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Chem Commun (Camb)
; 60(24): 3283-3286, 2024 Mar 19.
Article
in English
| MEDLINE
| ID: mdl-38421221
ABSTRACT
Pd2dba3·CHCl3 (2.5 mol%)-BINAPHANE (5 mol%) was used to promote the first catalytic enantioselective allylation of disubstituted ketenes to give α-allyl esters. The ester products were formed in good to excellent yields (61-93% yield for 13 examples, 16 examples in all), with moderate to good enantioselectivity (68-80% ee for 7 examples).