Membrane processes for environmental remediation of nanomaterials: Potentials and challenges.

Nanomaterials have gained huge attention with their wide range of applications. This is mainly driven by their unique properties. Nanomaterials include nanoparticles, nanotubes, nanofibers, and many other nanoscale structures have been widely assessed for improving the performance in different applications. However, with the wide implementation and utilization of nanomaterials, another challenge is being present when these materials end up in the environment, i.e. air, water, and soil. Environmental remediation of nanomaterials has recently gained attention and is concerned with removing nanomaterials from the environment. Membrane filtration processes have been widely considered a very efficient tool for the environmental remediation of different pollutants. Membranes with their different operating principles from size exclusions as in microfiltration, to ionic exclusion as in reverse osmosis, provide an effective tool for the removal of different types of nanomaterials. This work comprehends, summarizes, and critically discusses the different approaches for the environmental remediation of engineered nanomaterials using membrane filtration processes. Microfiltration (MF), ultrafiltration (UF), and nanofiltration (NF) have been shown to effectively remove nanomaterials from the air and aqueous environments. In MF, the adsorption of nanomaterials to membrane material was found to be the main removal mechanism. While in UF and NF, the main mechanism was size exclusion. Membrane fouling, hence requiring proper cleaning or replacement was found to be the major challenge for UF and NF processes. While limited adsorption capacity of nanomaterial along with desorption was found to be the main challenges for MF.

Membrane-based carbon capture: Recent progress, challenges, and their role in achieving the sustainable development goals.

The rapid growth in the consumption of fossil fuels resulted in climate change and severe health issues. Among the different proposed methods to control climate change, carbon capture technologies are the best choice in the current stage. In this study, the various membrane technologies used for carbon capture and their impact on achieving sustainable development goals (SDGs) are discussed. Membrane-based carbon capture processes in pre-combustion and post-combustion, which are known as membrane gas separation (MGS) and membrane contactor (MC), respectively, along with the process of fabrication and the different limitations that hinder their performances are discussed. Additionally, the 17 SDGs, where each representing a crucial topic in the current global task of a sustainable future, that are impacted by membrane-based carbon capture technologies are discussed. Membrane-based carbon capture technologies showed to have mixed impacts on different SDGs, varying in intensity and usefulness. It was found that the membrane-based carbon capture technologies had mostly influenced SDG 7 by enhancement in the zero-emission production, SDG 9 by providing 38-42% cost savings compared to liquid absorption, SDG 3 through reducing pollution and particulate matter emissions by 23%, and SDG 13, with SDG 13 being the most positively influenced by membrane-based carbon capture technologies, as they significantly reduce the CO2 emissions and have high CO2 capture yields (80-90%), thus supporting the objectives of SDG 13 in combatting climate change.

Membrane-based water and wastewater treatment technologies: Issues, current trends, challenges, and role in achieving sustainable development goals, and circular economy.

Membrane-based technologies are recently being considered as effective methods for conventional water and wastewater remediation processes to achieve the increasing demands for clean water and minimize the negative environmental effects. Although there are numerous merits of such technologies, some major challenges like high capital and operating costs . This study first focuses on reporting the current membrane-based technologies, i.e., nanofiltration, ultrafiltration, microfiltration, and forward- and reverse-osmosis membranes. The second part of this study deeply discusses the contributions of membrane-based technologies in achieving the sustainable development goals (SDGs) stated by the United Nations (UNs) in 2015 followed by their role in the circular economy. In brief, the membrane based processes directly impact 15 out of 17 SDGs which are SDG1, 2, 3, 5, 6, 7, 8, 9, 11, 12, 13, 14, 15, 16 and 17. However, the merits, challenges, efficiencies, operating conditions, and applications are considered as the basis for evaluating such technologies in sustainable development, circular economy, and future development.

Role of microalgae in achieving sustainable development goals and circular economy.

