PWC-based evaluation of groundwater pesticide pollution in the Júcar River Basin.

Predicting pesticides' behavior in the environment is necessary to anticipate and minimize their adverse effects. Despite the use of pesticides in Spain is increasing, the implementation and use of predictive mathematical models is seldomly done in practice due to the lack of available data. In this original work, the Pesticide Root Zone Model version 5 (PRZM 5) mathematical model under the Pesticide in Water Concentration 1.52 (PWC) interface has been applied to model pesticide behavior in nine groundwater bodies located inside the Júcar River Basin (JRB) in Spain. Mathematical modeling allowed calculating the maximum concentration of pesticides after completing the calibration process. Bromacil, terbuthylazine, atrazine, desethyl-terbuthylazine, and terbumeton concentrations in groundwater were simulated between 2006 and 2019. Results show that the maximum pesticide concentration value on every well exceeds the current Spanish Maximum Concentration Limit (0.1 µg/L). PRZM 5 was able to reproduce pesticide concentration observations over time despite the limited amount of available data. This study contributes to assessing environmental risks caused by the use of pesticides inside the JRB and can potentially be applied in other areas of interest.

Numerical Modeling of Groundwater Pollution by Chlorpyrifos, Bromacil and Terbuthylazine. Application to the Buñol-Cheste Aquifer (Spain).

Chlorpyrifos, Bromacil and Terbuthylazine are commonly used as insecticides and herbicides to control weeds and prevent non-desirable growth of algae, fungi and bacteria in many agricultural applications. Despite their highly negative effects on human health, environmental modeling of these pesticides in the vadose zone until they reach groundwater is still not being conducted on a regular basis. This work shows results obtained by version 5.08 of the Pesticide Root Zone Model (PRZM5) numerical model to simulate the fate and transport of Chlorpyrifos, Bromacil and Terbuthylazine between 2006 and 2018 inside the Buñol-Cheste aquifer in Spain. The model uses a whole set of parameters to solve a modified version of the mass transport equation considering the combined effect of advection, dispersion and reactive transport processes. The simulation process was designed for a set of twelve scenarios considering four application doses for each pesticide. Results show that the maximum concentration value for every scenario exceeds the current Spanish Maximum Concentration Limit (0.1 µg/L). Numerical simulations were able to reproduce concentration observations over time despite the limited amount of available data.