What does it take to renature cities? An expert-based analysis of barriers and strategies for the implementation of nature-based solutions.

This paper uses an expert-based methodology to survey the barriers and strategies related to the implementation of nature-based solutions (NBS). The ambition of the paper is to offer a bird's eye overview of the difficulties encountered by NBS deployment and ways to overcome them. With a wide participation of 80 experts from COST Action Circular City, we identify barriers specific to 35 pre-defined NBS of the following four categories: Vertical Greening Systems and Green Roofs; Food and Biomass Production; Rainwater Management; and Remediation, Treatment, and Recovery. The research sheds light on how a major interdisciplinary - yet predominantly technically-oriented - community of scientists and practitioners views this important topic. Overall, the most relevant barriers are related to technological complexity, lack of skilled staff and training programs and the lack of awareness that NBS is an option. Our results highlight concerns related to post implementation issues, especially operation and maintenance, which subsequently affect social acceptance. The paper identifies a "chain" effect across barriers, meaning that one barrier can affect the existence or the relevance of other barriers. In terms of strategies, most of them target governance, information, and education aspects, despite the predominantly technical expertise of the participants. The study innovates with respect to state-of-the-art research by showing a fine-grained connection between barriers, strategies and individual NBS and categories, a level of detail which is not encountered in any other study to date.

Economic impact assessment indicators of circular economy in a decentralised circular water system - Case of eco-touristic facility.

The transition from a linear make-use-dispose model to a Circular Economy (CE) model has gained momentum in recent years. To date, substantive efforts have been put by researchers and practitioners on environmental assessment of circular water systems (CWS). Yet, the economic aspect of CWS has not received the same attention. This research is an attempt to bridge this gap by evaluating the economic viability of a decentralised hybrid rainwater- wastewater-greywater (HRWG) system. For this purpose, a framework of Shadow Pricing- Life Cycle Cost-Benefit (SLCCB) to analyse a CWS is proposed. Shadow pricing could compliment the established Life Cycle Costing (LCC) methods. The main parameters (costs and benefits) of the proposed SLCCB framework are divided into two types: Internal and External. The Internal pricing covers the capital expenditure (CAPEX) and operational expenditure (OPEX), while the External pricing covers the environmental and social costs-benefits of implementing CWS. The proposed SLCCB added to the classical Net Present Value (NPV) and Payback Period (PP) calculations could provide a more realistic evaluation of the economic performance of CWS. To demonstrate the efficacy of the new CE model, a new CWS in Greece was studied. A sensitivity analysis was conducted to assess the impact of the reclaimed water tariffs, internal costs, life span of the project, and the annual discount rate on the SLCCB. The results of the study reveal that the SLCCB of CWS is highly sensitive to these parameters. The economic feasibility of CWS boost with increasing discount rate and reclaimed water tariffs, as well as with decreasing project's life span and internal costs. The conclusion of this research demonstrates that investment in CWS is economically viable if External parameters are taken into consideration.

Plastic pellets sorptive extraction: Low-cost, rapid and efficient extraction of polycyclic aromatic hydrocarbons from environmental waters.

For the first time, plastic pellets, a low-cost and easy to reach industrial raw material, are reported as an efficient sorbent material for the laboratory extraction of polycyclic aromatic hydrocarbons (PAHs) from environmental waters. The proposed methodology, termed plastic pellets sorptive extraction (P2SE), consisted of a two-step procedure whereby target analytes were initially adsorbed onto the surface of three low-density polyethylene (LDPE) pellets and then desorbed using microliters of an organic solvent. Interphase mass transfer was greatly accelerated by means of vortex agitation. Organic extracts were analyzed by means of liquid chromatography-fluorescence detection. Different experimental parameters were controlled and the optimum conditions found were: three LDPE pellets (∼80 mg) added to 20 mL aqueous sample (20% w:v NaCl) followed by vortex agitation at 3000 rpm; for desorption, the three LDPE pellets were immersed in 100 µL of acetonitrile and the mixture was shaken at 3000 rpm for 5 min using the vortex agitator. The calculated calibration curves gave high levels of linearity yielding coefficients of determination (r(2)) greater than 0.9913. The precision of the proposed method was found to be good and the limits of the detection were calculated in the low ng L(-1) level. Matrix effects were determined by applying the proposed method to spiked river water, treated municipal wastewater and seawater samples. To compensate for the low recoveries of the more hydrophobic PAHs in spiked effluent wastewater and seawater samples the standard addition methodology was applied. The proposed method was applied to the determination of target pollutants in real seawater samples using the standard addition method. Overall, the performance of the proposed P2SE method suggests that the use of inexpensive and easy to reach sorbent materials for extracting analytes in the laboratory merits more intensive investigation.