Organochlorine pesticides and polychlorinated biphenyls in city drains in Makurdi, central Nigeria: Seasonal variations, source apportionment and risk assessment.

A study of seasonal variation, sources and potential risks of organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) in open city drains in Makurdi, Central Nigeria was carried out. OCPs and PCBs were quantified using gas chromatograph-mass spectrometer. The total (∑8OCPs) concentrations (ngL-1) of OCPs in water was 2.99 with a mean ± SD of 0.75 ± 0.12 during wet season, while during dry season, the values were 11.43 and 2.86 ± 1.54 respectively. In sediment, the total concentration (ngg-1) of OCPs was 5270.66 with a mean ± SD of 1756.89 ± 450.01 during wet season and a total concentration of 5837.93 and the mean ± SD of 1945.98 ± 646.04, during dry season. Source apportionment of OCPs suggested historic application of the pollutants. The total (∑7PCBs) concentration (ngL-1) of PCBs in water was 0.24 with a mean ± SD of 0.03 ± 0.02 during wet season and a total concentration of 0.61 with a mean ± SD of 0.09 ± 0.11 during dry season. The total concentration (ngg-1) of PCBs in sediment was 37.88, mean ± SD of 5.41 ± 5.93 during wet season and a total of 47.07 and mean ± SD of 6.72 ± 7.27 during dry season. Ecological risk assessment based on effect range low (ERL) and effect range median (ERM) or threshold effect level (TEL) and probable effect level (PEL) that ecological risks were possible for some OCPs in this study, which calls for source control and remediation of the affected sites. Toxicity equivalency (TEQ) of PCB-118, the dioxin-like congener, indicated that it was most harmful to humans/mammals followed by birds, then fish.

Legacy and novel brominated flame-retardants in different fish types from inland freshwaters of South Africa: levels, distribution and implications for human health.

This study report the presence of polybrominated biphenyls (PBBs), polybrominated diphenyl ethers (PBDEs) and novel brominated flame-retardants (NBFRs) in muscle tissues of Labeo capensis (mudfish), Labeo umbratus (moggel), Cyprinus carpio (carp) and Clarias gariepinus (catfish) from Vaal River, South Africa. The concentrations (in ng g-1 wet weight (ww)) of these contaminants ranged from LOQ to 12.8 ng g-1 ww in catfish, with lowest concentrations found for mudfish ranging from

Removal of per- and polyfluoroalkyl substances from aqueous media using synthesized silver nanocomposite-activated carbons.

PURPOSE: Per- and polyfluoroalkyl substances (PFAS) have been found to be widespread, extremely persistent and bioaccumulative with toxicity tendencies. Pre-synthesized nanocomposite-activated carbons, referred to, as physically activated maize tassel silver (PAMTAg) and chemically activated maize tassel silver (CAMTAg) were utilized in the present study. They were used for the removal of 10 PFAS from aqueous solutions. METHODS: The nanocomposite-activated carbons were characterized via scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, Brunauer Emmett Teller (BET) and other techniques. Batch equilibrium experiments were conducted in order to investigate the effects of solution pH, adsorbent dosage, initial PFAS concentration and temperature on the removal of PFAS using PAMTAg and CAMTAg. Langmuir and Freundlich adsorption isotherm models were used to analyse the equilibrium data obtained. RESULTS: Maximum adsorption capacities of 454.1 mg/g (0.91 mmol/g) and 321.2 mg/g (0.78 mmol/g) were recorded for perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA), respectively using CAMTAg. The values recorded for the Gibbs' free energy (ΔG°) for the adsorption of PFOS and PFOA onto PAMTAg and CAMTAg were negative; PFOS (-9.61, -9.99 and - 10.39), PFOA (-8.77, -9.76 and - 10.21) using PAMTAg; and PFOS (-13.70, -12.70 and - 12.37), PFOA (-12.86, -12.21 and - 11.17) using CAMTAg. Therefore, the adsorption processes were spontaneous and feasible. The values recorded for enthalpy (ΔH°) (kJ/mol) for the adsorption of PFOS (-26.15) and PFOA (-35.86) onto CAMTAg were negative, indicating that the adsorption mechanism is exothermic in nature. Positive values were recorded for ΔH° for the adsorption of PFOS (2.32) and PFOA (12.69) onto PAMTAg, indicative of an endothermic adsorption mechanism. Positive entropy (ΔS°) values (0.04 and 0.07) were recorded for PFOS and PFOA using PAMTAg; whereas negative values (-0.04 and - 0.08) were recorded for ΔS° using CAMTAg. A positive ΔS° indicates an increase in randomness of the adsorbate at the solid-solution interface and the reverse is the case for a negative ΔS°. CONCLUSION: The interplay of electrostatic attraction and hydrophobic interactions enabled the removal of PFAS using PAMTAg and CAMTAg. Findings suggest that PAMTAg and CAMTAg are effective for the removal of PFAS from aqueous media and are good alternatives to commercially available activated carbons. SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s40201-020-00597-3.

