ABSTRACT
We present an innovative solution to improve the efficiency of thermophotovoltaic (TPV) devices by tackling the problem of sub-bandgap photon losses. We propose an optimized design for thin-film mirrors using inverse electromagnetic design principles, thereby enhancing the average reflectivity and photon re-use. Our method surpasses the traditional Bragg mirror by employing a gradient-descent based optimization over Bragg mirror geometrical parameters, leveraging the transfer matrix method for derivative calculations. The optimized structure, based on continuously chirped distributed Bragg reflectors proposed herein demonstrates a remarkable increase in reflectivity beyond 98%, over an almost three-octaves bandwidth (0.1eV-0.74eV). We show that the incident power loss in InGaAs TPV cells at an emitter temperature of 1200°C is significantly reduced. While our work shows considerable promise, further exploration is needed to ascertain the practicability and robustness of these designs under various operational conditions. This study thus provides a major step forward in TPV technology, highlighting a new route towards more effective energy conversion systems.
ABSTRACT
The outer space (3 K) represents an important thermodynamic resource. It has been known for decades that at nighttime, a sky-facing thermal emitter radiating strongly within the atmospheric transparency window (8-13 µm), can reach below the ambient temperature. In recent studies, thermoelectric generators were used to harness this temperature difference between the emitter and ambient to generate electricity. However, the demonstrated power density has been limited by parasitic thermal losses. Here we show that these parasitic losses can be reduced through thermal engineering. We present a simple model showing the optimum power density can be approached by controlling the relation between the emitter area and the thermal resistance of the thermoelectric generator. We show that the stacking of multiple thermoelectric generators is an effective way to approach this optimum. We experimentally demonstrate a generated electric power density >100 mW/m2, representing > 2-fold improvement over the previous results for nighttime radiative cooling.
ABSTRACT
Thermophotovoltaic power conversion utilizes thermal radiation from a local heat source to generate electricity in a photovoltaic cell. It was shown in recent years that the addition of a highly reflective rear mirror to a solar cell maximizes the extraction of luminescence. This, in turn, boosts the voltage, enabling the creation of record-breaking solar efficiency. Now we report that the rear mirror can be used to create thermophotovoltaic systems with unprecedented high thermophotovoltaic efficiency. This mirror reflects low-energy infrared photons back into the heat source, recovering their energy. Therefore, the rear mirror serves a dual function; boosting the voltage and reusing infrared thermal photons. This allows the possibility of a practical >50% efficient thermophotovoltaic system. Based on this reflective rear mirror concept, we report a thermophotovoltaic efficiency of 29.1 ± 0.4% at an emitter temperature of 1,207 °C.