In 2015, the United Nations General Assembly (UNGA) set out 17 Sustainable Development Goals (SDGs) to be achieved by 2030. These goals highlight key objectives that must be addressed. Each target focuses on a unique perspective crucial to meeting these goals. Social, political, and economic issues are addressed to comprehensively review the main issues combating climate change and creating sustainable and environmentally friendly industries, jobs, and communities. Several mechanisms that involve judicious use of biological entities are among instruments that are being explored to achieve the targets of SDGs. Microalgae have an increasing interest in various sectors, including; renewable energy, food, environmental management, water purification, and the production of chemicals such as biofertilizers, cosmetics, and healthcare products. The significance of microalgae also arises from their tendency to consume CO2, which is the main greenhouse gas and the major contributor to the climate change. This work discusses the roles of microalgae in achieving the various SDGs. Moreover, this work elaborates on the contribution of microalgae to the circular economy. It was found that the microalgae contribute to all the 17th SDGs, where they directly contribute to 9th of the SDGs and indirectly contribute to the rest. The major contribution of the Microalgae is clear in SDG-6 "Clean water and sanitation", SDG-7 "Affordable and clean energy", and SDG-13 "Climate action". Furthermore, it was found that Microalgae have a significant contribution to the circular economy.

Recent progress in renewable energy based-desalination in the Middle East and North Africa MENA region.

BACKGROUND: The Middle East and North Africa (MENA) countries are rapidly growing in population with very limited access to freshwater resources. To overcome this challenge, seawater desalination is proposed as an effective solution, as most MENA countries have easy access to saline water. However, desalination processes have massive demand for energy, which is mostly met by fossil fuel-driven power plants. The rapid technological advancements in renewable energy technologies, along with their gradually decreasing cost place renewable energy-driven power plants and processes as a promising alternative to conventional fuel-powered plants. AIM OF REVIEW: In the current work, renewable energy-powered desalination in the MENA region is investigated. Various desalination technologies and renewable energy resources, particularly those available in MENA are discussed. A detailed discussion of suitable energy storage technologies for incorporation into renewable energy desalination systems is also included. KEY SCIENTIFIC CONCEPTS OF REVIEW: The progress made in implementing renewable energy into power desalination plants in MENA countries is summarized and analyzed by describing the overall trend and giving recommendations for the potential amalgamation of available renewable energies (REs) and available desalination technologies. Finally, a case study in the MENA region, the Al Khafji solar seawater reverse osmosis (SWRO) desalination plant in the Kingdom of Saudi Arabia KSA, is used to demonstrate the implementation of REs to drive desalination processes.

Pathways resilient future for developing a sustainable E85 fuel and prospects towards its applications.

The utilization of ethanol as a component of motor gasolines is an extremely effective way to increase the detonation resistance and environmental properties. In Russia, despite the existing prerequisites for the development of bioethanol industry, the real production of bioethanol is not executed, which is associated with its high price. One of the promising ways of leveling this drawback is the utilization of water-cut waste from its production, involving ethyl alcohol impurity concentrate (EAIC) instead of pure ethanol. This is a mixture of head and bottoms fractions obtained in the process of ethyl alcohol purification by distillation. This research paper investigates the impact of the nature of hydrocarbon fraction blended with ethyl alcohol impurity concentrate on the final characterization of E85 fuel and, in particular, on its phase stability and Reid vapor pressure. Physicochemical characteristics of the developed fuel composition were studied. The results indicated that none of the possible classes of hydrocarbons could effectively solve the problems of phase stability and volatility of E85 fuel. Additionally, methyl tert-butyl ether (MTBE) was the only promising component. The composition, consisting of 70 % ethyl alcohol impurity concentrate and 30 % methyl tertiary butyl ether, met the requirements of American society for testing and materials (ASTM 5798) in almost all respects. A significant discrepancy is observed only in the water content, which is compensated by the great phase stability of the composition at low temperatures. In addition, this fuel composition is characterized by great potential competitiveness in Russian conditions and without fiscal support, which was proved by preliminary calculations of the cost of E85 fuel.

Geopolymer concrete as green building materials: Recent applications, sustainable development and circular economy potentials.