Levels of polybrominated diphenyl ethers (PBDEs) in water and sediment from open city drains in Makurdi Metropolitan Area, North Central Nigeria.

Polybrominated diphenyl ethers (PBDEs) have been classified as persistent organic pollutants (POPs) as well as endocrine-disrupting compounds (EDCs). This study determined the concentrations of six PBDE congeners (BDE 47, BDE 99, BDE 100, BDE 153, BDE 154, and BDE 183) in water and sediment samples from open city drains, in the Makurdi Metropolitan Area, North Central Nigeria, using gas chromatogragh-mass spectrometer. These congeners are components of the penta- and octa-BDE formulations that have been banned by the European Union. The samples were collected from the drains, bi-monthly, for 1 year across dry and wet seasons. All the congeners considered were found to be present in both water and sediment. The levels of Σ6PBDEs in water ranged from 0.05 to 0.28 ng L-1 during dry season and 0.02 to 0.36 ng L-1 during wet season, while their levels in sediment during dry and wet seasons ranged from 3.22 to 26.26 ng g-1 and 7.51 to 27.41 ng g-1, respectively. The percentage recoveries from solid phase and Soxhlet extractions ranged from 69 to 104% and 70 to 112%, respectively. It was concluded that the presence of all the congeners in both water and sediment posed a pollution risk to the river in which the drains discharge and require further monitoring and necessary preventive measures.

Levels, distributions, and ecological risk assessments of polybrominated diphenyl ethers and alternative flame retardants in river sediments from Vaal River, South Africa.

Sediments are known to be the ultimate sink for most pollutants in the aquatic environment. In this study, the concentrations of both legacy polybrominated diphenyl ethers (PBDEs) and alternative halogenated flame retardants (AHFRs) were measured in sediments samples from the Vaal River catchment. The concentrations of Σ7BDE-congeners ranged from 20 to 78 ng g-1 dry weight (dw) with BDE-209, -99, and -153 as the dominant congeners. The concentrations observed ranged from 9.4-56, 4-32, and 1-10.6 ng g-1 for BDE-209, -99, and -153, respectively. The concentrations of AHFRs, mainly contributed by decabromodiphenyl ethane (DBDPE) at approximately 95% of total AHFRs, ranged from 64 to 359 ng g-1 dw while the concentration of polybrominated biphenyls (PBBs), mainly PBB-209, ranged from 3.3-7.1 ng g-1 dw. The ratios of AHFRs to PBDEs observed in this study were 0.76, 1.17, and 7.3 for 2-ethyl-1-hexyl-2,3,4,5-tetrabromobenzoate and bis-(2-ethylhexyl)-tetrabromophthalate (EH-TBB & BEH-TEBP)/penta-BDE; 1,2-bis-(2,4,6-tribromophenoxy) ethane (BTBPE)/octa-BDE; and DBDPE/BDE209, respectively. These results indicate dominance of some AHFRs compared to PBDEs. Our results indicates that BDE-99 poses high risk (RQ > 1) while BDE-209 posed medium risk (0.1 < RQ < 1). Though the concentration of DBDPE was several orders of magnitude higher than BDE209, its ecological risk was found to be negligible (RQ < 0.01). Thus, more attention is required to regulate the input (especially the e-waste recycling sites) of brominated flame retardants into the environment.

The occurrence of brominated flame retardants in the atmosphere of Gauteng Province, South Africa using polyurethane foam passive air samplers and assessment of human exposure.

