Recent advances and challenges of the green ZnO-based composites biosynthesized using plant extracts for water treatment.

Recently, there has been a notable rise in the prevalence of persistent pollutants in the environment, posing a significant hazard due to their toxicity and enduring nature. Conventional wastewater treatment methods employed in treatment plants rarely address these persistent pollutants adequately. Meanwhile, the concept of green synthesis has garnered considerable attention, owing to its environmentally friendly approach that utilizes fewer toxic chemicals and solvents. The utilization of materials derived from sustainable sources presents a promising avenue for solving pressing environmental concerns. Among the various sources of biological agents, plants stand out for their accessibility, eco-friendliness, and rich reserves of phytochemicals suitable for material synthesis. The plant extract-mediated synthesis of zinc oxide nanoparticles (ZnONPs) has emerged as a promising solution for applications in wastewater treatment. Thorough investigations into the factors influencing the properties of these green ZnONPs are essential to establish a detailed and reliable synthesis process. Major weaknesses inherent in ZnONPs can be addressed by changing the optical, magnetic, and interface properties through doping with various semiconductor materials. Consequently, research efforts to mitigate water pollution are being driven by both the future prospects and limitations of ZnO-based composites. This review underscores the recent advancements of plant extract-mediated ZnONP composites for water treatment.

A waste-to-wealth conversion of plastic bottles into effective carbon-based adsorbents for removal of tetracycline antibiotic from water.

Currently, plastic waste and antibiotic wastewater are two of the most critical environmental problems, calling for urgent measures to take. A waste-to-wealth strategy for the conversion of polyethylene terephthalate (PET) plastic bottles into value-added materials such as carbon composite is highly recommended to clean wastewater contaminated by antibiotics. Inspired by this idea, we develop a novel PET-AC-ZFO composite by incorporating PET plastic-derived KOH-activated carbon (AC) with ZnFe2O4 (ZFO) particles for adsorptive removal of tetracycline (TTC). PET-derived carbon (PET-C), KOH-activated PET-derived carbon (PET-AC), and PET-AC-ZFO were characterized using physicochemical analyses. Central composite design (CCD) was used to obtain a quadratic model by TTC concentration (K), adsorbent dosage (L), and pH (M). PET-AC-ZFO possessed micropores (d ≈ 2 nm) and exceptionally high surface area of 1110 m2 g-1. Nearly 90% TTC could be removed by PET-AC-ZFO composite. Bangham kinetic and Langmuir isotherm were two most fitted models. Theoretical maximum TTC adsorption capacity was 45.1 mg g-1. This study suggested the role of hydrogen bonds, pore-filling interactions, and π-π interactions as the main interactions of the adsorption process. Thus, a strategy for conversion of PET bottles into PET-AC-ZFO can contribute to both plastic recycling and antibiotic wastewater mitigation.

Synthesis of magnetic MFe2O4 (M = Ni, Co, Zn, Fe) supported on porous carbons derived from Bidens pilosa weed and their adsorptive comparison of toxic dyes.

Bidens pilosa is classified as an invasive plant and has become a problematic weed to many agricultural crops. This species strongly germinates, grows and reproduces and competing for nutrients with local plants. To lessen the influence of Bidens pilosa, therefore, converting this harmful species into carbon materials as adsorbents in harm-to-wealth and valorization strategies is required. Here, we synthesized a series of magnetic composites based on MFe2O4 (M = Ni, Co, Zn, Fe) supported on porous carbon (MFOAC) derived from Bidens pilosa by a facile hydrothermal method. The Bidens pilosa carbon was initially activated by condensed H3PO4 to increase the surface chemistry. We observed that porous carbon loaded NiFe2O4 (NFOAC) reached the highest surface area (795.7 m2 g-1), followed by CoFe2O4/AC (449.1 m2 g-1), Fe3O4/AC (426.1 m2 g-1), ZnFe2O4/AC (409.5 m2 g-1). Morphological results showed nanoparticles were well-dispersed on the surface of carbon. RhB, MO, and MR dyes were used as adsorbate to test the adsorption by MFOAC. Effect of time (0-360 min), concentration (5-50 mg L-1), dosage (0.05-0.2 g L-1), and pH (3-9) on dyes adsorption onto MFOAC was investigated. It was found that NFOAC obtained the highest maximum adsorption capacity against dyes, RhB (107.96 mg g-1) < MO (148.05 mg g-1) < MR (153.1 mg g-1). Several mechanisms such as H bonding, π-π stacking, cation-π interaction, and electrostatic interaction were suggested. With sufficient stability and capacity, NFOAC can be used as potential adsorbent for real water treatment systems.