Environmental degradation and increased greenhouse gas emissions force communities to achieve sustainable green building and construction materials. The environmental and financial aspects of sustainable development and circular economy strongly depend on the recycling of wastes into new products. Geopolymers gained increasing attention because of their eco-friendly and superior mechanical characteristics and their ability to utilize numerous wastes as precursors. Although there are numerous studies on geopolymer, little attention was focused on geopolymer concrete (GeoC). Hence, This review follows the Preferred Reporting Items for Systematic Reviews (PRISMA) investigated in detail GeoC. The first part of this study explores the recent synthesis processes, different precursors, and applications of geopolymer concrete (GeoC) in numerous sectors as well as the mechanical, microstructural, and physical related characteristics of GeoC developed from various wastes. The second part discusses in detail the contributions of GeoC to the sustainable development goals (SDGs) stated by the United Nations. The last part discusses the implementation of different wastes to develop GeoC-based circular economy to provide recommendations and prospects for GeoC science and technology. An eco-friendly, sustainable, structurally sound GeoC matrixes can be developed from numerous industrial, municipal, and agricultural wastes. Such GeoC is a good candidate to traditional concrete and some other building materials. GeoC is strongly contribute into 12 SDGs of the main 17 SDGs. Optimizing the elements of GeoC would decrease its cost and thus promote a green circular economy.

High energy storage quasi-solid-state supercapacitor enabled by metal chalcogenide nanowires and iron-based nitrogen-doped graphene nanostructures.

Transition metal selenides (TMS) have excellent research prospects and significant attention in supercapacitors (SCs) owing to their high electrical conductivity, superior electrochemical activity and excellent structural stability. However, the commercial utilization of TMS remains challenge due to their elaborate synthesis. Present study designed a hierarchical cobalt selenide (CoSe2) nanowire array on Ni-foam to serve as a positive electrode for asymmetric SCs (ASCs). The nanowires-like morphology of CoSe2 was highly advantageous for SCs, as it offered enhanced electrical conductivity, plenty of surface sites, and short ion diffusion. The as-obtained, CoSe2 nanowire electrode demonstrated outstanding electrochemical features, with an areal capacity of 1.08 mAh cm-2 at 3 mA cm-2, high-rate performance (69.5 % at 50 mA cm-2), as well as outstanding stability after 10,000 cycles. The iron titanium nitride@nitrogen-doped graphene (Fe-TiN@NG) was prepared as a negative electrode to construct the ASCs cell. The obtained ASCs cell illustrated an energy density of 91.8 W h kg-1 at a power density of 281.4 W kg-1 and capacity retention of 94.6% over 10,000 cycles. The overall results provide a more efficient strategy to develop redox-ambitious active materials with a high capacity for advanced energy-storage systems.

New insights on introducing modern multifunctional additives into motor gasoline.

Multifunctional additives should be added into motor gasoline to raise the life of engine parts, increase the engine power, as well as reduce the exhaust emission and fuel consumption. This research article proposes new insights to produce modern multifunctional motor gasoline additives. The main components of these additives are detergents, corrosion inhibitors, and friction modifier. Additionally, original methods for assessing the effectiveness of detergent and tribological properties were studied. The test method for the interfacial surface tension is unsuitable for the primary assessment of the effectiveness of the detergent component of the additive package. However, it can well be used to control the quality of individual batches of multifunctional additives directly in production, if further comparison is made with the data obtained during the current control in production. For the initial assessment of detergent properties, the bench method can be modified by accelerating the formation of deposits on engine parts by running for 20 h on gasoline containing 3% wt of N-methylaniline (NMA). The results presented that the relative decrease in mechanical power losses when using the additive package correlates with the indicator of reducing the diameter of the wear scar. Moreover, new technical solutions were proposed to increase the availability of experimental evaluation of multifunctional additives into gasoline. Finally, these make it possible to achieve significant savings in time and money in the development and modification of multifunctional additives compositions into motor gasoline.

Uniqueness technique for introducing high octane environmental gasoline using renewable oxygenates and its formulation on Fuzzy modeling.

