Conductometric investigation of nano MnSO4 association parameters and complex formation with glycylglycine in aqueous and methanol-water mixtures: Thermodynamic parameters and potential applications.

This study aimed to investigate the ion pair association values and association parameters of nano MnSO4 in water and methanol-water mixtures (20 % and 40 % methanol by mass percentage) at varying temperatures (298.15, 303.15, 308.15, and 313.15 K) using the conductometric technique. Additionally, the parameters for complex formation between nano MnSO4 and glycylglycine as a ligand were determined. The focus was on elucidating the thermodynamic formation parameters for the nano Mn2+-glycylglycine interaction, with particular emphasis on comparing the 1: 1 and 1: 2 (M: L) complexes to understand the complexation behavior more comprehensively. The results indicated that the complexation process was spontaneous, as evidenced by negative ΔGf (formation free energy change) values, which increased with temperature, highlighting the enhanced spontaneity of the process. The findings provide valuable insights into designing new materials and procedures by enhancing our understanding of the complexation behavior of nano MnSO4 with ligands like glycylglycine, thus contributing to advancements in various applications such as chemical synthesis, medicines, and environmental remediation. By elucidating the thermodynamic aspects of these interactions, the study aimed to provide valuable information that could be utilized in practical applications and further research endeavors.

Effect of indomethacin on the electrical conductance and electrochemical voltammetry of copper chloride in methanol, ethanol, and their binary mixture with water.

This study investigated the physicochemical properties of the interaction of indomethacin and copper chloride using the electrical conductance measurement in methanol, ethanol, and their binary mixture with water at room temperature (298.15 K), to determine the solvation behavior, redox behavior, and kinetics. The association parameters were computed using the Fuoss-Hsia-Fernández-Prini and Fuoss-Shedlovsky models. The standard Gibbs energy for association (ΔGoA), Walden product (Λoηo), and hydrodynamic radii (RH) were calculated to study the interaction of indomethacin and copper chloride. On the other hand, cyclic voltammetry examines the electrochemical redox behavior of copper chloride using a gold electrode and its interactions with indomethacin. Results showed changes in peak potentials and currents density in the presence of indomethacin, indicating alterations in redox behavior and reaction rates. Overall, this research can be valuable in understanding the electrochemical properties and potential applications of indomethacin and copper chloride, as well as in developing new drugs or therapeutic agents, which could have has implications in various fields, including drug development, electrochemistry, and materials science.

An Eco-Friendly, Interference, and Solvent Free Surfactant-Assisted Dual-Wavelength ß-CorrectionSpectrometric Method for Total Determination and Speciation of Cu2+ Ions in Water.

Spectral interference through the presence of uninformative variables, excess reagents, and complications in the refinement of the analyte signal is common in the quest to identify complex species in real samples. Therefore, an economical green, facile, and sensitive strategy has been developed for Cu2+ detection using the anionic surfactant sodium dodecylsulphate- (SDS-) assisted dual-wavelength ß-correction spectrophotometric strategy combined with the chromogenic reagent zincon (ZI). The low limits of detection (LOD) and quantification (LOQ) of Cu2+ using ordinary (single wavelength) spectrophotometry were 0.19 (3.02) and 0.63 (10.0) µgmL-1, and these values were improved to 0.08 (1.27) and 0.26 µgmL-1 (4.12 µM)) using ß-correction (dual wavelength) spectrophotometry, respectively. The LOD and LOQ were improved from 0.08 (1.27) and 0.26 (4.12) µgmL-1 to 0.02 (0.32) and 0.08 µgmL-1 (1.27 µM) using SDS-assisted dual-ß-correction spectrometry, respectively. Ringbom, s, and the corrected absorbance (Ac) versus Cu2+ concentration plots were linear over the concentration range 1.10-2.4 (17.4-38.1) and 0.50-2.40 µgmL-1 (7.94-38.1 µM), respectively. Sandell's sensitivity index of 3.0 × 10-3 µg/cm2 was achieved. The selectivity was further confirmed via monitoring the impact of common diverse ions and surfactants on the corrected absorbance. Total determination and Cu2+ speciation in water were favorably implemented and validated by ICP-OES at 95% (P=0.05). Satisfactory Cu2+ recoveries in tap (92.2-98.0%) and mineral (105-111.0%) water samples were achieved. The sensing system is simple, reliable, sensitive, and selective for Cu2+ detection.