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Acta Crystallogr Sect E Struct Rep Online
; 70(Pt 11): o1179-80, 2014 Nov 01.
Article
in English
| MEDLINE
| ID: mdl-25484817
ABSTRACT
In the title compound, C14H14N2O5S, the mol-ecule exists in the enamine (C=C-NH) tautomeric form. The hydrazone fragment derived from the 3-acetyl-4-hy-droxy-6-methyl-2H-pyran-2-one moiety is approximately planar, with a maximum deviation of 0.1291â (11)â Å for the N atom bound to the S atom of the benzensulfono-hydrazide group. The latter adopts a gauche conformation relative to the hydrazone N-N bond, with an N-N-S angle of 113.54â (10)°. There is an intra-molecular N-Hâ¯O=C hydrogen bond that stabilizes the tautomeric form. In the crystal, mol-ecules are linked by N-Hâ¯O=C hydrogen bonds into chains extending parallel to [100].