Solar-Powered Gram-Scale Ammonia Production from Nitrate.

The photoelectrochemical (PEC) method has the potential to be an attractive route for converting and storing solar energy as chemical bonds. In this study, a maximum NH3 production yield of 1.01 g L-1 with a solar-to-ammonia conversion efficiency of 8.17% through the photovoltaic electrocatalytic (PV-EC) nitrate (NO3 -) reduction reaction (NO3 -RR) is achieved, using silicon heterojunction solar cell technology. Additionally, the effect of tuning the operation potential of the PV-EC system and its influence on product selectivity are systematically investigated. By using this unique external resistance tuning approach in the PV-EC system, ammonia production through nitrate reduction performance from 96 to 360 mg L-1 is enhanced, a four-fold increase. Furthermore, the NH3 is extracted as NH4Cl powder using acid stripping, which is essential for storing chemical energy. This work demonstrates the possibility of tuning product selectivity in PV-EC systems, with prospects toward pilot scale on value-added product synthesis.

Leveraging Intermolecular Charge Transfer for High-Speed Optical Wireless Communication.

Intermolecular charge transfer (CT) complexes have emerged as versatile platforms with customizable optical properties that play a pivotal role in achieving tunable photoresponsive materials. In this study, we introduce an innovative approach for enhancing the modulation bandwidth and net data rates in optical wireless communications (OWCs) by manipulating combinations of monomeric molecules within intermolecular CT complexes. Concurrently, we extensively investigate the intermolecular charge transfer mechanism through diverse steady-state and ultrafast time-resolved spectral techniques in the mid-infrared range complemented by theoretical calculations using density functional theory. These intermolecular CT complexes empower precise control over the -3 dB bandwidth and net data rates in OWC applications. The resulting color converters exhibit promising performance, achieving a net data rate of ∼100 Mb/s, outperforming conventional materials commonly used in the manufacture of OWC devices. This research underscores the substantial potential of engineering intermolecular charge transfer complexes as an ongoing progression and commercialization within the OWC. This carries profound implications for future initiatives in high-speed and secure data transmission, paving the way for promising endeavors in this area.

Outage probability analysis of a cooperative NOMA UWOC system with multiuser scheduling under weak oceanic turbulence.

A downlink cooperative non-orthogonal multiple access (NOMA) multiuser underwater wireless optical communication (UWOC) system with a greedy scheduling scheme has been proposed for the Internet of Underwater Things. In particular, the near user plays as a relay to assist the far user, and both decode-and-forward and amplify-and-forward relaying protocols are considered. Relying on the Gauss-Laguerre quadrature formula, the analytical expressions for the outage probability of users are derived considering the degrading effects of the underwater channel, namely, absorption, scattering, and turbulence-induced fading. The outage performance is further analyzed systematically under different water types, targeted data rates, the number of users, the receiver aperture size, and the power allocation coefficient. Numerical results demonstrate that the performance of the far user can be improved by the proposed cooperative NOMA technology. Moreover, the proposed cooperative NOMA system performs better compared with both conventional OMA and non-cooperative NOMA systems. Monte Carlo simulation results are presented to confirm the accuracy of derived expressions, which have a tight agreement with analytical results.

650-nm vertical-cavity surface-emitting lasers (VCSELs) for plastic optical fiber communication.

Vertical-cavity surface-emitting lasers (VCSELs) are widely used as light sources for high-speed communications. This is mainly due to their economical cost, high bandwidth, and scalability. However, efficient red VCSELs with emissions at 650 nm are required for plastic optical fiber (POF) technology because of the low-loss transmission window centered around this wavelength. This study investigates using 650-nm red VCSEL arrays in interconnected systems for POF communication to improve signal quality and increase data rates. The experimental results show that using one red VCSEL with a -3-dB bandwidth of 2 GHz in POF communication can achieve data rates of up to 4.7 Gb/s with 2 pJ/bit power efficiency using direct current-biased optical orthogonal frequency-division multiplexing (DCO-OFDM). The bit error ratio (BER) is 3.6×10-3, which is less than the hard-decision forward-error correction (FEC) limit of 3.8 × 10-3. In addition, temperature dependence measurements of the VCSEL have been presented from 15 ∘C to 38 ∘C. The essential parameters of VCSEL have also been measured: the maximum optical power is 2.5 mW, and the power conversion efficiency is 14%.

