Exploring the migration and transformation behaviors of heavy metals and ammonia nitrogen from electrolytic manganese residue to agricultural soils through column leaching test.

Heavy metals (HMs) and ammonia nitrogen (AN) leaching from electrolytic manganese residue (EMR) result in the contamination of agricultural soils and water bodies. Batch and column leaching tests were conducted to simulate the release of HMs and AN in EMR during precipitation, as well as their migration and transformation in agricultural soils. The results show that Mn, AN, Cd, Ni, and Zn present in the EMR had high acid soluble fraction (un-fixed AN) content, and the leachability of Mn and AN was significantly higher than that of other hazardous elements. The cumulative release of hazardous elements in the EMR stockpile was well-fitted (R2 > 0.95) by the HILL model. Significant HMs and AN accumulated in the agricultural soils after contamination from the EMR leachate. The pollution degree of HMs in agricultural soils was ranked as Mn > Ni > Pb ≈ Zn ≈ Cr > Cd. The acid soluble fraction (un-fixed AN) content of Mn, Ni, Zn, and AN in agricultural soils increased significantly. The risk assessment code shows that the risk level of Mn in agricultural soils changed from medium to high; Ni and Zn in surface soils changed from low to medium. These results indicated that the leaching from EMR would significantly increase the ecological risk of HMs in surrounding agricultural soils, and the large release of AN would pose a great threat to aquatic systems if not properly addressed.

Flow and structural analysis of sedimentary rocks by core flooding and nuclear magnetic resonance: A review.

Fluid flow analyses and investigations of associated structural variations in rock formations are important due to the complex nature of rocks and the high heterogeneity that exists within fluid-rock systems. Variations in fluid-rock parameters need to be ascertained over time with continuous or cyclic fluid injection into subsurface rocks for enhanced oil recovery and other subsurface applications. This Review introduces the use of the core flooding-nuclear magnetic resonance (NMR) technique for analysis of combined fluid flow and structural features in subsurface fluid-rock systems. It presents a summary of the results realized by various researchers in this area of study. The influence of several conditions, such as geochemical interactions, wettability, inherent heterogeneities in fluid flow and rock properties, and variations in these parameters, is analyzed. We investigate NMR measurements for both single fluid phase saturation and multiphase saturation. Additionally, the processes for identifying and distinguishing different fluid phases are emphasized in this study. Furthermore, capillary pressure and its influence on fluid-rock parameters are also discussed. Although this study emphasizes subsurface rocks and enhanced oil recovery, the experimental combination is also extended to core flooding using several other injection fluids and porous media. Finally, research gaps pertaining to core flooding-NMR systems regarding fluid flow, structural changes, fluid-rock systems, and instrumentation are pointed out. Transient flow analysis involving structural variations is suggested for future work in this regard.