ABSTRACT
Initial leaching characteristics of simulated nuclear waste immobilized in three alkali- borosilicate glasses (ABS-waste) were studied. The effects of matrix composition on the containment performance and degradation resistance measures were evaluated. Normalized release rates are in conformance with data reported in the literature. High Li and Mg loadings lead to the highest initial de-polymerization of sample ABS-waste (17) and contributed to its thermodynamic instability. Ca stabilizes non-bridging oxygen (NBO) and reduces the thermodynamic instability of the modified matrix. An exponential temporal change in the alteration thickness was noted for samples ABS-waste (17) and Modified Alkali-Borosilicate (MABS)-waste (20), whereas a linear temporal change was noted for sample ABS-waste (25). Leaching processes that contribute to the fractional release of all studied elements within the initial stage of glass corrosion were quantified and the main controlling leach process for each element was identified. As the waste loading increases, the contribution of the dissolution process to the overall fractional release of structural elements decreases by 43.44, 5.05, 38.07, and 52.99% for Si, B, Na, and Li respectively, and the presence of modifiers reduces this contribution for all the studied metalloids. The dissolution process plays an important role in controlling the release of Li and Cs, and this role is reduced by increasing the waste loading.
ABSTRACT
An acoustic emission (AE) technique was applied for early detection, characterisation and time progress description of cracking phenomenon caused by the corrosion of Al encapsulated in cement matrix. The study was conducted on an ordinary Portland cement (OPC) system encapsulating high purity Al bar. Acoustic signals were generated and released during immersing of the sample in deionised water. A computer controlled PCI-2 based AE system processed the signals detected by piezoelectric transducers. A subsequent comparative study of the AE data collected with those obtained from a reference OPC sample has been applied. Recorded AE activity confirmed that the process of initiation and development of Al corrosion causes significant mechanical stresses within the cement matrix. Our analysis demonstrated possibility to differentiate AE signals based on their characteristics, and potentially correlate detected AE with the fracture processes in the cement system encapsulating Al.