Scalable laser-based underwater wireless optical communication solution between autonomous underwater vehicle fleets.

The development of multiple autonomous underwater vehicles (AUVs) has revolutionized the traditional reliance on a single, costly AUV for conducting underwater surveys. This shift has garnered increasing interest among marine researchers. Communication between AUV fleets is an urgent concern due to the data rate limitation of underwater acoustic communication. Laser-based underwater wireless optical communication (UWOC) is a potential solution once the link-establishing requirement between AUVs can be met. Due to the limited coverage area of the laser beam, the previous pointing, acquisition, and tracking (PAT) method is to quickly adjust the beam direction and search for the target according to the set scanning path. In response to these challenges, we propose a scalable laser-based link establishment method that combines the maneuvering of the AUV, the acoustic positioning, and the control of the optical system. Our proposed approach has consistently outperformed the existing PAT method in simulated environments, effectively establishing laser links. Importantly, we have successfully implemented our approach in machine experiments, confirming its practical applicability.

Simultaneous Growth Strategy of High-Optical-Efficiency GaN NWs on a Wide Range of Substrates by Pulsed Laser Deposition.

Here, we explore a catalyst-free single-step growth strategy that results in high-quality self-assembled single-crystal vertical GaN nanowires (NWs) grown on a wide range of common and novel substrates (including GaN, Ga2O3, and monolayer two-dimensional (2D) transition-metal dichalcogenide (TMD)) within the same chamber and thus under identical conditions by pulsed laser deposition. High-resolution transmission electron microscopy and scanning transmission electron microscopy (HR-STEM) and grazing incidence X-ray diffraction measurements confirm the single-crystalline nature of the obtained NWs, whereas advanced optical and cathodoluminescence measurements provide evidence of their high optical quality. Further analyses reveal that the growth is initiated by an in situ polycrystalline layer formed between the NWs and substrates during growth, while as its thickness increases, the growth mode transforms into single-crystalline NW nucleation. HR-STEM and corresponding energy-dispersive X-ray compositional analyses indicate possible growth mechanisms. All samples exhibit strong band edge UV emission (with a negligible defect band) dominated by radiative recombination with a high optical efficiency (∼65%). As all NWs have similar structural and optical qualities irrespective of the substrate used, this strategy will open new horizons for developing III-nitride-based devices.

Acute aortic thrombosis following umbilical artery catheterisation in extremely low birthweight infants: walking the tight rope of management.

Umbilical artery catheterisation (UAC) is crucial in the management of clinically sick infants. One of its dreaded complications is aortic thrombus formation which accounts for significant morbidity and mortality. We present the case of a premature infant born at 32 weeks of gestation and with a birth weight of 960 gm, who developed signs of acute lower limb ischaemia following UAC cannulation. Ultrasound Doppler scan confirmed large aortic thrombus involving iliac arteries. Heparin infusion was started with clinical improvement over the next 12 hours and eventual complete resolution of clot size. This case underscores the importance of prompt detection of acute aortic thrombosis and cautions the use of heparin infusion in preterm infants can be lifesaving. Management can be challenging as risk of bleeding from anticoagulation and thrombolytic therapy can be catastrophic in extreme low birthweight premature infants and need to weigh with risk of severe intravascular haemorrhage.

Multifunctional difluoroboron ß-diketonate-based luminescent receiver for a high-speed underwater wireless optical communication system.