Polyurethane foam passive samplers were deployed between May 2016 and January 2017 to evaluate concentrations of polybrominated diphenyl ethers (PBDEs), selected alternative flame retardants (AFRs) and total hexabromocyclododecane (HBCDD) (sum of α-, ß-, and γ-HBCDD). The PUF air samplers were deployed in semi-urban, urban, industrial and landfill sites in Gauteng Province, South Africa. The acquired results presented a clear semi urban-industrial-urban-landfill concentration gradient for all BFRs measured. Taking into account 2 sampling periods (cold and warm periods) (n = 16), the atmospheric concentrations of ∑9PBDEs, HBCDDs and ∑AFRs were 100-2820 pg m-3, 12-117 pg m-3 and 41-4660 pg m-3, respectively, for the sparsely populated residential area, densely populated residential area, industrial area and the landfill area. In all cases, BDE 47, 99, and 209 were the most dominant congeners with high detection frequencies. The highest calculated daily exposure dose in Gauteng Province atmosphere was 0.61 and 1.54 ng kg -1 - bw d -1 for adults and children respectively. The estimated total intake of PBDEs was 0.47-33.4 ng kg -1 - bw d -1, which was generally below the lowest adverse effect limit (LOAEL), suggesting that the residents of Gauteng Province may not be significantly affected as a result of their exposure to these pollutants through inhalation. However, this does not necessarily suggest that the pollutants are harmless to human health, since they have the tendency to bioaccumulate in biological systems. Incidentally, this is the first study from Africa to report on the atmospheric concentrations of PBDEs, HBCDDs and AFRs in urban, landfill and industrial areas. The findings from this study further highlight the contributory role of landfills as potential sources of BFRs into the atmosphere.

Determination of legacy and novel brominated flame retardants in dust from end of life office equipment and furniture from Pretoria, South Africa.

Indoor dust is known to be a source of human exposure to brominated flame retardants (BFRs) and these consists of the legacy polybrominated diphenyl ethers (PBDEs), total hexabromocyclododecane (T-HBCDD) and the "Novel or alternate" Brominated flame retardants (NBFRs). In this study, x-ray fluorescence (XRF) analyser was employed to measure elemental bromine contents in office furniture and electronics as the first indication of the possible presence of BFRs. To investigate the possible BFRs present, a total of 21 dust samples were collected from surfaces of electronic equipment and office furniture and were analysed using gas chromatography-mass spectrometry (GC-MS). The concentrations of ∑7 BDE- congeners ranged from 50 to 3346ngng-1. Of the ∑7 BDE congeners analysed, BDE-209, -183 and -99 were the most dominant congeners. The concentrations observed ranged from

Preliminary screening of polybrominated diphenyl ethers (PBDEs), hexabromocyclododecane (HBCDD) and tetrabromobisphenol A (TBBPA) flame retardants in landfill leachate.

The occurrence of selected brominated flame retardants, including nine polybrominated diphenyl ether (PBDE) congeners, hexabromocyclododecane (HBCDD) and tetrabromobisphenol A (TBBPA) in leachate samples from eight landfill sites in South Africa, were investigated. In addition, the possible influences of dissolved organic carbon on their levels were also evaluated. Filtered leachate samples were subjected to solid-phase extraction to isolate the various target compounds. PBDEs with six bromine substituents and above, as well as α-HBCDD, ß-HBCDD and TBBPA, were generally found below the detection limit. However, the mean value of the total lower PBDE congeners ranged between 0.04 and 0.48 µg L-1, and the concentrations of γ-HBCDD ranged from not detectable (ND) to 0.05 µg L-1. No significant correlation was observed between the target compounds and dissolved organic carbon, although weak to moderate correlations were mostly observed for the lower PBDEs.

Soil concentrations of polybrominated diphenyl ethers and trace metals from an electronic waste dump site in the Greater Accra Region, Ghana: Implications for human exposure.

