Interfacial Design and Construction of Carbon Fiber Composites by Strongly Bound Hydroxyapatite Nanobelt-Carbon Nanotubes for Biological Applications.

Carbon fiber composites are promising candidates for orthopedic implant applications, which calls for a combination of high mechanical strength and outstanding biotribological properties. In this work, hydroxyapatite nanobelts-carbon nanotubes (HN) were designed and constructed into carbon fiber-anhydrous dicalcium phosphate (DCPA)-epoxy composites (CDE) for simultaneously optimizing the mechanical and biotribological properties via the combined methods of pulse electrochemical deposition and injected chemical vapor deposition. HN provides more nucleation sites for the growth of DCPA and favors the infiltration of epoxy. In addition, HN optimizes the fiber/matrix interface by generating strong interfacial mechanical interlocking. Owing to the synergism of a strongly bound HN, the mechanical and biotribological properties of CDE have demonstrated significant improvement. The tensile strength and elastic modulus of HN-modified CDE (HN-CDE) increase by 52 and 170% compared with CDE, respectively. The wear rate and average friction coefficient of HN-CDE are decreased by 42% and increased by 45% compared with those of CDE, respectively. HN-CDE, with superior mechanical strength and biotribological properties, has high potential as a bone substitute and orthopedic implant.

Balanced Mechanical and Biotribological Properties of Polymer Composites Reinforced by a 3D Interlocked Si3N4 Nanowire Membrane.

Polymer composites have great potential applications in the hip joint replacement, where the combinations of high mechanical strength and excellent biotribological properties are required. In this work, a well-dispersed three-dimensional (3D) silicon nitride nanowire membrane (SNm) designed as a reinforcement and brushite (Bs) served as bioactive filler are constructed into the polymer matrix, forming SNm-reinforced Bs/polymer composites (SNm-Bs/Pm). Especially, SNm could form a 3D interlocked structure, where the ultralong silicon nitride nanowires are entangled with each other. SNm could effectively facilitate the penetration of the polymer matrix and improve the cohesion strength of the polymer, thereby promoting mechanical and biotribological properties for SNm-Bs/Pm. The performances for polymer composites are optimized by increasing the layer number of preform. By comparing SNm-Bs/Pm with one-layer preform, the tensile strength of SNm-Bs/Pm with six-layer preforms reaches 83.3 MPa with an increase of 767.7%. In addition, the friction coefficient and wear rate of SNm-Bs/Pm with six-layer preforms in fetal bovine serum medium achieve 0.06 and 0.21 × 10-14 m3(N·m)-1 and decrease by 82.4 and 72.4%, respectively. The present work provides a promising methodology of preparing interlocked SNm-reinforced polymer composites with enhanced mechanical and biotribological properties that are potential for hip joint replacement applications.