ABSTRACT
To investigate reaction order and kinetic parameters of the reaction between crystal violet (CV) and sodium hydroxide (NaOH), various concentrations of the reactants were applied. The present work also verifies the unknown solid product produced under highly concentrated conditions. The reaction orders of CV and NaOH were determined to be 1 and 1.08 by pseudo rate method, respectively, with a rate constant, k, of 0.054 [(M-1.08) s-1]. In addition to pseudo rate method, the half-life approach was used to calculate the overall reaction order to verify the accuracy of pseudo rate method. The overall reaction order was determined to be 1.9 by the half-life method. The overall reaction order based on the two methods studied was approximately 2. The precipitate formation was observed when high concentrations of CV (0.01-0.1 M) and NaOH (1.0 M) were applied. Fourier transform infrared (FTIR) spectroscopy was used to compare the spectra of the precipitate generated and a commercial solvent violet 9 (SV9). Based on the FTIR spectra, it was confirmed that the molecular structure of the precipitate matched that of solvent violet 9.
ABSTRACT
Nanomaterials have been commonly employed to enhance the performance of polymeric membrane materials that are used in several industrial applications. Carbon nanotubes (CNTs) have gained notable attention over the years for use in membrane technology due to their anti-biofouling properties, salt rejection capability, exceptional electrical conductivity, and mechanical properties. This paper aims to discuss some of the recent applications of CNTs in membrane technology and their effect on a larger scale. The paper reviews successful case studies of incorporation of CNTs in membranes and their impact on water purification, desalination, gas separations, and energy storage, in an effort to provide a better understanding of their capabilities. Regarding the future trends of this technology, this review emphasizes improving the large-scale production processes and addressing environmental and health-related hazards of CNTs during production and usage.
