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1.
J Hazard Mater ; 162(2-3): 989-93, 2009 Mar 15.
Article in English | MEDLINE | ID: mdl-18614285

ABSTRACT

This study investigates the feasibility of enhanced electrokinetic Fenton process for the remediation of hexachlorobenzene (HCB) in low permeable soil. Laboratory scale experiments were carried out in two different type of experimental setup to evaluate the influence of electrode positions in the system. Kaolin was artificially contaminated with HCB and treated by electrokinetic Fenton process. beta-Cyclodextrin was used to enhance the solubility of HCB in pore fluid. Results show that the position of electrodes in the system and the way in which Fenton's reagent was added to the system has a significant influence on the treatment efficiency.


Subject(s)
Hexachlorobenzene/isolation & purification , Soil Pollutants/isolation & purification , Cyclodextrins/chemistry , Electrochemistry , Kaolin/chemistry , Oxidation-Reduction , Solubility
2.
Article in English | MEDLINE | ID: mdl-18569300

ABSTRACT

The feasibility of enhanced electrokinetic Fenton process for the remediation of Hexachlorobenzene (HCB) in low permeability soil was investigated. Kaolin was artificially contaminated with HCB and treated by electrokinetic and electrokinetic Fenton processes. beta -Cyclodextrin was used to enhance the solubility of HCB in pore fluid. Three tests were carried out, of which two were electrokinetic experiments to observe the suitability of beta -cyclodextrin as a flushing solution for these processes. The third experiment was the electrokinetic Fenton test using beta -cyclodextrin as an enhancing agent. Results show that the removal efficiency depends on the choice of a suitable flushing solution and physical parameters like pH, electric current and electro-osmotic flow.


Subject(s)
Electrochemistry/methods , Hexachlorobenzene/chemistry , Soil Pollutants/chemistry , Cyclodextrins/chemistry , Electrochemistry/instrumentation , Environmental Restoration and Remediation , Hexachlorobenzene/isolation & purification , Hydrogen-Ion Concentration , Soil Pollutants/isolation & purification
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