Synthesis of MnFe2O4/activated carbon derived from durian shell waste for removal of indole in water: Optimization, modelling, and mechanism.

While durian shell is often discharged into landfills, this waste can be a potential and zero-cost raw material to synthesize carbon-based adsorbents with purposes of saving costs and minimizing environmental contamination. Indole (IDO) is one of serious organic pollutants that influence aquatic species and human health; hence, the necessity for IDO removal is worth considering. Here, we synthesized a magnetic composite, denoted as MFOAC, based on activated carbon (AC) derived from durian shell waste incorporated with MnFe2O4 (MFO) to adsorb IDO in water. MFOAC showed a microporous structure, along with a high surface area and pore volume, at 518.9 m2/g, and 0.106 cm3/g, respectively. Optimization of factors affecting the IDO removal of MFOAC were implemented by Box-Behnken design and response surface methodology. Adsorption kinetics and isotherms suggested a suitable model for MFOAC to remove IDO. MFOAC was recyclable with 3 cycles. Main interactions involving in the IDO adsorption mechanism onto MFOAC were clarified, including pore filling, n-π interaction, π-π interaction, Yoshida H-bonding, H-bonding.

Recent progress and challenges of MOF-based nanocomposites in bioimaging, biosensing and biocarriers for drug delivery.

Metal-organic frameworks (MOFs), a burgeoning class of coordination polymers, have garnered significant attention due to their outstanding structure, porosity, and stability. They have been extensively studied in catalysis, energy storage, water harvesting, selective gas separation, and electrochemical applications. Recent advancements in post-synthetic strategies, surface functionality, and biocompatibility have expanded the application scope of MOFs, particularly in various biomedical fields. Herein, we review MOF-based nanomaterials bioimaging nanoplatforms in magnetic resonance imaging, computed tomography, and fluorescence imaging. MOFs serve as the foundation for biosensors, demonstrating efficiency in sensing H2O2, tumor biomarkers, microRNA, and living cancer cells. MOF-based carriers are well designed in drug delivery systems and anticancer treatment therapies. Additionally, we examine the challenges and prospects of MOFs in surface modification, release of metal ions, and interaction with intracellular components, as well as their toxicity and long-term effects.

Tecoma stans floral extract-mediated synthesis of MgFe2O4/ZnO nanoparticles for adsorption and photocatalytic degradation of coomassie brilliant blue dye.

Toxic organic dyes-containing wastewater treatment by adsorption and photocatalytic techniques is widely applied, but adsorbents and photocatalysts are often synthesized through chemical methods, leading to secondary pollution by released chemicals. Here, we report a benign method using Tecoma stans floral extract to produce MgFe2O4/ZnO (MGFOZ) nanoparticles for adsorption and photocatalytic degradation of coomassie brilliant blue (CBB) dye. Green MGFOZ owned a surface area of 9.65 m2/g and an average grain size of 54 nm. This bio-based nanomaterial showed higher removal percentage and better recyclability (up to five cycles) than green MgFe2O4 and ZnO nanoparticles. CBB adsorption by MGFOZ was examined by kinetic and isotherm models with better fittings of Bangham and Langmuir or Temkin. RSM-based optimization was conducted to reach an actual adsorption capacity of 147.68 mg/g. Moreover, MGFOZ/visible light system showed a degradation efficiency of 89% CBB dye after 120 min. CBB adsorption can be controlled by both physisorption and chemisorption while •O2- and •OH radicals are responsible for photo-degradation of CBB dye. This study suggested that MGFOZ can be a promising adsorbent and catalyst for removal of organic dyes in water.

