Facile construction of agar-based fire-resistant aerogels: A synergistic strategy via in situ generations of magnesium hydroxide and cross-linked Ca-alginate.

Biomass-based aerogel materials have many advantages, such as low thermal conductivity and non-toxicity. These materials are environmentally friendly and have broad development potential in the fields of packaging, cushioning and green building insulation. However, defects, such as low mechanical strength and poor fire safety, greatly limit the application of these materials. In this work, the agar/polyvinyl alcohol composite aerogel modified by the magnesium hydroxide (MH)/sodium alginate (SA) composite flame retardant system was developed by using a freeze-dried technology and the strategy of in-situ generation of MH and crosslinking of SA. The results showed that the MH/SA dramatically enhanced the mechanical and thermal stability of the composites. The compression modulus of AP-M35S15 was 2.37 MPa, which was 152.13 % higher than that of AP-M50. The limiting oxygen index value of AP-M35S15 was 34.1 % and reached V-0 level in the vertical burning test, which was better than those of the samples with a single MH effect. The cone calorimetric test showed that the MH/SA composite flame retardant system performed better in extending the ignition time, slowing down the heat release rate and reducing the total heat release and had a more complete dense carbon structure after burning.

In situ nanoarchitectonics of magnesium hydroxide particles for property regulation of carboxymethyl cellulose/poly(vinyl alcohol) aerogels.

Carboxymethyl cellulose (CMC)-based aerogels with low density, low thermal conductivity, and biodegradability are promising candidates for environmentally friendly heat-insulating materials. However, the application of CMC-based aerogels as insulation materials in building exterior walls is limited by the high water sensitivity, poor mechanical properties and high flammability of these aerogels. In this work, a simple hydration method was used to generate magnesium hydroxide (MH) directly from CMC/polyvinyl alcohol (PVA) mixed sol with active MgO obtained by calcined magnesite as the raw material. A series of composite aerogels with different MH contents were prepared through the freeze-drying method. Scanning electron microscopy showed that nanoflower-like MH was successfully synthesised in situ in the 3D porous polymer aerogel matrix. Compared with the mechanical properties and water resistance of the original CMC/PVA composite aerogels, those of the composite aerogels were significantly improved. In addition, the flame retardancy of the CMC/PVA composite aerogels was greatly enhanced by the introduction of MH into the polymer matrix, and the limiting oxygen index reached 35.5% when the MH loading was 60%.