The depletion of fuel production and raising ecological issues have paid the progress of biofuels in the entire world. Among different biofuels is introducing renewable fuel additives as prospective beneficial blendstocks towards fulfilling systematic, low-carbon technologies internal combustion engines. This research article proposes a new approach to formulate a Fuzzy modeling for examining various promising alternative renewable oxygenated compounds, including ethanol, isopropanol, MTBE, and 2-methyl furan into heavy hydrocracked gasoline a base fuel. No previous study has utilized Fuzzy modeling in formulation of producing high octane fuel based on renewable additives compounds. The effect of selected additives was investigated on the antiknock characteristics. The results reported that the quality and quantity of heavy hydrocracked naphtha have been reinforced, using low carbon oxygenates. Besides, the acquired results provided the possibility to determine the optimum range of selected renewable oxygenates percentages of 30-50% wt. The calculated data of Fuzzy modeling were verified with experimental results. It illustrated that predicted environmental gasoline yields agreed well with experimental results. Finally, low carbon liquid fuel could contribute to produce high quality environmental gasoline, improve environmental characteristics, in terms of decreasing greenhouses emissions, and maximize the vehicles technologies.

Faradic capacitive deionization (FCDI) for desalination and ion removal from wastewater.

Capacitive deionization (CDI) is one of the emerging desalination technologies that attracted much attention in the last years as a low-cost, energy-efficient, and environmentally-friendly alternative to other desalination technologies, such as multi-stage flash desalination (MSF) and multiple effect distillation (MED). The implementation of faradaic electrode materials is a promising method for enhancing CDI systems' performance by achieving higher salt removal characteristics, lower energy consumption, and better ion selectivity. Therefore, a novel CDI technology named Faradaic CDI (FCDI) that implements faradaic electrode materials arose as a high-performance CDI cell design. In this work, the application of FCDI cells in desalination and wastewater treatment systems is reviewed. First, the progress done on using various FCDI systems for saline water desalination is summarized and discussed. Next, the application of FCDI in wastewater treatment applications and selective ion removal is presented. A thorough comparison between FCDI and conventional carbon-based CDI is carried out in terms of working principle, electrode material's cost, salt removal performance, energy consumption, advantages, and disadvantages. Finally, future research consideration regarding FCDI technology is included to drive this technology closer towards practical application.

A critical review on environmental impacts of renewable energy systems and mitigation strategies: Wind, hydro, biomass and geothermal.

The annual growth of global energy demand and the associated environmental impacts (EIs) has an important role in the large sustainable and green global energy transition. Renewable energy systems have been attracting substantial economic, environmental, and technical attention throughout the last decade, while some have been in the market for almost a century. However, even renewable energy may negatively affect the environment, which is widely considered much less harsh than fossil energy resources. This, in return, requires more consideration and appropriate precautions to be taken. This work discusses the environmental impacts (EIs) of small and medium-sized wind, hydro, biomass, and geothermal power systems. The approach goes through all stages from planning and conception to construction and installation and throughout service life and decommissioning. For various circumstances and technically and ecologically viable guidelines for their effect on natural resources and wildlife, clear and comprehensive solutions have been given.

Environmental impacts of nanofluids: A review.

Nanofluids (NFs) have been expanding their applications in many areas as high-performance heat transfer fluid (HTF) for heating and cooling purposes. This is mainly due to the improved thermophysical properties relative to the base fluid (BF). The addition of nanoparticles (NPs) to BF, to obtain NFs, increases the thermal conductivity, hence better heat transfer properties and thermal performance. The properties of NFs can be considered somehow intermediate between those of the BF and the added solid NPs. The improved heat transfer using NFs results in increased energy conversion efficiency, which results in reduced energy consumption for heating or cooling applications. BF and their environmental impacts (EIs) have been widely discussed within the scope of their applications as a HTF, with most of the attention given to the improved energy efficiency. The IEs of NPs and their toxicity and other characteristics have been extensively studied due to the widespread applications on newly engineered NPs. However, with the evolution of expanding the applications of NFs, the different EIs were not well addressed. The discussion should consider both the base fluid and NPs added in combination as the NF constitutes. The current work presents a brief discussion on the EIs of NFs. The discussion presented in this work considers the NPs as the primary contributor to the EIs of different NFs. It was found that the EIs of NFs depend significantly on the type of NP used, followed by the BF, and finally, the loading of NPs in BF. The use of non-toxic and naturally occurring NPs at lower NPs loading in water as NF promises a much lower EIs in terms of toxicity energy requirements for production, and other EIs, while still maintaining high thermal performance. The production methods of both NPs, i.e., synthesis route, and NF, i.e., one-step or two-step, were found to have a significant effect on the associated EIs of the produced NF. The simpler NP synthesis route and NF production will result in much lower chemicals and energy requirements, which in turn reduce the EIs.