Effect of pyrolysis temperature on characteristics and chloramphenicol adsorption performance of NH2-MIL-53(Al)-derived amine-functionalized porous carbons.

Several activities such as aquaculture, human and feedstock therapies can directly release antibiotics into water. Due to high stability, low hydrolysis and non-biodegradation, they can accumulate in the aqueous environment and transport to aquatic species. Here, we synthesized amine-functionalized porous carbons (ANC) by a direct-pyrolysis process of NH2-MIL-53(Al) as a sacrificial template at between 600 and 900 °C and utilized them to eliminate chloramphenicol antibiotic from water. The NH2-MIL-53(Al)-derived porous carbons obtained high surface areas (304.7-1600 m2 g-1) and chloramphenicol adsorption capacities (148.3-261.5 mg g-1). Several factors such as hydrogen bonding, Yoshida hydrogen bonding, and π-π interaction, hydrophobic interaction possibly controlled adsorption mechanisms. The ANC800 could be reused four cycles along with high stability in structure. As a result, NH2-MIL-53(Al)-derived porous carbons are recommended as recyclable and efficient adsorbents to the treatment of antibiotics in water.

Optimization of hydrothermal synthesis conditions of Bidens pilosa-derived NiFe2O4@AC for dye adsorption using response surface methodology and Box-Behnken design.

The presence of stable and hazardous organic dyes in industrial effluents poses significant risks to both public health and the environment. Activated carbons and biochars are widely used adsorbents for removal of these pollutants, but they often have several disadvantages such as poor recoverability and inseparability from water in the post-adsorption process. Incorporating a magnetic component into activated carbons can address these drawbacks. This study aims to optimizing the production of NiFe2O4-loaded activated carbon (NiFe2O4@AC) derived from a Bidens pilosa biomass source through a hydrothermal method for the adsorption of Rhodamine B (RhB), methyl orange (MO), and methyl red (MR) dyes. Response surface methodology (RSM) and Box-Behnken design (BBD) were applied to analyze the key synthesis factors such as NiFe2O4 loading percentage (10-50%), hydrothermal temperature (120-180 °C), and reaction time (6-18 h). The optimized condition was found at a NiFe2O4 loading of 19.93%, a temperature of 135.55 °C, and a reaction time of 16.54 h. The optimum NiFe2O4@AC demonstrated excellent sorption efficiencies of higher than 92.98-97.10% against all three dyes. This adsorbent was characterized, exhibiting a well-developed porous structure with a high surface area of 973.5 m2 g-1. Kinetic and isotherm were studied with the best fit of pseudo-second-order, and Freundlich or Temkin. Qmax values were determined to be 204.07, 266.16, and 177.70 mg g-1 for RhB, MO, and MR, respectively. By selecting HCl as an elution, NiFe2O4@AC could be efficiently reused for at least 4 cycles. Thus, the Bidens pilosa-derived NiFe2O4@AC can be a promising material for effective and recyclable removal of dye pollutants from wastewater.

Simultaneous optimization of production yield and sulfadiazine adsorption of MgFe2O4 loaded on prickly pear biochars using Box-Behnken design.

