ABSTRACT
The adsorption of Pb(II) and Cd(II) on three commercial microporous activated carbons was analysed. Adsorption kinetics and statistics were investigated, and the results were described with different models. The highest values of the correlation coefficient R2 were obtained for the pseudo-second-order kinetics model for all ions tested and all sorbents used. The adsorption process was found to be determined by both diffusion in the liquid layer and intraparticle diffusion. The adsorption equilibrium is very well described by Langmuir, Temkin, Thoth or Jovanovic isotherm models. Based on the values of n from the Freundlich isotherm and KL from the Langmuir isotherm, the adsorption of cadmium and lead ions was found to be favourable. The highest monolayer capacities were obtained during the adsorption of lead ions (162.19 mg/g) and for cadmium (126.34 mg/g) for activated carbon WG-12. This carbon is characterised by the highest amount of acid functional groups and the largest specific surface area. The adsorption efficiency of the tested ions from natural water is lower than that from a model solution made from deionised water. The lowest efficiencies are obtained when the process occurs from highly mineralised water.
ABSTRACT
The adsorption of nickel Ni(II) and chromium Cr(III) ions on the commercial activated carbons WG-12, F-300 and ROW 08, which differ in their pore structure and the chemical nature of their surfaces, were analyzed. The nickel ions Ni2+ were best adsorbed on the WG-12 activated carbon, which had the largest number of carboxyl and lactone groups on the surface of the activated carbons, and the largest specific surface area. Chromium, occurring in solutions with pH = 6 in the form of Cr(OH)2+ and Cr(OH)2+ cations, was best adsorbed on the ROW 08 Supra activated carbon, which is characterized by the highest values of water extract. The precipitation of chromium hydroxide in the pores of the activated carbon was the mechanism responsible for the high adsorption of Cr(III) on this carbon. For the other sorbents, the amount of carboxyl and lactone groups determined the amount of Cr(III) and Ni(II) adsorption. The adsorption kinetics results were described with PFO, PSO, Elovich and intraparticle diffusion models. The highest correlation coefficients for both the Cr(III) and Ni(II) ions were obtained using the PSO model. Among the seven adsorption isotherm models, very high R2 values were obtained for the Toth, Temkin, Langmuir and Jovanovic models. The Cr(III) ions were removed in slightly larger quantities than the Ni(II) ions. The capacities of the monolayer qm (calculated from the Langmuir isotherm) ranged from 55.85 to 63.48 mg/g for the Cr(III), and from 40.29 to 51.70 mg/g for the Ni(II) ions (pH = 6). The adsorption efficiency of Cr(III) and Ni(II) cations from natural waters with different degrees of mineralization (spring, weakly and moderately mineralized) was only a few percent lower than that from deionized water.
