A GIS study to rank Irish agricultural lands with background and anthropogenic concentrations of metal(loid)s in soil.

Heavy metal pollution may cause a serious threat to human health and is a global problem. The bio-availability of metals and metalloids (metal (loid)s) in the soil is a dominating parameter for metal (loid) uptake by plants, and which may subsequently be ingested by individuals through the food pathway. This study aimed to develop a novel approach based on a semi-quantitative probability-impact (P-I) matrix with the help of a GIS mapping tool. ArcGIS was used for data analysis, classification, and reclassification of parameters of the model. Nine influencing parameters were selected for a semi-quantitative risk ranking. These are soil pH, soil organic carbon (SOC), soil texture class, slope, field/soil drainage class, Integrated Risk Quotient (IRQ), proximity to mines, urban activity, and potential biosolids application areas. The results revealed that certain areas (including Co. Louth, Co. Wicklow, Co. Wexford) along the East coast of Ireland pose a higher relative risk. Therefore, in-depth quantitative human health risk assessment is proposed considering the potential bioaccumulation of metal (loid)s if the crops are grown on land with elevated levels of metal (loid)s. Furthermore, this work reveals the usefulness of the GIS mapping techniques in risk assessment to rank areas of elevated levels of potential pollutants.

Risk factors and assessment strategies for the evaluation of human or environmental risk from metal(loid)s - A focus on Ireland.

Elevated human exposure to metals and metalloids (metal(loid)s) may lead to acute sickness and pose a severe threat to human health. The human body is exposed to metal(loid)s principally through food, water, supplements, and (occasionally) air. There are inherent background levels of many metal(loid)s in regional soils as a consequence of geological sources. Baseline levels coupled with anthropogenic sources such as regional application of biosolids may lead to increased levels of certain metal(loid)s in soil, leading to potential transfer to water sources and potential uptake by plants. The latter could potentially transfer into the feed-to-food chain, viz. grazing animals, and bio-transfer to food products resulting in human exposure. This study addresses health concerns due to excessive intake of metal(loid)s by conducting a traditional review of peer-reviewed journals between 2015 and 2019, secondary references and relevant websites. The review identified the most researched metal(loid)s as Cu, Zn, Pb, Cd, Ni, Cr, As, Hg, Mn, Fe in the environment. The potential uptake of metal(loid)s by plants (phytoavailability) is a function of the mobility/retainability of metal(loid)s in the soil, influenced by soil geochemistry. The most critical parameters (including soil pH, soil organic matter, clay content, cation exchange capacity, the capability of decomposition of organic matter by microbes, redox potential, ionic strength) influencing metal(loid)s in soil are reviewed and used as a foundation to build a framework model for ranking metal(loid)s of concern. A robust quantitative risk assessment model is recommended for evaluating risk from individual metal(loid)s based on health-based indices (Daily Dietary Index (DDI), No Observed Adverse Effect Level (NOAEL), and Lowest Observed Adverse Effect Level (LOAEL)). This research proposes a risk assessment framework for potentially harmful metal(loid)s in the environment and highlights where regulation and intervention may be required.