Organochlorine pesticide contamination of soils and dust from an urban environment in the Niger Delta of Nigeria.

The concentrations, sources, and risk of twenty organochlorine pesticides (OCPs) in soils and dusts from a typical urban setting in the Niger Delta of Nigeria were examined. The Σ20 OCP concentrations (ng g-1) varied from 4.49 to 150 with an average value of 32.6 for soil, 4.67 to 21.5 with an average of 11.7 for indoor dust, and 1.6 to 96.7 with an average value of 23.5 for outdoor dust. The Σ20 OCP concentrations in these media were in the order: soil > outdoor dust > indoor dust, which was in contrast with the order of the detection frequency, i.e., indoor dust (95 to 100 %) > soil (60 to 90 %) > outdoor dust (30 to 80 %). The concentrations of the different OCP classes in these media followed the order: aldrin + dieldrin + endrin and its isomers (Drins) > chlordanes > dichlorodiphenyltrichloroethane (DDTs) > hexachlorocyclohexane (HCHs) > endosulfans for outdoor dust and soil, while that of the indoor dust followed the order: Drins > chlordanes > endosulfans > DDTs > HCHs. The cancer risk values for human exposure to OCPs in these sites exceeded 10-6 which indicates possible carcinogenic risks. The sources of OCPs in these media reflected both past use and recent inputs.

Spatial characteristics, sources and exposure risk of polychlorinated biphenyls in dusts and soils from an urban environment in the Niger Delta of Nigeria.

Chlorinated organic compounds, such as polychlorinated biphenyls (PCBs), are a threat to both humans and the environment because of their toxicity, persistence, and capacity for long-range atmospheric transport. The concentrations of 28 PCB congeners, including 12 dioxin-like and seven indicator PCBs, were investigated in soils, and indoor and outdoor dusts from Port Harcourt city, Nigeria, in order to evaluate the characteristic distribution patterns in these media, their sources, and possible risk. The PCB concentrations varied from 4.59 to 116 ng g-1 for soils, and from 1.80 to 23.0 ng g-1 and 2.73 to 57.4 ng g-1 for indoor and outdoor dusts respectively. The sequence of PCB concentrations in these matrices was soil > outdoor dust > indoor dust. The composition of PCBs in these matrices indicated the prevalence of lower chlorinated PCBs in indoor and outdoor dusts, while the higher chlorinated congeners were dominant in soils. Di-PCBs were the predominant homologues in indoor dusts, while deca-PCBs were the most prevalent homologues in outdoor dusts and soils. The TEQ values of dioxin-like PCBs in 60 % of the soils, 100 % of the indoor dust, and 30 % of the outdoor dust were above the indicative value of 4 pg TEQ g-1 established by the Canadian authority. The hazard index (HI) values for exposure of adults and children to PCBs in these media were mostly greater than one, while the total cancer risk (TCR) values exceeded the acceptable risk value of 10-6, which indicate probable non-carcinogenic and carcinogenic risks resulting from exposure to PCBs in these media. Source analysis for PCBs in these matrices shows that they originated from diverse sources.

Spatial distribution of polycyclic aromatic hydrocarbons in dust and soils from informal trade sites in southern Nigeria: Implications for risk and source analysis.

Polycyclic aromatic hydrocarbons (PAHs) are a group of semi-volatile and persistent organic compounds considered priority pollutants because of their pervasive nature and high toxicity to the ecosystem and humans. Therefore, this study aimed to evaluate the PAH concentrations in dust and soils around informal trade sites (ITS) in Nigeria to determine the level of risk, sources, and significance of these activities to the PAH load of the environment. The 16 US EPA PAHs in dust and soils from ITS were determined by gas chromatography-mass spectrometry (GC-MS). The PAH concentrations in dust from these informal trade sites varied from 120 to 8790, 56 to 4780, and 102-1090 µg kg-1 for automobile mechanic workshops (AMW), car dismantling (CDS), and material recovery sites (MRS), respectively, whereas those of soils ranged from 3000 to 95,500, 554 to 14,700, and 966-25,200 µg kg-1 for AMW, CDS, and MRS respectively. The PAH profiles indicated that 3- to 5-ring PAHs were prominent in dust and soils around the ITS. The concentrations of the US EPA 16 PAHs in dust and soils from these ITS showed no correlation with organic matter, while the concentrations of PAH homologues in soils of these ITS showed no correlation with those of dust. Incremental lifetime cancer risk (ILCR) values in the magnitude of 10-4 to 101 were obtained for adult and childhood exposure to PAHs in dust and soils from these ITS. Exposure to PAHs in dust from these ITS gives rise to less risk than for soils. The results indicated that automobile mechanic workshops contribute more PAHs to the environment than car dismantling and material recovery activities. The source analysis showed that the PAH contamination of these sites arises from burning of biomass, plastic materials, and oils, and emissions from vehicles.

Distribution, sources and exposure risk of polycyclic aromatic hydrocarbons in soils, and indoor and outdoor dust from Port Harcourt city, Nigeria.

In this study, we evaluated the concentrations, composition, sources, and potential risks of polycyclic aromatic hydrocarbons (PAHs) in soils, and indoor and outdoor dust from Port Harcourt city in Nigeria. Gas chromatography-mass spectrometry (GC-MS) was used for the detection and quantification of PAH species in the samples. The concentrations of the US EPA 16 PAHs plus 2-methyl-naphthalene (∑17 PAHs) in soils, and indoor and outdoor dust from Port Harcourt city ranged from 240 to 38 400, 276 to 9130 and 44 to 13 200 µg kg-1 (dry weight, d.w.) respectively. The PAH concentrations in these matrices followed the sequence: soil > indoor dust > outdoor dust. The composition of PAHs in soils and dust (indoor and outdoor) showed remarkable differences with prominence of 3- and 5-ring PAHs. The estimated carcinogenic risk to the residents arising from exposure to these concentrations of PAHs in soils, and indoor and outdoor dust from Port Harcourt was above the acceptable target cancer risk value of 10-6. We concluded that these sites require clean-up, remedial actions and implementation of stringent pollution control measures with the intention of reducing the undesirable impacts of PAHs on both the ecosystem and humans.