ABSTRACT
For achieving the better modifying effect of polyurethane on asphalt pavement materials, the PUA powder modifier was prepared with fine grinding at the glass transition temperature, and polyurethane-modified asphalt (PUA-MA) with different dosages of modifier was prepared. The impact of the PUA on the physical properties of asphalt binder was studied. The modifying mechanism of PUA on asphalt was explored by investigating the thermal performance and chemical composition of asphalt (thermogravimetric analysis, differential scanning calorimetry test, and Fourier transform infrared spectroscopy). The micrograph of the interactive interface was characterized by scanning an electron microscope. Furthermore, the rheological properties of PUA-MA were also investigated and analyzed. The results indicated that the PUA had a dense structure with few pores on the surface. After mixing with asphalt, it altered the asphalt's internal structure via physical fusion and chemical reaction (carbamate formation). PUA improved the thermal stability of asphalt, enhanced the asphalt's thermal decomposition temperature, and further reduced the thermal mass loss while decreasing the glass transition temperature. The addition and dosage increase in the PUA modifier significantly improved the softening point, viscosity, complex shear modulus, and rutting factor of asphalt. Also, the PUA could improve the elastic recovery ability of asphalt and enhance the rutting resistance of asphalt at high temperatures. However, the crack resistance at low temperatures was not effectively improved (ductility and penetration decreased). When the dosage was 6-9%, PUA-MA had the best high-temperature performance, but asphalt showed poor low-temperature performance at this dosage. This study provides a theoretical reference for popularizing and applying polyurethane as an asphalt modifier in road engineering.
ABSTRACT
To confirm the feasibility of waste incineration fly ash applied in asphalt pavement materials, the waste fly ash from the waste incineration station in Dongguan (DG-FA) and Guangzhou (GZ-FA) were selected as mineral filler replacing limestone powder (LF) to prepare asphalt mortar. The physical properties, chemical composition, and thermal characteristics of FA were analyzed. The effect of FA on the physical properties and rheological properties of asphalt binder was investigated systematically. The micromorphology of FA asphalt mortar was characterized. Finally, the blocking effect of asphalt binder on the leaching of toxic elements from FA was evaluated through XRF test. The results showed that the granular composition of FA particles was similar to that of LF. Furthermore, compared to LF, the specific surface area and the pore structure of FA were more developed, and the high active amorphous material was higher. Adding FA to asphalt mortar and increasing replacing amount improved its high-temperature rutting resistance as well as its ability to adhere to asphalt, while the low-temperature crack resistance was decreased. Further, the asphalt binder provided the good shielding effect against the migration of heavy metals in FA. While the leaching concentration of Pb element slightly exceeded the hazardous waste leaching standard (GB5085.3-2007), the remaining elements met the standard requirements. Overall, FA improved asphalt mortar performance, and the asphalt had a good curing and stabilizing effect on the toxic elements in fly ash, indicating that FA could be used as a filler in asphalt pavements.
