Homogenization induced by chaotic mixing and diffusion in an oscillatory chemical reaction.

A model for an imperfectly mixed batch reactor with the chlorine dioxide-iodine-malonic acid (CDIMA) reaction, with the mixing being modelled by chaotic advection, is considered. The reactor is assumed to be operating in oscillatory mode and the way in which an initial spatial perturbation becomes homogenized is examined. When the kinetics are such that the only stable homogeneous state is oscillatory then the perturbation is always entrained into these oscillations. The rate at which this occurs is relatively insensitive to the chemical effects, measured by the Damköhler number, and is comparable to the rate of homogenization of a passive contaminant. When both steady and oscillatory states are stable, spatially homogeneous states, two possibilities can occur. For the smaller Damköhler numbers, a localized perturbation at the steady state is homogenized within the background oscillations. For larger Damköhler numbers, regions of both oscillatory and steady behavior can co-exist for relatively long times before the system collapses to having the steady state everywhere. An interpretation of this behavior is provided by the one-dimensional Lagrangian filament model, which is analyzed in detail.

Excitable media in a chaotic flow.

The response to a localized perturbation of an excitable medium under stirring by chaotic advection is investigated. It is found that below a critical stirring rate a localized perturbation produces a coherent global excitation of the system. For very slow stirring, however, the coherence of the global excitation is gradually lost. We propose a simple model to describe the effect of the flow on the excitable dynamics, and explain the observed behavior as a consequence of a steady excited filament state found in the reduced problem.

Multifractal structure of chaotically advected chemical fields

The structure of the concentration field of a decaying substance produced by chemical sources and advected by a smooth incompressible two-dimensional flow is investigated. We focus our attention on the nonuniformities of the Holder exponent of the resulting filamental chemical field. They appear most evidently in the case of open flows where irregularities of the field exhibit strong spatial intermittency as they are restricted to a fractal manifold. Nonuniformities of the Holder exponent of the chemical field in closed flows appears as a consequence of the nonuniform stretching of the fluid elements. We study how this affects the scaling exponents of the structure functions, displaying anomalous scaling, and relate the scaling exponents to the distribution of local Lyapunov exponents of the advection dynamics. Theoretical predictions are compared with numerical experiments.