Non-relativistic energy equations for diatomic molecules constrained in a deformed hyperbolic potential function.

CONTEXT: In this paper, the approximate analytical energy equations for the deformed hyperbolic potential have been obtained for arbitrary parameters of the potential. The potential function was transformed to a molecular potential by subjecting it to the Varshni conditions which allows for the determination of the energy levels of diatomic molecules. The molecular vibrational energy spectra for [Formula: see text], [Formula: see text], [Formula: see text], [Formula: see text], and [Formula: see text] diatomic molecules were obtained and found to match with the results obtained with another analytical approach, potential functions, and experimental data. The noticeable slight differences in the approximate energy spectra obtained in this work and existing literature may be ascribed to the analytical method, computational approach, and the accuracy of the molecular potential functions. The obtained energy equations were used to determine the energy of a particle for arbitrary parameters of the potential function. The obtained energy is bounded and increases with the increase in the quantum numbers. The results conformed to the ones obtained via the path integral approach and numerical solutions obtained via the MATHEMATICA program. METHOD: The energy spectra equations were obtained via the Nikiforov-Uvarov approach and semi-classical WKB approximation. The Pekeris approximation has been applied to resolve the difficulty in solving the complete energy spectrum of the non-relativistic wave equation for the potential function. The numerical data of the energy spectra was obtained using the MATHEMATICA program.

Nonrelativistic solutions of Schrödinger equation and thermodynamic properties with the proposed modified Mobius square plus Eckart potential.

We obtain solutions of Schrödinger equation for the modified Mobius square plus Eckart (MMPSE) potential via the formula method. Numerical results are reported. In addition, the partition function Z and other thermodynamic properties such as vibrational free energy, F, vibrational internal energy, U, vibrational entropy, S, and vibrational specific heat, C are presented. We also discuss special cases of this potential. Our result is consistent with previous studies in the literature.

Dirac equation and thermodynamic properties with the Modified Kratzer potential.

In this work, we present the analytical solutions of Dirac equation for modified Kratzer potential in the pseudospin and spin symmetry limits using the formula method. The energies of the pseudospin and spin symmetry limit are obtained analytically and numerically. The numerical values are compared with those obtained in literature. Furthermore, we study the thermodynamic properties of some diatomic molecules within the nonrelativistic spin symmetry limits.

Nonrelativistic treatment of inversely quadratic Hellmann-Kratzer potential and thermodynamic properties.

The study presents approximate analytical solutions of the Schrödinger equation with a newly proposed potential model called Inversely Quadratic Hellmann-Kratzer potential (IQHKP). This potential is a superposition of Inversely Quadratic Hellman potential and Kratzer potential. The energy eigenvalues and corresponding wavefunction are calculated via the formula method. We applied our results to evaluate thermodynamic functions such as vibrational free energy, F, vibrational internal energy, U, vibrational entropy, S, and vibrational specific heat, C. We also reported special cases of importance.