Fuel cells for carbon capture applications.

The harmful effect of carbon pollution leads to depletion of the ozone layer, which is one of the main challenges confronting the world. Although progress is made in developing different carbon dioxide (CO2) capturing methods, these methods are still expensive and face several technical challenges. Fuel cells (FCs) are efficient energy converting devices that produce energy via an electrochemical process. Recently varying kinds of fuel cells are considered as an effective method for CO2 capturing and/or conversion. Among the different types of fuel cells, solid oxide fuel cells (SOFCs), molten carbonate fuel cells (MCFCs), and microbial fuel cells (MFCs) demonstrated promising results in this regard. High-temperature fuel cells such as SOFCs and MCFCs are effectively used for CO2 capturing through their electrolyte and have shown promising results in combination with power plants or industrial effluents. An algae-based microbial fuel cell is an electrochemical device used to capture and convert carbon dioxide through the photosynthesis process using algae strains to organic matters and simultaneously power generation. This review present a brief background about carbon capture and storage techniques and the technological advancement related to carbon dioxide captured by different fuel cells, including molten carbonate fuel cells, solid oxide fuel cells, and algae-based fuel cells.

Evaluation of the nanofluid-assisted desalination through solar stills in the last decade.

Remote areas and poor communities are occasionally deprived of access to freshwater. It is, therefore, critical to providing a cheap and efficient desalination system that encourages the development of those communities and benefiting society at large. Solar stills are an affordable, direct method of water desalination, but its productivity is the critical challenge hindering its application. To ease this, research has focused on the role of nanofluids to improve heat transfer. Other works have focused on improving the design in consort with utilizing the nanofluids. This review reports and discusses the substantial role of nanofluids to enhance the productivity and energy utilization efficiency of the solar stills. Specifically, the mechanism of energy transfer between the nanoparticles and the base fluid. This includes both plasmonic and thermal effects. It is evident that nanofluid utilization in small fraction enhanced the thermal conductivity compared to base fluid alone. Alumina was found to be the most suitable nanoparticle used as nanofluid inside the solar stills due to its availability and lower cost. Still, other competitors such as carbon nanostructures need to be investigated as it provides higher enhancement of thermal conductivity. Also, several aspects of energy utilization enhancement have been discussed, including innovative application techniques. The challenges of such integrated systems are addressed as well.

Environmental impacts of solar energy systems: A review.

The annual increases in global energy consumption, along with its environmental issues and concerns, are playing significant roles in the massive sustainable and renewable global transmission of energy. Solar energy systems have been grabbing most attention among all the other renewable energy systems throughout the last decade. However, even renewable energies can have some adverse environmental repercussions; therefore, further attention and proper precautional procedures should be given. This paper discusses in detail the environmental impacts of several commercial and emerging solar energy systems at both small- and utility-scales. The study expands to some of the related advances, as well as some of the essential elements in their systems. The approach follows all the stages, starting with the designs, then throughout their manufacturing, materials, construction or installation phases, and over operation lifetime and decommissioning. Specific solutions for most systems such as waste minimization and recycling are discussed, alongside with some technically and ecologically favorable recommendations for mitigating the impacts.

Progress in carbon capture technologies.