The last decade has witnessed considerable progress in underwater wireless optical communication in complex environments, particularly in exploring the deep sea. However, it is difficult to maintain a precise point-to-point reception at all times due to severe turbulence in actual situations. To facilitate efficient data transmission, the color-conversion technique offers a paradigm shift in large-area and omnidirectional light detection, which can effectively alleviate the étendue limit by decoupling the field of view and optical gain. In this work, we investigated a series of difluoroboron ß-diketonate fluorophores by measuring their photophysical properties and optical wireless communication performances. The emission colors were tuned from blue to green, and >0.5 Gb/s data transmission was achieved with individual color channel in free space by implementing an orthogonal frequency-division multiplexing (OFDM) modulation scheme. In the underwater experiment, the fluorophore with the highest transmission speed was fabricated into a 4×4 cm2 luminescent concentrator, with the concentrated emission from the edges coupled with an optical fiber array, for large-area photodetection and optical beam tracking. The net data rates of 130 Mb/s and 217 Mb/s were achieved based on nonreturn- to-zero on-off keying and OFDM modulation schemes, respectively. Further, the same device was used to demonstrate the linear light beam tracking function with high accuracy, which is beneficial for sustaining a reliable and stable connection in a dynamic, turbulent underwater environment.

Wide-field-of-view optical detectors for deep ultraviolet light communication using all-inorganic CsPbBr3 perovskite nanocrystals.

Optical wireless communication (OWC) links suffer from strict requirements of pointing, acquisition, and tracking (PAT) between the transmitter and receiver. Extending the narrow field-of-view (FoV) of conventional light-focusing elements at the receiver side can relax the PAT requirements. Herein, we use all-inorganic CsPbBr3 nanocrystals (NCs) to extend various optical concentrators' FOV to 60°, regardless of the original FOV values of the concentrators. Given the robustness of UV light against communication channel misalignment, the used CsPbBr3 NCs provide another advantage of converting transmitted UVC light into a green color that matches the peak absorption of the widely available Si-based detectors. We evaluated the feasibility of the reported wide FoV optical detectors by including them in deep UV OWC systems, deploying non-return-to-zero on-off keying (NRZ-OOK) and orthogonal-frequency division multiplexing (OFDM) modulation schemes. The NRZ-OOK and OFDM schemes exhibit stable communication over the 60° FoV, providing data transmission rates of 100 Mb/s and 71.6 Mb/s, respectively, a unique capability to the reported design.

Beam wander prediction with recurrent neural networks.

Among the problems that prevent free-space optical communication systems from becoming a truly mainstream technology is beam wander, which is especially important for structured light beams since beam misalignment introduces additional crosstalk at the receiver. The paper suggests a recurrent neural network-based (RNN) solution to predict beam wander in free space optics (FSO). The approach uses past beam center of mass positions to predict future movement, significantly outperforming various prediction types. The proposed approach is demonstrated using under-sampled experimental data over a 260 m link as a worst-case and over-sampled simulated data as a best-case scenario. In addition to conventional Gaussian beams, Hermite- and Laguerre-Gaussian beam wander is also investigated. With a 20 to 40% improvement in error over naive and linear predictions, while predicting multiple samples ahead in typical situations and overall matching or outperforming considered predictions across all studied scenarios, this method could help mitigate turbulence-induced fading and has potential applications in intelligent re-transmits, quality of service, optimized error correction, maximum likelihood-type algorithms, and predictive adaptive optics.

Submarine optical fiber communication provides an unrealized deep-sea observation network.

Oceans are crucial to human survival, providing natural resources and most of the global oxygen supply, and are responsible for a large portion of worldwide economic development. Although it is widely considered a silent world, the sea is filled with natural sounds generated by marine life and geological processes. Man-made underwater sounds, such as active sonars, maritime traffic, and offshore oil and mineral exploration, have significantly affected underwater soundscapes and species. In this work, we report on a joint optical fiber-based communication and sensing technology aiming to reduce noise pollution in the sea while providing connectivity simultaneously with a variety of underwater applications. The designed multifunctional fiber-based system enables two-way data transfer, monitoring marine life and ship movement near the deployed fiber at the sea bottom and sensing temperature. The deployed fiber is equally harnessed to transfer energy that the internet of underwater things (IoUTs) devices can harvest. The reported approach significantly reduces the costs and effects of monitoring marine ecosystems while ensuring data transfer and ocean monitoring applications and providing continuous power for submerged IoUT devices.

