Perovskite Oxides: Syntheses and Perspectives on Their Application for Nitrate Reduction.

Over the decades, the rise in nitrate levels in the ecosystem has posed a serious threat to the continuous existence of humans, fauna, and flora. The deleterious effects of increasing levels of nitrates in the ecosystem have led to adverse health and environmental implications in the form of methemoglobinemia and eutrophication, respectively. Different pathways/routes for the syntheses of perovskites and their oxides were presented in this review. In recent times, electrocatalytic reduction has emerged as the most utilized technique for the conversion of nitrates into ammonia, an industrial feedstock. According to published papers, the efficiency of various perovskites and their oxides used for the electrocatalytic reduction of nitrate achieved a high Faradaic efficiency of 98%. Furthermore, studies published have shown that there is a need to improve the chemical stability of perovskites and their oxides during scale-up applications, as well as their scalability for industrial applications.

Levels and health risk assessments of Phthalate acid esters in indoor dust of some microenvironments within Ikeja and Ota, Nigeria.

The levels, profiles of Phthalate acid esters (PAEs) and their associated health risk in children and adults using indoor dust samples were assessed from nine (9) microenvironments in Nigeria. Six PAEs congeners were determined using Gas Chromatography-Mass Spectrometry and the human health risk assessments of PAEs exposure to children and adults were computed using the United States Environmental Protection Agency (USEPA) exposure model. The mean concentrations of the total PAEs (Σ6PAEs) in indoor dust across the study locations ranged from 1.61 ± 0.12 to 53.3 ± 5.27 µg/g with 72.0% of di-n-octyl phthalate (DnOP) as the most predominant contributor of PAEs in sample locations B, C, D, E, F and G. PAEs estimated daily intake results exceeded the USEPA value of 20 and 50 kg/bw/day for children and adults respectively in some locations. Non-carcinogenic risk exposure indicated no risk (HI < 1), while the carcinogenic risk was within the recommended threshold of 1.00 × 10-4 to 1.00 × 10-6 for benzyl butyl phthalate and bis-2-ethylhexyl phthalate. From our findings, lower levels of PAEs were observed in locations with good ventilation system. Also, the human health risk evaluation indicated indoor dust ingestion as the dominant exposure route of PAEs for both children and adults, while the children were at a higher risk of PAEs exposure. To protect children susceptible to these endocrine-disrupting pollutants, soft vinyl children's toys and teething rings should be avoided. Appropriate policies and procedures on the reduction of PAEs exposure to humans should be enacted by all stakeholders, including government regulatory agencies, industries, school administrators and the entire community.

Physico-chemical characterization of indoor settled dust in Children's microenvironments in Ikeja and Ota, Nigeria.

Indoor dust is a collection of particles identified as a major reservoir for several emerging indoor chemical pollutants. This study presents indoor dust particles' morphology and elemental composition in eight children's urban and semi-urban microenvironments (A-H) in Nigeria. Samples were collected using a Tesco vacuum cleaner and analyzed with scanning electron microscopy coupled with an energy-dispersive X-ray (SEM-EDX). The morphology results confirm the presence of alumino silicates, mineral particles and flakes, fly ash and soot, and soot aggregates deposited on alumino silicate particles in the sampled microenvironments. These particles may trigger serious health concerns that directly or indirectly affect the overall well-being of children. From the EDX analysis, the trend of elements (w/w %) in the dust particles across the sampled sites was silicon (386) > oxygen (174)> aluminium (114) > carbon (34.5) > iron (28.0) > calcium (16.7) > magnesium (14.2) > sodium (7.92) > potassium (7.58) > phosphorus (2.22) > lead (2.04) > manganese (1.17) > titanium (0.21). Lead (Pb), a toxic and carcinogenic heavy metal, was observed in locations A and B. This is a concern without a safe lead level because of the neurotoxicity effect on children. As a result, further research on the concentrations, bioavailability, and health risk assessment of heavy metals in these sampled locations is recommended. Furthermore, frequent vacuum cleaning, wet moping and adequate ventilation systems will significantly reduce the accumulation of indoor dust-bound metals.

Indoor air quality in day-care centres: a global review.

A healthy indoor environment is critical for children due to the severe effect of poor indoor air quality (IAQ) on their overall well-being. Day-care centres (DCCs) are important indoor microenvironments for children apart from their homes. Therefore, monitoring IAQ in this microenvironment is vital because of the vulnerability of the occupants. This review gives a global overview of the predominant indoor chemical pollutant levels monitored in DCCs, compares their concentration with available regulations for IAQ, evaluates the sources and health risk effects of chemical pollutants and proposes strategies for enhancing IAQ in DCCs. Thirty-seven (37) articles were used based on specific stated inclusion and exclusion criteria. Continents like Europe and Asia have the most published studies in indoor DCCs. The decreasing trend of pollutants examined in most studies include particulate matter > carbon dioxide > formaldehyde > carbon monoxide > total volatile organic compounds > volatile organic compounds > nitrogen dioxide > ozone > benzene > sulphur dioxide = radon. Particulate matter in the size and mass concentration range of PM10 (0.116-1920.71 µg/m3) > PM2.5 (0.279.2-260.74 µg/m3) was the most investigated pollutant. While nitrogen dioxide, radon and carbon monoxide were consistent with the existing national and international reference values for IAQ across the continents, exceedances occurred in other pollutants. The limited number of indoor chemical pollutant studies suggests the need for more comprehensive studies on IAQ in DCC globally. Further studies should highlight the availability of low-cost sensors and mobile analytical equipment that will promote affordable ground-level data accessibility. Supplementary Information: The online version contains supplementary material available at 10.1007/s11869-023-01320-5.