ABSTRACT
Weathering processes are recognized as drivers of soil and water resource sustainability, but how pedogenesis stage impacts contaminant reactivity and mobility in soils has been minimally investigated. The primary goal of this study was to quantify how soil development influences contaminant reactivity. To achieve this goal, soils from two depths (30 and 100 cm) across a chronosequence (ages 3.5, 20, 69, 140, 200, and 908 ky) in the Oregon Coast Range were subjected to arsenic (As) adsorption isotherms, with As removal from solution serving as a proxy for soil-contaminant reactivity. Langmuir models were applied to isotherm data to quantify relationships between contaminant retention capacity, soil age and soil physicochemical properties, and data revealed that 20 ky soils from a 30-cm-depth had the greatest affinity for As sorption (8,474.5 mg kg-1). Chemical extractions revealed that amorphous (oxy)hydroxides were the dominant mineral phases governing As sorption, even in the presence of abundant crystalline oxides. Micro-X-ray fluorescence spectroscopy revealed a strong spatial correlation between As and Fe in reacted soils. The abundance of amorphous minerals within soils is controlled by the balance between their production from weathering of primary minerals and their loss from ripening to crystalline minerals, and because the mode, extent and minerals governing contaminant sorption determine solid-aqueous phase partitioning, this knowledge will assist in improving models for predicting Critical Zone processes that govern the sustainability of soil and water quality.
ABSTRACT
Arsenic (As), chromium (Cr), and vanadium (V) are naturally occurring, redox-active elements that can become human health hazards when they are released from aquifer substrates into groundwater that may be used as domestic or irrigation source. As such, there is a need to develop incisive conceptual and quantitative models of the geochemistry and transport of potentially hazardous elements to assess risk and facilitate interventions. However, understanding the complexity and heterogeneous subsurface environment requires knowledge of solid-phase minerals, hydrologic movement, aerobic and anaerobic environments, microbial interactions, and complicated chemical kinetics. Here, we examine the relevant geochemical and hydrological information about the release and transport of potentially hazardous geogenic contaminants, specifically As, Cr, and V, as well as the potential challenges in developing a robust understanding of their behavior in the subsurface. We explore the development of geochemical models, illustrate how they can be utilized, and describe the gaps in knowledge that exist in translating subsurface conditions into numerical models, as well as provide an outlook on future research needs and developments.