A major challenge that humans facing is the uncontrolled discharge of antibiotic-containing wastewater into the environment, accompanying with huge threats to human community. The utilization of cost-effective biomass-based adsorbents is considered a potential solution for the treatment of antibiotic wastewater. This study aims to optimize the synthesis of MgFe2O4 nanoparticles loaded on prickly pear biochar (PPB) with outstanding sulfadiazine adsorbability using response surface methodology. Thirteen materials (MgFe2O4-PPB) produced based on Box-Behnken design were tested to evaluate the impact of the main factors on the material preparation process, including ratio of MgFe2O4:PPB precursors, calcination temperature and calcination time. Under optimized conditions, i.e., MgFe2O4:PPB ratio 0.5, temperature 600 °C and time 1 h, the production yield of 46.5% and sulfadiazine removal percentage of 85.4% were obtained. Characterization of optimized MgFe2O4-PPB indicated the good porosity and functionality suitable for the adsorption of sulfadiazine. Elovich model showed the best description of kinetic process. Temkin model was considered to be an accurate description of the isotherm adsorption. Proposed mechanism for antibiotic adsorption onto MgFe2O4-PPB was described. We clarify cost-benefit analysis to asses the importance of MgFe2O4-PPB as well as the economic and environmental impacts of biochar-based composites.

Biosynthesis of green CuO@C nanocomposite using Combretum indicum flower extract for organic dye removal: adsorption performance, modeling, and recyclability studies.

Water contamination becomes one of the most high-priority environmental concerns, calling for the efficient treatment techniques. Bionanocomposites can be robust adsorbents, but the synthesis requires toxic chemicals or energy consuming and cause the secondary pollution. Green nanocomposites can be biogenically synthesized using the plant extract to end up with a critically safe strategy. Herein, we used the flower extract of Combretum indicum plant as a bio-based reductant and carbonaceous source for the green CuO@C nanocomposite. This green nanoadsorbent obtained a specific surface area of 17.33 m2/g, good crystallinity, and functional group-containing surface, i.e., -OH and -CONH-. We also conducted the optimization of parameters, i.e., concentration, CuO@C dose, pH, time, and temperature, and reached removal efficiencies towards malachite green (MG, 83.23%), Congo red (CR, 84.60%), brilliant blue (BB, 71.39%), and methylene blue (MB, 23.67%). The maximum adsorption capacities were found as ordered, MG (46.387 mg/g) > MB (23.154 mg/g) > BB (22.8 mg/g) > CR dye (11.063 mg/g). Through the intra-particle diffusion kinetic model, MG and BB adsorption endured a three-step process, while CR and MB adsorption was a two-step process. The recyclability of the green CuO@C nanocomposite was three cycles with 67.54% for the final cycle of BB removal. Moreover, the nanoadsorbent displayed a high stability, checked by X-ray diffraction, FT-IR analysis, EDX spectra, and SEM images. It is recommended that the green CuO@C nanocomposite biosynthesized using the Combretum indicum flower extract can be a good alternative for the dye treatment from wastewater.

A comparative study on the malachite green dye adsorption of chemically synthesized and green MgFe2O4 nanoparticles using gerbera floral waste extract.

The situation of discharging a large amount of dyes from the textile industries has caused many adverse effects on human health and the ecosystems. Emerging bio-nanomaterials represent a new trend in efficient dye removal in aqueous media. Herein, we mention that MgFe2O4 bioprepared using gerbera extract has been successfully used to adsorb malachite green (MG) in water. A comparison was made to determine the dye removal efficiency between biogenic MgFe2O4 (MFOB) and chemical MgFe2O4 (MFOC). The spherical MFOB material exhibited a large surface area of 85.0 m2 g-1 and high crystallinity. The obtained outcomes showed that the highest adsorption capacity of MG dye was 584.49 mg g-1 at a MFOB dose of 0.05 g L-1 and MG concentration of 10 mg L-1. Higher correlation coefficients in the Langmuir isotherm suggested monolayer adsorption of MG. The Box-Behnken design and response surface method were established to optimize MG removal percentage under the conditions, i.e., initial MG concentration (10-30 mg L-1), adsorbent dose (0.02-0.08 g L-1), and pH of dye solution (6-8). MFOB had good reusability with high removal efficiencies after three continuous cycles. Post reuse, this adsorbent still showed excellent stability through the verification of their structural properties in comparison with fresh MFOB, showing potential for practical applications.

