ABSTRACT
HYPOTHESIS: Because they have self-similar low-surface-energy microstructures throughout the whole material block, fabricating superhydrophobic monoliths has been currently a promising remedy for the mechanical robustness of non-wetting properties. Noticeably, porous materials have microstructured interfaces throughout the complete volume, and silanization can make surfaces low-surface-energy. Therefore, the porous structure and surface silane-treatment can be combined to render hydrophilic inorganics into mechanically durable superhydrophobic monoliths. EXPERIMENTS: Superhydrophobic diatomaceous earth pellets were produced by thermal-sintering, followed by a silanization process with octyltriethoxysilane. The durability of superhydrophobicity was evaluated by changes in wetting properties, surface morphology, and chemistry after a systematic abrasion sliding test. FINDINGS: The intrinsic porosity of diatomite facilitated surface silanization throughout the whole sintered pellet, thus producing the water-repelling monolith. The abrasion sliding converted multimodal porosity of the volume to hierarchical roughness of the surface comprised of silanized particles, thereby attaining superhydrophobic properties of high contact angles over 150° and sliding angles below 20°. The tribological properties revealed useful information about the superhydrophobicity duration of the non-wetting monolith against friction. The result enables the application of porous structures in the fabrication of the anti-abrasion superhydrophobic materials even though they are originally hydrophilic.
ABSTRACT
The discovery of Pickering emulsion templated assembly enables the design of a hybrid colloidal capsule with engineered properties. However, the underlying mechanisms by which nanoparticles affect the mechanical properties of the shell are poorly understood. Herein, in situ mechanical compression on the transmission electron microscope and aberration-corrected scanning transmission microscope are unprecedentedly implemented to study the intrinsic effect of nanoparticles on the mechanical properties of the calcium carbonate (CaCO3 )-decorated silica (SiO2 ) colloidal capsule. The stiff and brittle nature of the colloidal capsule is due to the interfacial chemical bonding between the CaCO3 nanoparticles and SiO2 inner shell. Such bonding strengthens the mechanical strength of the SiO2 shell (166 ± 14 nm) from the colloidal capsule compared to the thicker single SiO2 shell (310 ± 70 nm) from the silica hollow sphere. At elevated temperature, this interfacial bonding accelerates the formation of the single calcium silicate shell, causing shell morphology transformation and yielding significantly enhanced mechanical strength by 30.9% and ductility by 94.7%. The superior thermal durability of the heat-treated colloidal capsule holds great potential for the fabrication of the functional additives that can be applied in the wide range of applications at elevated temperatures.
