A Spontaneous Heavy Hydrogen Generator via a Protium Redox.

The extreme significance of heavy hydrogen (D2) in medicinal, nuclear, and chemical sectors, despite its scarce natural abundance, underscores the vital imperative for inventing novel chemistries for its production. We showcase a spontaneous heavy hydrogen generator during commensurate electrical energy production by decoupling the direct chemistry of OD-/D+ dual ions via a protium redox. This exergonic electrochemistry yields ∼357 mL of D2 in nearly 85 h of continuous operation, with a commensurate electrical energy output of 122 kJ/per mole of D2. This laboratory-level demonstration of spontaneous heavy hydrogen production presents a novel chemistry for the scalable manufacture of nonprimordial D2.

Directional molecular transport in iron redox flow batteries by interfacial electrostatic forces.

The mounting global energy demand urges surplus electricity generation. Due to dwindling fossil resources and environmental concerns, shifting from carbon-based fuels to renewables is vital. Though renewables are affordable, their intermittent nature poses supply challenges. In these contexts, aqueous flow batteries (AFBs), are a viable energy storage solution. This study tackles AFBs' energy density and efficiency challenges. Conventional strategies focus on altering molecule's solubility but overlook interface's transport kinetics. We show that triggering electrostatic forces at the interface can significantly enhance the mass transport kinetics of redox active molecules by introducing a powerful electrostatic flux over the diffusional flux, thereby exerting a precise directionality on the molecular transport. This approach of controlling the directionality of molecular flux in an all iron redox flow battery amplifies the current and power rating with approximately 140 % enhancement in the energy density.

Electrostatically driven unidirectional molecular flux for high performance alkaline flow batteries.

To mitigate the mismatch between energy availability and energy demand due to day/night shifts and seasonal variations, intensive efforts have been dedicated to storing renewable energy in various energy storage modules. Redox flow batteries have an upper hand over conventional batteries as energy storage modules due to their capability of decoupling energy and power. However, interfacial events, such as mass transport and electron transfer, play pivotal roles in flow batteries' energy storage and conversion mechanisms. We show that by activating electrostatic forces at the interface, unidirectional molecular flux can be achieved to and from the driving electrode surface, thereby generating a parallel or antiparallel electrostatic current along with a diffusion current. This approach of triggering electrostatic forces in flow batteries enhances their volumetric energy density and amplifies the energy efficiency to values as high as ∼92% without altering the solubility limit of the redox active species.