Recent advances in electrochemical and optical sensing of the organophosphate chlorpyrifos: a review.

Chlorpyrifos (CP) is one of the most popular organophosphorus pesticides that is commonly used in agricultural and nonagricultural environments to combat pests. However, several concerns regarding contamination due to the unmitigated use of chlorpyrifos have come up over recent years. This has popularized research on various techniques for chlorpyrifos detection. Since conventional methods do not enable smooth detection, the recent trends of chlorpyrifos detection have shifted toward electrochemical and optical sensing techniques that offer higher sensitivity and selectivity. The objective of this review is to provide a brief overview of some of the important and innovative contributions in the field of electrochemical and optical sensing of chlorpyrifos with a primary focus on the comparative advantages and shortcomings of these techniques. This review paper will help to offer better perspectives for research in organophosphorus pesticide detection in the future.

An Efficient Inclusion Complex Based Fluorescent Sensor for Mercury (II) and its Application in Live-Cell Imaging.

The formation of an inclusion complex between hydroxypropyl-ß-cyclodextrin (H-CD) and 4-acetylphenyl-4-(((6-chlorobenzo[d]thiazol-2-yl)-imino)-methyl)-benzoate (L) was investigated by FT-IR, 1H-NMR, X-ray diffraction (XRD), FT-Raman, scanning electron microscope (SEM) techniques in the solid-state, absorption and emission spectroscopy in the liquid state and the virtual state as molecular docking technique. The binding properties of the inclusion complex (H-CD: L) with cations in deionized water was observed via absorbance and photoluminescence (PL) emission spectroscopy. The fluorescence probe (H-CD: L) inclusion complex (IC) was examined for several heavy metal cations, and identified that the PL emission wavelength of the complex displayed a continuous rise in the fluorescence intensity for Hg2+. A linearity range of 1 × 10-8 - 11 × 10-8 M and limit of detection value of 2.71 × 10-10 M was found to be achieved for the detection of Hg2+. This outcome proves that the inclusion complex H-CD: L would be a promising material for the development a solid-state fluorescence probe for detecting Hg2+. It also shows application in real sample analysis and cell imaging.