ABSTRACT
In the emerging photovoltaic (PV) technologies, the golden triangle rule includes higher efficiency, longevity (or stability), and low cost, which are the foremost criteria for the root of commercial feasibility. Accordingly, a unique low-cost, ecofriendly, all-solution-processed, "bio-inspired" graphitic carbon (extracted from the most invasive plant species of Eichhornia crassipes: listed as one of the 100 most dangerous species by the International Union for Conservation of Nature) and a mixed halide perovskite interface-engineered, unique single-cell large-scale (10 × 10 sq.cm with an active area of 88 cm2) carbon-based perovskite solar cell (C-PSC) are demonstrated for the first time, delivering a maximum PCE of 6.32%. Notable performance was observed under low light performance for the interface-engineered champion device fabricated using the layer-to-layer approach, which, even when tested under fluorescent room light condition (at 200 lux of about â¼0.1 SUN illumination), exhibited a significant PCE. In terms of addressing the stability issues in the fabricated PSC devices, the present work has adopted a two-step strategy: the instability toward the extrinsic factors is addressed by encapsulation, and the subsequent intrinsic instability issue is also addressed through interfacial engineering. Surprisingly, when tested under various stability conditions (STC) such as ambient air, light (continuous 1 SUN, under room light illumination (0.1 SUN) and direct sunlight), severe damp up to a depth of â¼25 mm water (cold (â¼15 °C) and hot (â¼65 °C)), acidic pH (â¼5), and alkaline pH (â¼11)) conditions, the fabricated large-scale carbon-based perovskite solar cells (C-LSPSCs) retained unexpected long-term stability in their performance for over 50 days. As to appraise the performance superiority of the fabricated C-LSPSC devices under various aforesaid testing conditions, a working model of a mini-fan has been practically powered and demonstrated.
ABSTRACT
In this work, zeolite NaA (RA) and NaX (RX) have been successfully synthesized using rice husk ash and it is a low cost synthesis process and it does not produce environmental hazards. Sodium silicate (SS) is extracted from rice husk ash which is an alternative silica source for zeolite synthesis. The zeolites are prepared by using a SS silica source extracted from the rice husk ash, and it has been used as an adsorbent for the CO2 adsorption process which may help in controlling the global warming problems. The zeolites are synthesized by a hydrothermal method without using any organic templating agent. FESEM and TEM micrographs revealed that the synthesized zeolites RA and RX have "Ice cube" and octahedral morphology respectively. From the N2 sorption studies, the BET surface area of the synthesized zeolites have been found and are 106.25 m2 g-1 and 512.79 m2 g-1 respectively. The maximum CO2 adsorption capacities of zeolite RA and RX are 2.22 and 2.45 mmol g-1, respectively at a temperature of 297.15 K. The recorded data are fitted by using non-linear adsorption isotherm models of Langmuir, Freundlich and Toth isotherm models. The fitted isotherm models are observed to be a type I adsorption isotherm according to the IUPAC classification criterion.
ABSTRACT
In this study, zeolite sodalite SOD (50NaO2:Al2O3:5SiO2), zeolite LTA (2NaO2:Al2O3:1.926SiO2) and zeolite FAU (16NaO2:Al2O3:4SiO2) of different structures were synthesized successfully through simple conventional hydrothermal crystallization technique without using any template agent. Morphological analysis of three different types of zeolites revealed that the samples exhibit three different shapes such as the "Raspberry-like", "Dice" cube like and "Octahedral" shaped morphology respectively. The thermal stability was found to be about 4.8%, 14.6% and 20.5% for the synthesized zeolites SOD, LTA and FAU respectively. From the N2 adsorption-desorption studies, it was observed that adsorption types IV and I correspond to the synthesized samples. CO2 adsorption by the synthesized zeolite SOD, LTA and FAU were examined in the pressure range from 0 to 101.325 kPa at a constant temperature of 297.15 K. The highest adsorption capacity of 3.7 mmol/g was obtained for zeolite FAU. The synthesized zeolite was studied using a nonlinear regression curve fit to determine the adsorption isotherm model using Langmuir and Freundlich isotherm model. It has been found that the synthesized zeolites have a large electric field gradient due to which they can strongly adsorb quadrupole of CO2 molecules.
ABSTRACT
Perovskite solar cells (PSCs) composed of organic polymer-based hole-transporting materials (HTMs) are considered to be an important strategy in improving the device performance, to compete with conventional solar cells. Yet the use of such expensive and unstable HTMs, together with hygroscopic perovskite structure remains a concern - an arguable aspect for the prospect of onsite photovoltaic (PV) application. Herein, we have demonstrated the sustainable fabrication of efficient and air-stable PSCs composed of an invasive plant (Eichhornia crassipes) extracted porous graphitic carbon (EC-GC) which plays a dual role as HTM/counter electrode. The changes in annealing temperature (~450 °C, ~850 °C and ~1000 °C) while extracting the EC-GC, made a significant impact on the degree of graphitization - a remarkable criterion in determining the device performance. Hence, the fabricated champion device-1c: Glass/FTO/c-TiO2/mp-TiO2/CH3NH3PbI3-xClx/EC-GC10@CH3NH3PbI3-x Clx/EC-GC10) exhibited a PCE of 8.52%. Surprisingly, the introduced EC-GC10 encapsulated perovskite interfacial layer at the perovskite/HTM interface helps in overcoming the moisture degradation of the hygroscopic perovskite layer in which the same champion device-1c evinced better air stability retaining its efficiency ~94.40% for 1000 hours. We believe that this present work on invasive plant extracted carbon playing a dual role, together as an interfacial layer may pave the way towards a reliable perovskite photovoltaic device at low-cost.