A review on the occurrence, analytical methods, and impact of microplastics in the environment.

Nowadays, microplastic pollution is one of the globally urgent concerns as a result of discharging plastic products into the atmosphere, aquatic and soil environments. Microplastics have average size of less than 5 mm, are non-biodegradable, accumulative, and highly persistent substances. Thousands of tons of microplastics are still accumulated in various environments, posing an enormous threat to human health and living creatures. Here, we review the occurrence and analytical methods, and impact of microplastics in the environments including soil, aquatic media, and atmosphere. Analytical methods including visual observation, Fourier-transform infrared spectroscopy, Raman spectroscopy, scanning electron microscopy, and pyrolysis-gas chromatography-mass spectrometry were evaluated. We elucidated the environmental and human health impacts of microplastics with emphasis on life malfunction, immune disruption, neurotoxicity, diseases and other tangible health risks. This review also found some shortages of analytical equivalence and/or standardization, inconsistence in sampling collection and limited knowledge of microplastic toxicity. It is hopeful that the present work not only affords a more insight into the potential dangers of microplastics on human health but also urges future researches to establish new standardizations in analytical methods.

Production of MgFe2O4/activated carbons derived from a harmful grass Cynodon dactylon and their utilization for ciprofloxacin removal.

Cynodon dactylon, an invasive species, exhibits its robust adaptability, reproduction and nutrient regime against the local species. Taking advantage of this harmful grass as a raw precursor to produce valuable materials for wastewater treatment has paid much attention. Herein, we report on the fabrication of Cynodom dactylon derived MgFe2O4@AC with a main goal of effective removal of ciprofloxacin antibiotic from water. Our findings showed that MgFe2O4@ACK1 composites attained mesoporous textures, high specific surface areas (884.3-991.6 m2 g-1), and MgFe2O4-20%@ACK1 was the most effective with a very high removal efficiency of 96.7%. The Elovich model was suitable for describing the kinetic of adsorption with (Radj)2 of 0.9988. Meanwhile, the isotherm data obeyed the Langmuir model corresponding to (Radj)2 of 0.9993. Qmax value of MgFe2O4-20%@ACK1 was determined at 211.67 mg g-1. The proposed adsorption mechanism primarily comprises five routes as follows, (i) pore-filling, (ii) π-π interaction, (iii) electrostatic interaction, (iv) hydrogen bonding, and (v) hydrophobic interaction. MgFe2O4-20%@ACK1 adsorbent could reuse with three cycles. We recommend that MgFe2O4/ACs derived from Cynodom dactylon could be high-efficiency adsorbents for the elimination of antibiotics.

Occurrence, toxicity, impact and removal of selected non-steroidal anti-inflammatory drugs (NSAIDs): A review.

Non-steroidal anti-inflammatory drugs (NSAIDs) are among the most frequently used pharmaceuticals for human therapy, pet therapeutics, and veterinary feeds, enabling them to enter into water sources such as wastewater, soil and sediment, and seawater. The control of NSAIDs has led to the advent of the novel materials for treatment techniques. Herein, we review the occurrence, impact and toxicity of NSAIDs against aquatic microorganisms, plants and humans. Typical NSAIDs, e.g., ibuprofen, ketoprofen, diclofenac, naproxen and aspirin were detected at high concentrations in wastewater up to 2,747,000 ng L-1. NSAIDs in water could cause genotoxicity, endocrine disruption, locomotive disorders, body deformations, organs damage, and photosynthetic corruption. Considering treatment methods, among adsorbents for removal of NSAIDs from water, metal-organic frameworks (10.7-638 mg g-1) and advanced porous carbons (7.4-400 mg g-1) were the most robust. Therefore, these carbon-based adsorbents showed promise in efficiency for the treatment of NSAIDs.

A critical review on the biosynthesis, properties, applications and future outlook of green MnO2 nanoparticles.