Unregulated electronic waste (e-waste) recycling operations have become a significant environmental issue as well as human health risk in developing countries across the world. The present study evaluated the extent of pollution in Agbogbloshie e-waste recycling site in Accra, Ghana. The concentrations of polybrominated diphenyl ethers (PBDEs) and some selected trace metals were determined using gas chromatography electron impact ionization mass spectrometry and flame atomic absorption spectrophotometry, respectively. The concentrations of ∑ PBDEs ranged from 15.6 to 96.8ngg-1 dry weight, with an overall mean of 54.8ngg-1dw. BDE-28 was the dominant congener followed by BDE-209 and BDE-47. The order of mean concentrations of the abundant trace metals was Fe>Cu>Pb≫Mn, with a mean range of .531-289mgkg-1. Geoaccumulation index suggested that the surface soils deteriorated from moderate to high metal pollution, particularly for Cu, Pb and Fe. Of the trace metals analysed, Fe exhibited the highest concentration ranging from 3.97 to 918mgkg-1. Correlation and principal component analyses suggested possible interactions between PBDEs and the trace metals analysed, while source assessment suggested that PBDEs and trace metals were mostly derived from inputs from the e-waste recycling activities. Average daily dose (ADD) was estimated using concentrations corresponding to 5th percentile, median and 95th percentile. Hazard quotients of 380 and 862 were obtained for adults and children respectively, for Cu and Pb which is a cause for concern especially for local children.

Recent approaches to improving selectivity and sensitivity of enzyme-based biosensors for organophosphorus pesticides: A review.

Pesticide determination has attracted great attention due to the fact that they exhibit high acute toxicity and can cause long-term damage to the environment and human lives even at trace levels. Although classical analytical methods (including gas chromatography, high performance liquid chromatography, capillary electrophoresis and mass spectrometry) have been effectively used for analysis of pesticides in contaminated samples, they present certain limitations such as time-consuming sample preparation, complexity, and the requirement of expensive instrumentation and highly skilled personnel. For these reasons, there is an expanding need for analytical methods able to provide simple, rapid, sensitive, selective, low cost and reliable detection of pesticides at trace levels. Over the past decades, acetylcholinesterase (AChE) biosensors have emerged as simple, rapid and ultra-sensitive tools for toxicity detection of pesticides in the environment and food. These biosensors have the potential to complement or replace the classical analytical methods by simplifying or eliminating sample preparation and making field-testing easier and faster with significant decrease in cost per analysis. With the recent engineering of more sensitive AChE enzymes, the development of more reliable immobilization matrices and the progress in the area of microelectronics, AChE biosensors could become competitive for multi-analyte screening and soon be used for the development of portable instrumentation for rapid toxicity testing of samples. The enzymes organophosphorus hydrolase (OPH) and organophosphorus acid anhydrolase (OPAA) have also shown considerable potential in OP biosensor applications and they have been used for direct detection of OPs. This review presents the recent advances in the fabrication of enzyme biosensors for organophosphorus pesticides (OPs) and their possible applications for toxicity monitoring of organophosphorus pesticide residues in real samples. The focus will be on the different strategies for the biosensor construction, the analytical performance of the biosensors and the advantages and disadvantages of these biosensor methods. The recent works done to improve the analytical performance, sensitivity and selectivity of these biosensors will also be discussed.

Concentration profiles, source apportionment and risk assessment of polycyclic aromatic hydrocarbons (PAHs) in dumpsite soils from Agbogbloshie e-waste dismantling site, Accra, Ghana.

The concentrations of eighteen (18) polycyclic aromatic hydrocarbons (PAHs), including the 16 USEPA's priority PAHs as well as two alkyl-substituted naphthalenes were determined in dumpsite soils collected from different sampling sites within the Agbogbloshie e-waste dismantling site in Accra, Ghana. Following their isolation with ultrasonic-assisted extraction technique, the concentrations of the PAHs were determined by gas chromatography mass spectrometry (GC-MS). Loss-on-ignition (LOI) method was employed for the determination of total organic carbon (TOC) of the soil samples. The mean Σ18PAHs obtained were 3006, 5627, 3046, 5555, and 7199 ng g(-1) dry weight (dw) for sampling sites A (mosque), B (dismantling site), C (residential house/police station), D (personal computer repairers' shop) and E (e-waste open burning area), respectively. In all cases, the prevalence of phenanthrene, fluoranthene and pyrene was generally observed across the sampling sites. In this study, PAHs with two to three rings and four to six rings exhibited strong positive correlations, whereas BbF and BkF showed weak positive and negative correlations with other PAHs investigated. With the exception of BbF and BkF, all the PAHs had moderate to strong positive correlations with the TOC. Benzo[a]pyrene equivalent (BaPeq) concentration is a useful indicator of the carcinogenic potency of environmental matrices and these ranged between 111 and 454 ng g(-1), which are generally below the 'safe' level of 600 ng g(-1) established for the protection of the environment and human health. Interestingly, the seven carcinogenic PAHs were the major contributors to the BaPeq concentrations accounting between 97.7 and 98.3 %. Despite the minimal risk to cancer via exposure to the investigated dumpsite soil as indicated in the present study, the prolonged exposure to these pollutants via various exposure pathways may result in increased risk to cancer over time. The application of several methodological approaches for PAH source apportionment, including the use of molecular diagnostic ratios, mostly implicated pyrogenic processes as the main sources of PAHs into the investigated dumpsite soils. Furthermore, their compositional profiles across the sampling sites also suggest similar sources of PAHs into the dumpsite soil.