Engineering Metal-Organic Frameworks with Tunable Colors for High-Performance Wireless Communication.

Metal-organic frameworks (MOFs) have emerged as excellent platforms possessing tunable and controllable optical behaviors that are essential in high-speed and multichannel data transmission in optical wireless communications (OWCs). Here, we demonstrate a novel approach to achieving a tunable wide modulation bandwidth and high net data rate by engineering a combination of organic linkers and metal clusters in MOFs. More specifically, two organic linkers of different emission colors, but equal molecular length and connectivity, are successfully coordinated by zirconium and hafnium oxy-hydroxy clusters to form the desired MOF structures. The precise change in the interactions between these different organic linkers and metal clusters enables control over fluorescence efficiency and excited state lifetime, leading to a tunable modulation bandwidth from 62.1 to 150.0 MHz and a net data rate from 303 to 363 Mb/s. The fabricated color converter MOFs display outstanding performance that competes, and in some instances surpasses, those of conventional materials commonly used in light converter devices. Moreover, these MOFs show high practicality in color-pure wavelength-division multiplexing (WDM), which significantly improved the data transmission link capacity and security by the contemporary combining of two different data signals in the same path. This work highlights the potential of engineered MOFs as a game-changer in OWCs, with significant implications for future high-speed and secure data transmission.

Wearable sensors for monitoring marine environments and their inhabitants.

Human societies depend on marine ecosystems, but their degradation continues. Toward mitigating this decline, new and more effective ways to precisely measure the status and condition of marine environments are needed alongside existing rebuilding strategies. Here, we provide an overview of how sensors and wearable technology developed for humans could be adapted to improve marine monitoring. We describe barriers that have slowed the transition of this technology from land to sea, update on the developments in sensors to advance ocean observation and advocate for more widespread use of wearables on marine organisms in the wild and in aquaculture. We propose that large-scale use of wearables could facilitate the concept of an 'internet of marine life' that might contribute to a more robust and effective observation system for the oceans and commercial aquaculture operations. These observations may aid in rationalizing strategies toward conservation and restoration of marine communities and habitats.

Light-Induced Bipolar Photoresponse with Amplified Photocurrents in an Electrolyte-Assisted Bipolar p-n Junction.

The p-n junction with bipolar characteristics sets the fundamental unit to build electronics while its unique rectification behavior constrains the degree of carrier tunability for expanded functionalities. Herein, a bipolar-junction photoelectrode employed with a gallium nitride (GaN) p-n homojunction nanowire array that operates in electrolyte is reported, demonstrating bipolar photoresponse controlled by different wavelengths of light. Significantly, with rational decoration of a ruthenium oxides (RuOx ) layer on nanowires guided by theoretical modeling, the resulting RuOx /p-n GaN photoelectrode exhibits unambiguously boosted bipolar photoresponse by an enhancement of 775% and 3000% for positive and negative photocurrents, respectively, compared to the pristine nanowires. The loading of the RuOx layer on nanowire surface optimizes surface band bending, which facilitates charge transfer across the GaN/electrolyte interface, meanwhile promoting the efficiency of redox reaction for both hydrogen evolution reaction and oxygen evolution reaction which corresponds to the negative and positive photocurrents, respectively. Finally, a dual-channel optical communication system incorporated with such photoelectrode is constructed with using only one photoelectrode to decode dual-band signals with encrypted property. The proposed bipolar device architecture presents a viable route to manipulate the carrier dynamics for the development of a plethora of multifunctional optoelectronic devices for future sensing, communication, and imaging systems.

Nanostructured Gallium Nitride Membrane at Wafer Scale for Photo(Electro)catalytic Polluted Water Remediation.