MnO2 nanoparticles have played a vital role in biomedical, catalysis, electrochemical and energy storage fields, but requiring toxic chemicals in the fabrication intercepts their applications. There is an increasing demand for biosynthesis of MnO2 nanoparticles using green sources such as plant species in accordance with the purposes of environmental mitigation and production cost reduction. Here, we review recent advancements on the use of natural compounds such as polyphenols, reducing sugars, quercetins, etc. Extracted directly from low-cost and available plants for biogenic synthesis of MnO2 nanoparticles. Role of these phytochemicals and formation mechanism of bio-medicated MnO2 nanoparticles are shed light on. MnO2 nanoparticles own small particle size, high crystallinity, diverse morphology, high surface area and stability. Thanks to higher biocompatibility, bio-mediated synthesized MnO2 nanoparticles exhibited better antibacterial, antifungal, and anticancer activity than chemically synthesized ones. In terms of wastewater treatment and energy storage, they also served as efficient adsorbents and catalyst. Moreover, several aspects of limitation and future outlook of bio-mediated MnO2 nanoparticles in the fields are analyzed. It is expected that the present work not only expands systematic understandings of synthesis methods, properties and applications MnO2 nanoparticles but also pave the way for the nanotechnology revolution in combination with green chemistry and sustainable development.

Efficient and recyclable Nd3+-doped CoFe2O4 for boosted visible light-driven photocatalytic degradation of Rhodamine B dye.

Rare earth metal doping spinel ferrites offer excellent electronic, magnetic, and photocatalytic properties, but they have not been well explored for environmental mitigation. Herein, we report the facile fabrication of novel CoNd x Fe2-x O4 (x = 0-0.05) photocatalysts based on Nd3+ incorporated into CoFe2O4 for the degradation of Rhodamine B under visible light irradiation. The Nd3+ dopant considerably increased the specific surface area (35 m2 g-1) and enhanced the degradation performance (94.7%) of CoNd x Fe2-x O4 catalysts. Nd3+-doped CoFe2O4 played a role in the formation of radicals, including ˙OH, h+, and ˙O2 -. With high recyclability and performance, CoNd0.05Fe1.95O4 nanoparticles can be efficient and reusable photocatalysts for degrading organic dyes, including Rhodamine B from wastewaters.

Green synthesis of ZnFe2O4 nanoparticles using plant extracts and their applications: A review.

Magnetic nanoparticles, particularly ZnFe2O4 are of enormous significance in biomedical and water treatment fields. However, chemical synthesis of ZnFe2O4 nanoparticles endures some major limitations, e.g., the use of toxic substances, unsafe procedure, and cost-ineffectiveness. Biological methods are more preferable approaches since they take advantages of biomolecules available in plant extract serving as reducing, capping, and stabilizing agents. Herein, we review plant-mediated synthesis and properties of ZnFe2O4 nanoparticles for multiple applications in catalytic and adsorption performance, biomedical, catalyst, and others. Effect of several factors such as Zn2+/Fe3+/extract ratio, and calcination temperature on morphology, surface chemistry, particle size, magnetism and bandgap energy of obtained ZnFe2O4 nanoparticles was discussed. The photocatalytic activity and adsorption for removal of toxic dyes, antibiotics, and pesticides were also evaluated. Main results of antibacterial, antifungal and anticancer activities for biomedical applications were summarized and compared. Several limitations and prospects of green ZnFe2O4 as an alternative to traditional luminescent powders have been proposed.

Novel ZIF-67-derived Co@CNTs nanocomposites as effective adsorbents for removal of tetracycline and sulfadiazine antibiotics.

