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Sci Total Environ ; 408(10): 2226-32, 2010 Apr 15.
Article in English | MEDLINE | ID: mdl-20189222

ABSTRACT

The biogeochemical processes affecting the transport and cycling of terrestrial organic carbon in coastal and transition areas are still not fully understood. One means of distinguishing between the sources of organic materials contributing to particulate organic matter (POM) in Babitonga Bay waters and sediments is by the direct measurement of delta(13)C of dissolved inorganic carbon (DIC) and delta(13)C and delta(15)N in the organic constituents. An isotopic survey was taken from samples collected in the Bay in late spring of 2004. The results indicate that the delta(13)C and delta(15)N compositions of OM varied from -21.7 per thousand to -26.2 per thousand and from +9.2 per thousand to -0.1 per thousand, respectively. delta(13)C from DIC ranges from +0.04 per thousand to -12.7 per thousand. The difference in the isotope compositions enables the determination of three distinct end-members: terrestrial, marine and urban. Moreover, the evaluation of source contribution to the particulate organic matter (POM) in the Bay, enables assessment of the anthropogenic impact. Comparing the depleted values of delta(13)C(DIC) and delta(13)C(POC) it is possible to further understand the carbon dynamic within Babitonga Bay.


Subject(s)
Carbon/analysis , Chelating Agents/analysis , Humic Substances/analysis , Nitrogen/analysis , Seawater/chemistry , Water Pollutants, Chemical/analysis , Brazil , Carbon Isotopes/analysis , Ecosystem , Environmental Monitoring/methods , Nitrogen Isotopes/analysis , Sewage/analysis , Water Movements
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