Photo(electro)catalysis methods have drawn significant attention for efficient, energy-saving, and environmental-friendly organic contaminant degradation in wastewater. However, conventional oxide-based powder photocatalysts are limited to UV-light absorption and are unfavorable in the subsequent postseparation process. In this paper, a large-area crystalline-semiconductor nitride membrane with a distinct nanoporous surface is fabricated, which can be scaled up to a full wafer and easily retrieved after photodegradation. The unique nanoporous surface enhances broadband light absorption, provides abundant reactive sites, and promotes the dye-molecule reaction with adsorbed hydroxyl radicals on the surface. The superior electric contact between the nickel bottom layer and nitride membrane facilitates swift charge carrier transportation. In laboratory tests, the nanostructure membrane can degrade 93% of the dye in 6 h under illumination with a small applied bias (0.5 V vs Ag/AgCl). Furthermore, a 2 inch diameter wafer-scale membrane is deployed in a rooftop test under natural sunlight. The membrane operates stably for seven cycles (over 50 h) with an outstanding dye degradation efficiency (>92%) and satisfied average total organic carbon removal rate (≈50%) in each cycle. This demonstration thus opens the pathway toward the production of nanostructured semiconductor layers for large-scale and practical wastewater treatment using natural sunlight.

Simultaneous distributed acoustic sensing and communication over a two-mode fiber.

We designed and tested a distributed acoustic sensing (DAS) that co-exists with optical communication over a two-mode fiber (TMF). In particular, we excited both linearly polarized (LP) modes, LP01 and LP11a, using a photonic lantern for simultaneous information signal transmission while collecting the backscattered Rayleigh light at the near end of the fiber to detect vibrations from a predetermined source. While transmitting data using on-off keying (OOK) or orthogonal frequency-division multiplexing (OFDM) modulation schemes, the optical fiber DAS offers high signal-to-noise ratio (SNR) values that are always larger than the minimum acceptable 2 dB SNR. In addition, as a proof-of-concept experiment, we report parallel sensing and OFDM transmission achieving a data rate of up to 4.2 Gb/s with a bit error rate (BER) of 3.2 × 10-3.

CNN-Aided Optical Fiber Distributed Acoustic Sensing for Early Detection of Red Palm Weevil: A Field Experiment.

Red palm weevil (RPW) is a harmful pest that destroys many date, coconut, and oil palm plantations worldwide. It is not difficult to apply curative methods to trees infested with RPW; however, the early detection of RPW remains a major challenge, especially on large farms. In a controlled environment and an outdoor farm, we report on the integration of optical fiber distributed acoustic sensing (DAS) and machine learning (ML) for the early detection of true weevil larvae less than three weeks old. Specifically, temporal and spectral data recorded with the DAS system and processed by applying a 100-800 Hz filter are used to train convolutional neural network (CNN) models, which distinguish between "infested" and "healthy" signals with a classification accuracy of ∼97%. In addition, a strict ML-based classification approach is introduced to improve the false alarm performance metric of the system by ∼20%. In a controlled environment experiment, we find that the highest infestation alarm count of infested and healthy trees to be 1131 and 22, respectively, highlighting our system's ability to distinguish between the infested and healthy trees. On an outdoor farm, in contrast, the acoustic noise produced by wind is a major source of false alarm generation in our system. The best performance of our sensor is obtained when wind speeds are less than 9 mph. In a representative experiment, when wind speeds are less than 9 mph outdoor, the highest infestation alarm count of infested and healthy trees are recorded to be 1622 and 94, respectively.

Simultaneous phosphate recovery and sodium removal from brackish aquaculture effluent via diafiltration-nanofiltration process.