Human factors are one of the key contributors to carbon dioxide emissions into the environment. Since the industrial revolution, the atmospheric carbon dioxide levels have increased appreciably. This has been attributed to the utilization of fossil fuels for energy generation coupled with the clearing of forests and extensive manufacturing of some industrial products such as cement. The increase in atmospheric concentrations of carbon dioxide has been widely linked to climate change and the Earth's temperature. A drastic approach is therefore needed in terms of policy formulation to address this global challenge. Carbon capture and storage are reliable tools that can be introduced to the industrial sector to address this issue. Therefore, this review presents a thorough investigation of the various technologies that can be harnessed to capture carbon dioxide. The cost associated with the capture, transport, and storage of the carbon dioxide is discussed. Socio-economic aspects of carbon capture and storage technologies are also presented in this review. Factors influencing public awareness of the technology and perceptions associated with carbon capture and storage should be a point for consideration in future research activities relating to this novel technology. This, in effect, this will ensure effective expert knowledge communication to the general public and foster social acceptance of this technology.

Hybrid low-carbon high-octane oxygenated gasoline based on low-octane hydrocarbon fractions.

Low-carbon fuel is the main trend in the development of oil refining in leading countries. Likewise, efforts continue optimizing internal combustion engines for increasing their fuel economy, and therefore exhaust emissions will be reduced. This research proposes a novel approach for producing low-carbon high-octane oxygenated environmentally friendly motor gasoline based on low-octane hydrocarbon fractions. Experimental studies of the antiknock performance for four representatives of oxygenated compounds, involving bioethanol, methyl tertiary butyl ether (MTBE), isopropanol, and 2-methylfuran with low-octane hydrocarbon fractions, as well as low-octane blends of individual hydrocarbons of surrogate fuels were carried out. Additionally, the change in antilocking performance of oxygenated compounds has been dependent on their types and group composition of the base low-octane motor fuel. The results illustrated that high-octane environmentally friendly motor gasolines RON 91 and RON 95 have been produced. Besides, the injectivity of hydrocarbons to oxygenated compounds by the ability to increase the octane rating by the research method will increase in the series: olefins < naphthenes < aromatics < paraffins, and by the motor method:naphthenes < olefins < aromatics < paraffins. Finally, environmentally friendly motor gasoline can decrease the environment impacts, reduce the overhead charges, as well as maximize the product quality.

Review of the regulations and techniques to eliminate toxic emissions from diesel engine cars.

One of the challenging issues affecting the automotive industry in recent times has to do with the total emissions produced by the sector annually. This investigation sums up some of these toxic emissions generated by diesel engine cars. Legislations related to these emissions were also discussed thoroughly. Techniques that can be adopted to eliminate these gases were also investigated as well. In spite of the successes made in this sector, there is still more room for improvement in terms of commitments by all stakeholders in the industry and this has been carefully discussed in this report.

Environmental impact of desalination processes: Mitigation and control strategies.

Freshwater supplies are in shortage relative to the high demand for different human activities, making desalination of saline water a must. Desalination to extract water from saline water has been well established as a reliable non-conventional water supply. However, desalination as any human-based process has resulted in many impacts on the environment. Brine loaded with chemicals being discharged back to the environment, along with greenhouse gases (GHGs) emissions being released to the atmosphere, are the most significant impacts, which has been extensively studied, with some efforts given to its mitigation and control. The current work discusses the mitigation and control strategies (M&CS) to the different environmental impacts (EIs) of desalination processes. The article compiles the M&CS in one work, instead of the distributed and separate treatment of the EIs of each desalination step and its respective M&CS as currently present in literature. The article tracks the water flow in an intake-to-outfall approach exploring how to minimize the impacts at each step and as a whole process. This starts from intake, pretreatment processes, desalination technology, and finally, brine discharge. The EIs associated with each desalination process element is thoroughly discussed with proposed M&CS. The work shows clearly that many EIs can be eliminated or minimized by incorporating specific design criteria and process improvements. The feedwater source has shown to have a great effect on EIs. Similarly, desalination technology has shown a considerable effect on the EIs related to brine characteristics and energy consumption. Hybrid and emerging desalination systems have shown reduced EIs relative to conventional thermal and membrane desalination technologies, while the utilization of renewable and waste energy sources has shown a significant reduction in EIs related to energy consumption.