Dielectric and Mechanical Properties of PDMS-La2Ba2XZn2Ti3O14 (X = Mg/Ca/Sr) Nanocomposites.

Flexible polydimethylsiloxane-La2Ba2XZn2Ti3O14 (X = Mg/Ca/Sr) [PDMS-LBT] nanocomposites with high permittivity (dielectric constant, k) are prepared through a room-temperature mixing process. The LBT nanoparticles used in this study are prepared through a high-temperature solid-state reaction. It is observed that LBT (X = Mg/Ca) nanoparticles are spherical in nature, with particle size ∼20 nm, as observed from the HRTEM images, whereas LBT (X = Sr) nanoparticles are cubical in nature with particle size ≥100 nm. These LBT (X = Mg/Ca/Sr) nanoparticles are crystalline in nature, as apparent from the XRD analysis and SAED patterns. The permittivity of LBT nanoparticles is higher when "Ca" is present in place of "X". These three oxides show a temperature-dependent dielectric behavior, where LBT nanoparticles with "Sr" show a sharp change in permittivity at a temperature of ∼105 °C. These kinds of oxide materials, especially LBT (X = Sr) nanoparticles/oxides, can be used in dielectric/resistive switching devices. The effect of LBT nanoparticle concentration on the dielectric and mechanical properties of PDMS-LBT nanocomposites is widely studied and found that there is a significant increase in dielectric constant with an increase in the concentration of LBT nanoparticles. There is a decrease in the volume resistivity with the increase in the LBT nanoparticle concentration. All the PDMS-LBT nanocomposites have low dielectric loss (ε″) compared to the dielectric constant value. It is found that both permittivity (ε') and AC conductivity (σac) of PDMS-LBT composites are increased with the temperature at a frequency of 1 Hz. The % elongation at break (% EB) and tensile strength (TS) decrease with the LBT nanoparticle concentration in the matrix PDMS, which is due to the non-reinforcing behavior of LBT nanoparticles. The distribution and dispersion of LBT nanoparticles in the matrix PDMS are observed through HRTEM and AFM/SPM.

Functional Pyromellitic Diimide as a Corrosion Inhibitor for Galvanized Steel: An Atomic-Scale Engineering.

Corrosion of metal/steel is a major concern in terms of safety, durability, cost, and environment. We have studied a cost-effective, nontoxic, and environmentally friendly pyromellitic diimide (PMDI) compound as a corrosion inhibitor for galvanized steel through density functional theory. An atomic-scale engineering through the functionalization of PMDI is performed to showcase the enhancement in corrosion inhibition and strengthen the interaction between functionalized PMDI (F-PMDI) and zinc oxide (naturally existing on galvanized steel). PMDI is functionalized with methyl/diamine groups (inh1 (R = -CH3, R' = -CH3), inh2 (R = -CH3, R' = -CH2CH2NH2), and inh3 (R = -C6H3(NH2)2, R' = -CH2CH2NH2). The corrosion inhibition parameters (e.g., orbital energies, electronegativity, dipole moment, global hardness, and electron transfer) indicate the superior corrosion inhibition performance of inh3 (inh3 > inh2 > inh1). Inh3 (∼182.38 kJ/mol) strongly interacts with ZnO(101̅0) compared to inh2 (∼122.56 kJ/mol) and inh1 (∼119.66 kJ/mol). The superior performance of inh3 has been probed through charge density and density of states. Larger available states of N and H (of inh3) interact strongly with Zn and Osurf (of the surface), respectively, creating N-Zn and H-Osurf bonds. Interestingly, these bonds only appear in inh3. The charge accumulation on Osurf, and depletion on H(s), further strengthens the bonding between inh3 and ZnO(101̅0). The microscopic understanding obtained in this study will be useful to develop low-cost and efficient corrosion inhibitors for galvanized steel.

A Soft Polydimethylsiloxane Liquid Metal Interdigitated Capacitor Sensor and Its Integration in a Flexible Hybrid System for On-Body Respiratory Sensing.

We report on the dual mechanical and proximity sensing effect of soft-matter interdigitated (IDE) capacitor sensors, together with its modelling using finite element (FE) simulation to elucidate the sensing mechanism. The IDE capacitor is based on liquid-phase GaInSn alloy (Galinstan) embedded in a polydimethylsiloxane (PDMS) microfludics channel. The use of liquid-metal as a material for soft sensors allows theoretically infinite deformation without breaking electrical connections. The capacitance sensing is a result of E-field line disturbances from electrode deformation (mechanical effect), as well as floating electrodes in the form of human skin (proximity effect). Using the proximity effect, we show that spatial detection as large as 28 cm can be achieved. As a demonstration of a hybrid electronic system, we show that by integrating the IDE capacitors with a capacitance sensing chip, respiration rate due to a human's chest motion can be captured, showing potential in its implementation for wearable health-monitoring.

Facile preparation of multifunctional hollow silica nanoparticles and their cancer specific targeting effect.

Efficient delivery of therapeutics to tumor cells is one of the key issues in cancer therapy. In the present work, we have established a facile and unique chemical strategy for fabrication of highly biocompatible and water-dispersible multifunctional hollow silica nanoparticles (HSNPs). These mesoporous silica nanoparticles, having ring-like morphology, were fabricated by the sol-gel method followed by selective etching of the inner inorganic core. Further, to accomplish cancer-specific targeting properties, folic acid was tethered to the surface of HSNPs through amide bond formation using the EDC/NHS coupling method. Thereafter, rhodamine B isothiocyanate (RITC) was conjugated to the HSNPs to endow the fluorescent property to the nanoparticles required for biological imaging applications. The successful formation of multifunctional HSNPs was confirmed by XRD, FTIR, zeta potential, TEM, FESEM, and BET surface area measurements. The average particle size of HSNPs was found to be 50 nm to 70 nm from TEM analysis, which is the desired size-range for drug-delivery vehicles. These HSNPs showed good mesoporous behavior and were found to be an excellent candidate for loading and releasing the anticancer drug doxorubicin (DOX). The bioactivity of the HSNPs was verified by biological assay including cell cytotoxicity by MTT assay, intracellular uptake by fluorescence microscopy, cell cycle analysis by fluorescence-activated cell sorting (FACS), and apoptosis study. Besides, the effect of salt concentration on the drug release performance was evaluated. An in vitro biological study revealed that these DOX-loaded folate-targeted HSNPs achieved excellent efficacy for simultaneously targeting and destroying cancer cells.