Tetracycline (TCC) and sulfadiazine (SDZ) are two of the most consumed antibiotics for human therapies and bacterial infection treatments in aquafarming fields, but their accumulative residues can result in negative effects on water and aquatic microorganisms. Removal techniques are therefore required to purify water before use. Herein, we concentrate on adsorptive removal of TCC and SDZ using cobalt@carbon nanotubes (Co@CNTs) derived from Co-ZIF-67. The presence of CNTs on the edge of nanocomposites was observed. Taguchi orthogonal array was designed with four variables including initial concentration (5-20 mg L-1), dosage (0.05-0.2 g L-1), time (60-240 min), and pH (2-10). Concentration and pH were found to be main contributors to adsorption of tetracycline and sulfadiazine, respectively. The optimum condition was found at concentration 5 mg L-1, dosage 0.2 g L-1, contact time 240 min, and pH 7 for both TCC and SDZ removals. Confirmation tests showed that Co@CNTs-700 removed 99.6% of TCC and 97.3% of SDZ with small errors (3-5.5%). Moreover, the kinetic and isotherm were studied, which kinetic and isotherm data were best fitted with pseudo second-order model and Langmuir. Maximum adsorption capacity values for TCC and SDZ were determined at 118.4-174.1 mg g-1 for 180 min. We also proposed the main role of interactions such as hydrogen bonding, π-π stacking, and electrostatic attraction in the adsorption of antibiotics. With high adsorption performance, Co@CNTs-700 is expected to remove antibiotics efficiently from wastewater.

New frontiers of invasive plants for biosynthesis of nanoparticles towards biomedical applications: A review.

Above 1000 invasive species have been growing and developing ubiquitously on Earth. With extremely vigorous adaptability, strong reproduction, and spreading powers, invasive species have posed an alarming threat to indigenous plants, water quality, soil, as well as biodiversity. It was estimated that an economic loss of billions of dollars or equivalent to 1 % of gross domestic product as a consequence of lost crops, control efforts, and damage costs caused by invasive plants in the United States. While eradicating invasive plants from the ecosystems is practically infeasible, taking advantage of invasive plants as a sustainable, locally available, and zero-cost source to provide valuable phytochemicals for bionanoparticles fabrication is worth considering. Here, we review the harms, benefits, and role of invasive species as important botanical sources to extract natural compounds such as piceatannol, resveratrol, and quadrangularin-A, flavonoids, and triterpenoids, which are linked tightly to the formation and application of bionanoparticles. As expected, the invasive plant-mediated bionanoparticles have exhibited outstanding antibacterial, antifungal, anticancer, and antioxidant activities. The mechanism of biomedical activities of the invasive plant-mediated bionanoparticles was insightfully addressed and discussed. We also expect that this review not only contributes to efforts to combat invasive plant species but also opens new frontiers of bionanoparticles in the biomedical applications, therapeutic treatment, and smart agriculture.

A critical review on the bio-mediated green synthesis and multiple applications of magnesium oxide nanoparticles.

Nowadays, advancements in nanotechnology have efficiently solved many global problems, such as environmental pollution, climate change, and infectious diseases. Nano-scaled materials have played a central role in this evolution. Chemical synthesis of nanomaterials, however, required hazardous chemicals, unsafe, eco-unfriendly, and cost-ineffective, calling for green synthesis methods. Here, we review the green synthesis of MgO nanoparticles and their applications in biochemical, environmental remediation, catalysis, and energy production. Green MgO nanoparticles can be safely produced using biomolecules extracted from plants, fungus, bacteria, algae, and lichens. They exhibited fascinating and unique properties in morphology, surface area, particle size, and stabilization. Green MgO nanoparticles served as excellent antimicrobial agents, adsorbents, colorimetric sensors, and had enormous potential in biomedical therapies against cancers, oxidants, diseases, and the sensing detection of dopamine. In addition, green MgO nanoparticles are of great interests in plant pathogens, phytoremediation, plant cell and organ culture, and seed germination in the agricultural sector. This review also highlighted recent advances in using green MgO nanoparticles as nanocatalysts, nano-fertilizers, and nano-pesticides. Thanks to many emerging applications, green MgO nanoparticles can become a promising platform for future studies.