A comprehensive comparative study on microwave- assisted pyrolysis products derived from raw and digested organic waste, with emphasis on sewage sludge, food waste, and livestock manure.

This study focused on characterizing sewage sludge, food waste, and livestock manure, representative of continuously generated organic wastes, along with their anaerobic digestion residues. Microwave assisted pyrolysis was employed to investigate the relationship between the properties of the raw organic wastes and the resulting pyrolysis products, utilizing the R-program for analysis. Evaluation of the pyrolysis products of these six organic wastes revealed that char yield was primarily influenced by ash and fixed carbon contents, with higher yields observed in residues from anaerobic digestion compared to the original organic waste. Liquid and gaseous product quantities were found to increase with volatile content, while high-fat content within the volatile fraction notably enhanced liquid product yields, impacting syngas production. Analysis of syngas composition indicated a negative correlation between high nitrogen content in the feedstock and H2 generation. Furthermore, examining the correlation between chemical properties of organic waste and pyrolysis products revealed a proportional increase in protein components with nitrogen content, suggesting potential improvements in pyrolysis efficiency through raw material pretreatment enhancements by the R program.

Comparison of pyrolysis gasification of livestock manure, food wastewater, and their co-digested sludge.

For energy recovery, anaerobic digestion is applied to organic waste, such as livestock manure (LM) and food wastewater (FW). Digested sludge(DS), a residue from the anaerobic co-digestion of LM and FW, is another type of organic waste that can be converted into energy through pyrolysis. This study compared the pyrolysis characteristics of LM, FW, and DS. The product content varied with the pyrolysis temperature, rate of temperature increase, reaction time, and final reaction temperature. Gas production from FW and DS was similar; however, gas production from LM was low. As the pyrolysis temperature increased, the H2 content increased, and the CO2 content decreased, respectively. At 1000 °C, the H2 content of LM increased to 45%, and FW produced the most gas but the lowest H2 content. The H2/CO ratios of LM and FW ranged from 3.5 to 5.2, while those of DS ranged from 5.5 to 12.4, with the highest values. The carbon conversion rate was the highest for the gaseous products of LM (30-54%) and lowest for the gaseous products of digested sludge (26-36%). Conversely, the cold gas efficiency was the highest for the DS and lowest for the LM. Following anaerobic digestion, the DS generated less tar than the untreated LM and FW, showed higher efficiency in gas generation and gas properties, and exhibited a higher value as a char fuel.

Syngas generation from different types of sewage sludge using microwave-assisted pyrolysis with silicon carbide as the absorbent.

In this study, the pyrolysis of sewage sludge was explored through microwave-assisted pyrolysis. Three kinds of sludge (primary sludge, waste-activated sludge, and digested sludge) from a sewage treatment process were used. All three kinds of sewage sludge had a low microwave absorption capacity; therefore, an absorber was added to enable microwave-assisted pyrolysis. By using silicon carbide as the heating element, it was possible to increase the temperature within a short time by applying microwaves. During the microwave-assisted pyrolysis of sewage sludges, the amount of gas generated and the H2 and CO fraction of the produced gas increased as temperature increased. The pyrolysis of waste-activated sludge produced the greatest quantity of gas. However, the primary sludge produced the highest amount of syngas in terms of H2 and CO, which indicate the high-quality of the syngas.

Field test of water-net based wastewater treatment for nutrient removal and bioethanol production.

In this study, an open pond constructed in Myanmar, a region with tropical climate and favorable environmental conditions for algae growth, was considered to conduct field experiments on sewage inflow river water. The nutrient removal efficiency and productivity of Hydrodictyon reticulatum (H. reticulatum) were analyzed, and the maximum fermentation limit concentration for bioethanol production was determined. Three ponds were operated in batch mode to investigate the effect of light intensity. Photoinhibition was caused due to excessive light intensity in summer season in the region with tropical climate resulting in reduced facility efficiency in the absence of shade. For light blocking, a transparent film was found to be more effective than a translucent film. In the transparent film shading facility, the nitrogen and phosphorus removal efficiencies were maintained above 76% and 81%, respectively, and the productivity of H. reticulatum was 2.27 g m-2 d-1. For a raceway open pond facility shaded with transparent film, the performance was evaluated based on hydraulic retention time (HRT), and the productivity of algae was found to increase with increasing supply of nitrogen and phosphorous. Maximum biomass production of 3.21 g m-2 d-1 was observed with an HRT of 3 d, suggesting the possibility of long-term operation. As a result of evaluating the ethanol production based on the initial concentration of H. reticulatum, the yield of bioethanol at the initial reducing sugar content of 120 g L-1 was 89.4%, but bioethanol production was only 8.9 g L-1.

Pilot-scale cultivation of water-net in secondary effluent using an open pond raceway for nutrient removal and bioethanol production.

Although microalgae are seen as a potential alternative source of energy and other materials currently sourced from petroleum, issues still remain with industrialization because of difficulties in developing commercially operational microalgal production systems. We set up a pilot-scale study that involved the simultaneous reuse of wastewater and production of algae under different light and harvesting conditions. We cultivated Hydrodictyon reticulatum (H. reticulatum), a type of water-net algae, using secondary effluent from a wastewater treatment plant in a raceway open pond combined with an underwater light device. Experimental results showed that the underwater light device maintained some level of underwater light throughout the year. Photoinhibition of algal growth only occurred when the sunlight exceeded 1270 µmol m-2 s-1. During the non-harvest process, the maximum algal concentration was 1700 mg L-1 at 20 days after the experiment began, the maximum specific growth rate was 0.18 d-1 and the maximum productivity was 21.3 g m-2 d-1. Conversely, periodic harvesting decreased the concentration of nutrients in the effluent more as the days of cultivation increased, but the productivity of algae also decreased to 11.7 g m-2 d-1. The maximum yield of bioethanol using three kinds of fermentation strains was 93.5% and, thus, the commercial value of H. reticulatum as a raw material for energy production was excellent.