Expansion of the aquaculture industry has been accompanied by environmental impact as the discharged effluent contains excess nutrients such as phosphorus compounds. Recovery of such nutrients is not economically feasible as it presents in trace amounts. Furthermore, brackish aquaculture effluent which contains high sodium chloride (NaCl) content makes the treated solution inappropriate for fertilizer production. Herein, this study proposed a diafiltration-nanofiltration route to perform a simultaneous phosphate concentrating and osmotion (sodium) removal from brackish aquaculture effluent. Effects of operating pressure, phosphate, and sodium content on membrane performance were first determined using Desal-5 DK membrane with three types of solutions namely (i) freshwater without NaCl, (ii) dilute brackish water with 1,500 mg/L NaCl, and (iii) brackish water with 10,000 mg/L NaCl. It was found that at 4 bar operating pressure, it could achieve higher phosphate rejection and sodium permeance. The presence of NaCl negatively influenced both phosphate rejection and concentrating factor (CF) due to the salt screening effect. It was noteworthy that negative sodium rejection (up to -16%, CF <1) could be attained, indicating the concentrating effect for sodium was negligible. The concentrating process was effective to concentrate phosphate by 2-fold but less effective in removing sodium. Diafiltration was then introduced and resulted in about 76% of sodium removal. Diafiltration-nanofiltration (DF-NF) mode was shown to be a more efficient method than nanofiltration-diafiltration (NF-DF) mode as phosphate could be concentrated up to 2 factors with 99 wt% of sodium being removed from the real brackish aquaculture effluent. These findings showed that DF-NF is a feasible approach for concentrating phosphate while removing sodium ions from aquaculture effluent and the recovered nutrient solution has huge potential to be applied as liquid fertilizer for hydroponic plants.

Plasmonic Nb2CTx MXene-MAPbI3 Heterostructure for Self-Powered Visible-NIR Photodiodes.

The ability of MXenes to efficiently absorb light is greatly enriched by the surface plasmons oscillating at their two-dimensional (2D) surfaces. Thus far, MXenes have shown impressive plasmonic absorptions spanning the visible and infrared (IR) regimes. However, their potential use in IR optoelectronic applications, including photodiodes, has been marginally investigated. Besides, their relatively low resistivity has limited their use as photosensing materials due to their intrinsic high dark current. Herein, heterostructures made of methylammonium lead triiodide (MAPbI3) perovskite and niobium carbide (Nb2CTx) MXene are prepared with a matching band structure and exploited for self-powered visible-near IR (NIR) photodiodes. Using MAPbI3 has expanded the operation range of the MAPbI3/Nb2CTx photodiode to the visible regime while suppressing the relatively large dark current of the NIR-absorbing Nb2CTx. In consequence, the fabricated MAPbI3/Nb2CTx photodiode has responded linearly to white light illumination with a responsivity of 0.25 A/W and a temporal photoresponse of <4.5 µs. Furthermore, when illuminated by NIR laser (1064 nm), our photodiode demonstrates a higher on/off ratio (∼103) and faster response times (<30 ms) compared to that of planar Nb2CTx-only detectors (<2 and 20 s, respectively). The performed space-charge-limited current (SCLC) and capacitance measurements reveal that such an efficient and enhanced charge transfer depends on the coordinate bonding between the surface groups of the MXene and the undercoordinated Pb2+ ions of the MAPbI3 at the passivated MAPbI3/Nb2CTx interface.

Chlorine-Infused Wide-Band Gap p-CuSCN/n-GaN Heterojunction Ultraviolet-Light Photodetectors.

Copper thiocyanate (CuSCN) is a p-type semiconductor that exhibits hole-transport and wide-band gap (∼3.9 eV) characteristics. However, the conductivity of CuSCN is not sufficiently high, which limits its potential application in optoelectronic devices. Herein, CuSCN thin films were exposed to chlorine using a dry etching system to enhance their electrical properties, yielding a maximum hole concentration of 3 × 1018 cm-3. The p-type CuSCN layer was then deposited onto an n-type gallium nitride (GaN) layer to form a prototypical ultraviolet-based photodetector. X-ray photoelectron spectroscopy further demonstrated the interface electronic structures of the heterojunction, confirming a favorable alignment for holes and electrons transport. The ensuing p-CuSCN/n-GaN heterojunction photodetector exhibited a turn-on voltage of 2.3 V, a responsivity of 1.35 A/W at -1 V, and an external quantum efficiency of 5.14 × 102% under illumination with ultraviolet light (peak wavelength of 330 nm). The work opens a new pathway for making a plethora of hybrid optoelectronic devices of inorganic and organic nature by using p-type CuSCN as the hole injection layer.