration depth (drop tower test). In addition, Scanning Electron Microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR) was performed. The research shows that there was a good distribution of STF particles on the ρ-Aramid fabric surface, promoting increased friction between the interfilament and the yarns, further increasing performance and, consequently, improving the energy absorption and dissipation mechanism and, also, the penetration effectiveness in relation to non-impregnated ρ-Aramid fabric. Regarding the protection efficiency against UV exposure (250-400 nm region), there was a significantly decreased compared to those non-impregnated Kevlar® woven with STFs. The FTIR analysis showed that the conditions of aging, after exposure to UV, did not produce new functional groups, that is, there was no chemical modification. Finally, Kevlar fabric impregnated with STFs improved penetration depth performance with the blades independent of the blade type with up to 81% increase in resistance. This result was improved due to interactions between the nanoparticles present in STFs, yarns, and even high-performance woven impregnated with shear-thickening fluids.
ABSTRACT
The application of nanocoatings in the textile finishing is increasingly being explored because they open a whole new vista of value-addition possibilities in the textile sector. In the present work, low temperature pulsed DC magnetron sputtering method was used to create functional TiO2 nanocoatings on poly(lactic acid) textile fibres surfaces. In this study, the principal objectives in the application of TiO2 nanocoatings to textile materials are to impart UV protection functions and self-cleaning properties to the textile substrates. The TiO2 films were characterized by X-ray diffraction, scanning electron microscopy, atomic force microscopy, transmission electron microscopy, UV-visible spectroscopy and contact angle analysis. The Photocatalytic activity of the films was tested by measuring the photodegradation rates of rhodamine-B dye aqueous solution under UV light irradiation. The ultraviolet protection function was tested according to the Australian/New Zealand standards. It was observed that the TiO2 nanocoatings on poly(lactic acid) fibres showed an excellent ultraviolet protection (> 40) function and the photocatalytic efficiency was maintained even after a strong washing treatment.