Mercury concentrations in eggshells of the Southern Ground-Hornbill (Bucorvus leadbeateri) and Wattled Crane (Bugeranus carunculatus) in South Africa.

In this study, wild hatched eggshells were collected from the nests of threatened Wattled Crane and South Ground-Hornbill in an attempt to determine their total Hg concentrations. A total of fourteen eggshell samples from both bird species were collected from different study areas in the Mpumlanga and KwaZulu-Natal Provinces of South Africa. The eggshells were acid digested under reflux and their total Hg concentrations were determined using cold-vapour atomic absorption spectrophotometry (CV-AAS). The observed total Hg levels for the South Ground-Hornbill samples ranged from 1.31 to 8.88 µg g(-1) dry weight (dw), except for one outlier which had an elevated 75.0 µg g(-1) dw. The levels obtained for the Wattled Crane samples were relatively high and these ranged from 14.84 to 36.37 µg g(-1) dw. Generally, all the measured total Hg concentrations for the Wattled Crane samples exceeded the estimated total Hg levels derived for eggshell which were known to cause adverse reproductive effects in avian species from previous studies. Based on these findings, it is, therefore, possible that the exposure of these birds to elevated Hg may have contributed to their present population decline.

Polybrominated diphenyl ethers (PBDEs) in eggshells of the Southern Ground-Hornbill (Bucorvus leadbeateri) and Wattled Crane (Bugeranus carunculatus) in South Africa.

This study was undertaken to assess the levels of eight PBDE congeners, namely: PBDE-17, 47, 100, 99, 154, 153, 183 and 209 in eggshells of Southern Ground-Hornbill (SGH) Bucorvus leadbeateri and Wattled Crane (WC) Bugeranus carunculatus obtained from different nesting sites within the eastern savanna of Limpopo Province and the midlands of KwaZulu-Natal, respectively. Analyses were performed using gas chromatography­mass spectrometry employing the electron impact ionization technique. The results obtained indicated that the lower brominated congeners were predominant in both species. The total PBDEs ranged between not detected (ND) to 264 µg g−1 lipid weight and 5.98­7146 µg g−1 lipid weight in the SGH and WC samples, respectively. More so, the mean recoveries of the 13C-labelled surrogate standards ranged between 40% (PBDE-100) and 136% (PBDE-99). The potential hazards to these birds via PBDEs exposure were evaluated by determining the hazard quotients (HQs) by employing the established Lowest Observed Effect Level (LOEL) values associated with impaired pipping and hatching success as well as that associated with impaired reproduction. HQs values varying from 0.58 to 0.94 and 27.71 to 45.27, respectively were obtained for SGH and WC species. This implies that the SGH populations are exposed to low to moderate hazards, while the WC populations are susceptible to high hazards. Considering the potential threats posed by PBDEs, particularly to the WC species, it is likely that exposure to the current environmental levels of PBDEs by these birds may contribute to their reduced breeding success and declining population trends.

Maize tassel-modified carbon paste electrode for voltammetric determination of Cu(II).

The preparation and application of a practical electrochemical sensor for environmental monitoring and assessment of heavy metal ions in samples is a subject of considerable interest. In this paper, a carbon paste electrode modified with maize tassel for the determination of Cu(II) has been proposed. Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) were used to study morphology and identify the functional groups on the modified electrode, respectively. First, Cu(II) was adsorbed on the carbon paste electrode surface at open circuit and voltammetric techniques were used to investigate the electrochemical performances of the sensor. The electrochemical sensor showed an excellent electrocatalytic activity towards Cu(II) at pH 5.0 and by increasing the amount of maize tassel biomass, a maximum response at 1:2.5 (maize tassel:carbon paste; w/w) was obtained. The electrocatalytic redox current of Cu(II) showed a linear response in the range (1.23 µM to 0.4 mM) with the correlation coefficient of 0.9980. The limit of detection and current-concentration sensitivity were calculated to be 0.13 (±0.01) µM and 0.012 (±0.001) µA/µM, respectively. The sensor gave good recovery of Cu(II) in the range from 96.0 to 98.0 % when applied to water samples.

