ABSTRACT
We studied the diffusion of gold nanoparticles in semidilute and entangled solutions of polystyrene (PS) in toluene using fluctuation correlation spectroscopy (FCS). The polymer concentration was varied from approximately 6c* to 20c*, where c* is the overlap concentration. In our experiments, the particle radius (R approximately 2.5 nm) was much smaller compared to the radius of gyration (Rg approximately 18 nm) of the chain but comparable to the average mesh size (xi) of the fluctuating polymer network. The diffusion coefficient (D) of the particles decreased monotonically with polymer concentration and it can be fitted with a stretched exponential function, D=D0 exp(-microcnu), with the value of the scaling parameter, nu approximately 0.9. At high concentration of the polymer, a clear subdiffusive motion of the particles was observed. The results were compared with the diffusion of free dyes (coumarin 480), which showed normal diffusive behavior for all concentrations.
Subject(s)
Diffusion , Gold/chemistry , Metal Nanoparticles/chemistry , Polystyrenes/chemistry , Solutions , Temperature , Toluene/chemistryABSTRACT
We studied critical adsorption on curved surfaces by utilizing spherical nanoparticles immersed in a critical binary liquid mixture of 2,6 lutidine+water. The temperature dependence of the adsorbed film thickness and excess adsorption was determined from fluorescence correlation spectroscopy measurements of the enlarged effective hydrodynamic radius of the particles. Our results indicated that the adsorbed film thickness is of the order of correlation length associated with concentration fluctuations. The excess adsorption per unit area increases following a power law in reduced temperature with an exponent of -1, which is the mean-field value for the bulk susceptibility exponent. This has been confirmed with silica particles of two different radii, 10 and 25 nm. The results were also compared with the theoretical mean-field scaling function.