An amperometric biosensor based on horseradish peroxidase immobilized onto maize tassel-multi-walled carbon nanotubes modified glassy carbon electrode for determination of heavy metal ions in aqueous solution.

A biosensor for trace metal ions based on horseradish peroxidase (HRP) immobilized on maize tassel-multiwalled carbon nanotube (MT-MWCNT) through electrostatic interactions is described herein. The biosensor was characterized using Fourier transform infrared (FTIR), UV-vis spectrometry, voltammetric and amperometric methods. The FTIR and UV-vis results inferred that HRP was not denatured during its immobilization on MT-MWCNT composite. The biosensing principle was based on the determination of the cathodic responses of the immobilized HRP to H2O2, before and after incubation in trace metal standard solutions. Under optimum conditions, the inhibition rates of trace metals were proportional to their concentrations in the range of 0.092-0.55 mg L⁻¹, 0.068-2 mg L⁻¹ for Pb²âº and Cu²âº respectively. The limits of detection were 2.5 µg L⁻¹ for Pb²âº and 4.2 µg L⁻¹ for Cu²âº. Representative Dixon and Cornish-Bowden plots were used to deduce the mode of inhibition induced by the trace metal ions. The inhibition was reversible and mixed for both metal ions. Furthermore, the biosensor showed good stability, selectivity, repeatability and reproducibility.

Distribution of polybrominated diphenyl ethers and dust particle size fractions adherent to skin in indoor dust, Pretoria, South Africa.

In order to determine human exposure to the indoor toxicant, selection of dust fraction and understanding dust particle size distribution in settled indoor dust are very important. This study examined the influence of dust particle size on the concentration of polybrominated diphenyl ethers (PBDEs) congeners, assessed the distribution of dust particle size and characterized the main indoor emission sources of PBDEs. Accordingly, the concentrations of PBDE congeners determined in different indoor dust fractions were found to be relatively higher in the order of dust particle size: 45-106 µm>(<45 µm)>106-150 µm. The finding shows arbitrary selection of dust fractions for exposure determination may result in wrong conclusions. Statistically significant moderate correlation between the concentration of Σ9PBDEs and organic matter content calculated with respect to the total dust mass was also observed (r=0.55, p=0.001). On average, of total dust particle size <250 µm, 93.4 % (m/m%) of dust fractions was associated with less than 150 µm. Furthermore, of skin adherent dust fractions considered (<150 µm), 86 % (v/v%) is in the range of particle size 9.25-104.7 µm. Electronic materials treated with PBDEs were found the main emission sources of PBDE congeners in indoor environment. Based on concentrations of PBDEs determined and mass of indoor dust observed, 150 µm metallic sieve is adequate for human exposure risk assessment. However, research in this area is very limited and more research is required to generalize the fact.

Concentrations of polybromobiphenyls and polybromodiphenyl ethers in home dust: relevance to socio-economic status and human exposure rate.

This study reports on the levels of all major polybromobiphenyls (PBBs) and polybromodiphenyl ethers (PBDEs) in 31 home dust samples collected in Pretoria, South Africa. Low concentrations of PBB and PBDE congeners were detected in 21 and 7 samples, respectively. The Σ10PBDEs concentration ranged from <0.3 to 234 ng g(-1) dry weight (dw) of dust with a median of 18.3 ng g(-1) dw. No significant differences in the total concentration of PBDEs were observed among three socio-economic categories considered. The overall daily intake of PBDEs via ingestion of dust was estimated for children and adults using median concentrations of Σ10PBDEs. Accordingly, for children and adults the exposure rate values are 0.96 and 0.38 ng day(-1), respectively. In addition, the estimated daily dust ingestion exposure rate doses for children and adults with respect to BDE-47 and BDE-99 were by far lower than the reference dose values. It can, therefore, be said that South Africans living in Pretoria are exposed to low concentrations of PBDEs from home environment dust.

Determination of selected phthalate esters compounds in water and sediments by capillary gas chromatography and flame ionization detector.

The presence of phthalate esters (PAEs) in the environment is not desirable and therefore, needs to be monitored. This study reports the first data on the concentration levels of PAEs in water and sediments of the Jukskei River catchment area, South Africa. The study was conducted during the summer and winter seasons of 2005. Liquid-liquid extraction (LLE) and Soxhlet extraction (SE) methods were optimized, evaluated and used to determine PAEs of interest in water (unfiltered and filtered) and sediments samples, respectively. Mean percentage recoveries in spiked doubly distilled water ranged from 100 ± 5.32 dimethyl phthalate (DMP) - 122 ± 0.46 di-2-ethylhexyl phthalate (DEHP) and 91.6 ± 1.93 diethyl phthalate (DEP) - 117 ± 4.80 dibutyl phthalate (DBP) in sediments. The concentration levels of PAEs studied in unfiltered environmental water samples were in the range of 0.04(± 0.00) (DMP) - 9.76(± 00.1) ng mL(-1)(DEHP) for PAEs and from 0.09 (± 0.01) (DMP) - 4.38 (± 0.06) ng mL(-1)(DEHP) for filtered environmental water samples. Concentration levels obtained in sediments were from 0.05 (0.00) (DMP) - 4910 (0.36) ng/gdw (DEHP). PAEs adsorbed on the sample bottle gave concentration levels of up to 0.10 (± 0.03) ng mL(-1)for some samples and no analyte was detected (ND) in some cases Generally, concentrations obtained were below the water quality guideline values of United States Environmental Protection Agency (USEPA).

Trace metals, anions and polybromodiphenyl ethers in settled indoor dust and their association.

Contaminants in settled indoor dust are potentially health hazardous to human. Thus, identification and quantification of toxic chemicals in settled indoor dust is of great concern. In this study, the levels of major anions ([Formula: see text]), trace metals (Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, As and Pb) and polybromodiphenyl ethers (PBDEs) in settled office and home dust were determined and correlations between the contaminants investigated. Depending on the available materials in both microenvironments, the most possible sources were identified. The results showed that the settled office dusts (n = 6 pooled samples from 85 offices) were more contaminated than home dusts (n = 8 homes). For anions, [Formula: see text] and Cl(-) accounted for 87 and 97% of the total office and home dust contaminants, respectively. For trace metals, Fe, Cu, Zn and Mn, accounted for 98% of the contaminants in both office and home dust samples. Fe exhibited the highest percentage of 76.7 and 87.3% in office and home dust samples, respectively. For PBDEs, the mean concentrations detected in office and home dust ranged between 5.8-86.3 and 1.5-20.6 ng g(-1), respectively. The log-transformed correlation between the total concentrations of trace metals and major anions detected in offices and homes was positive for offices and negative for homes with a statistically significant values (r = 0.73, p < 0.01; r = -0.22, p < 0.01, respectively). The daily exposure rates determined for the most hazardous such as As, Cd, Pb and PBDEs congeners, relative to the individual concentrations reported in the literature in settled indoor dust, were found very lower. Therefore, maybe it is possible to expect less potential health risk. Investigation of formation of coordination compounds between trace metals and PBDEs congeners is possible; however, this requires further study.

Characterization of PM10 samples from Vanderbijlpark in South Africa.

In this study, mass concentrations and physico-chemical characteristics of suspended particulates of aerodynamic size 10 µm (PM10) were evaluated. A dual E-Sampler which combines the light scatter and the gravimetric filter methods was used. Sampling occurred between August and December 2009. Scanning Electron Microscope - Energy Dispersive Spectrometry (SEM-EDS) and Inductively Coupled Plasma 6000 were used for elemental and physical characterization. The highest daily average mass concentration measured was 0.03543 mg/m(3) and was below the international and national daily limit of 0.150 mg/m(3), as well as the strict Vaal Triangle regional standard of 0.075 µg/m(3). Relatively high daily average mass concentrations were obtained during the winter period. Concentrations of evaluated heavy metals decreased in the following order: iron (Fe) > manganese (Mn) > zinc (Zn) > copper (Cu) > vanadium (V) > titanium (Ti) > nickel (Ni) > lead (Pb). Positive correlations were established between Zn and Pb (r = 0.916); Zn and Mn (r = 0.883); Zn and V (0.984); Zn and Ni (r = 0.877); Zn and Fe (r = 0.914), which suggests common sources. However, Zn and Ti (r = 0.522); Zn and Cu (0.781) were poorly correlated.